Citation: Cheng-juan LI, Rong-yun LI, Zhi-tong CHU, Hou-ting LIU, Jing LU, Su-na WANG, Yun-wu LI. Synthesis, Structure and Proton Conduction of a Crystalline Ni(Ⅱ)-MOF with Continuous Hydrogen Bonds[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(4): 645-652. doi: 10.11862/CJIC.2021.088 shu

Synthesis, Structure and Proton Conduction of a Crystalline Ni(Ⅱ)-MOF with Continuous Hydrogen Bonds

Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252059, China

Corresponding author: Jing LU, lujing@lcu.edu.cn Su-na WANG, wangsuna@lcu.edu.cn
Received Date: 13 October 2020
Revised Date: 31 December 2020

Figures(6)

The flexible multi-carboxylic acid organic ligand and Ni(Ⅱ) cation were selected to construct Ni-MOF[Ni₂(L)(Nphen)₂(H₂O)₄]_n(1)(H₄L=5, 5′-(butane-1, 4-diylbis(oxy)) diisophthalic acid, Nphen=5-nitro-1, 10-phenanthro-line) under hydrothermal condition. X-ray single diffraction studies reveal that there are continuous hydrogen bonds in the crystal structure of complex 1, which would be beneficial to its proton conducting behavior. The IR, powder X-ray diffraction and thermogravimetric analyses suggest that the obtained complex is pure and stable. The electrochemical researches on the composite membrane incorporated by complex 1 and Nafion reveal that doping of complex 1 can significantly improve the proton conduction behavior of Nafion membrane. The proton conductivity of the composite membrane was 24.08% higher than that of pure Nafion membrane. CCDC: 2052757.
- metal-organic framework,
- hydrothermal synthesis,
- crystal structure,
- continuous hydrogen bond,
- proton conduction
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