Citation: Zhan-Xin WU, Ya-Song QU, Xiao-Hua YU, Gang XIE, Wen-Zhi ZHANG, Peng-Yuan CUI, Yong-Gang LI. La(OH)₃ Loaded Zinc Aluminum Hydrotalcite: Preparation and Performance for Zinc Nickel Secondary Battery[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(5): 778-784. doi: 10.11862/CJIC.2021.096 shu

La(OH)₃ Loaded Zinc Aluminum Hydrotalcite: Preparation and Performance for Zinc Nickel Secondary Battery

Zhan-Xin WU ¹ ,
Ya-Song QU ¹ ,
Xiao-Hua YU ^1,, ,
Gang XIE ^{1, 2, 3} ,
Wen-Zhi ZHANG ¹ ,
Peng-Yuan CUI ¹ ,
Yong-Gang LI ⁴

1.
Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
2.
Kunming Metallurgical Research Institute Co., Ltd., Kunming 650503, China
3.
State Key Laboratory of Common Associated Non-ferrous Metal Resources Pressure Hydrometallurgy Technology, Kunming 650503, China
4.
Yunnan Copper Technology Development Co., Ltd., Kunming 650033, China

Corresponding author: Xiao-Hua YU, yxhyxh1978@aliyun.com
Received Date: 17 July 2020
Revised Date: 16 March 2021

Figures(7)

Lanthanum hydroxide (La(OH)₃) was loaded on the surface of zinc-aluminum hydrotalcite (Zn-Al LDHs) by co precipitation method. The X-ray diffraction (XRD) patterns and scanning electron microscopy (SEM) images reveal that the La(OH)₃ was successfully loaded on the surface of the Zn-Al LDHs, and the loaded Zn-Al LDHs still showed hexagonal plate-like crystals with uniform particle size and good dispersion; 5%La(OH)₃@Zn-Al LDHs had the best electrochemical performance. Cyclic voltammetry (CV), Tafel polarization curves and electrochemical impedance spectroscope (EIS) showed that it had better reversibility, larger positive corrosion potential and lower resistance. 5%La(OH)₃@Zn-Al LDHs showed the cycle retention of 94.84% after 80 cycles.
- load,
- Zn-Al LDHs,
- Zn-Ni secondary battery,
- La(OH)₃
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La(OH)₃ Loaded Zinc Aluminum Hydrotalcite: Preparation and Performance for Zinc Nickel Secondary Battery