Citation: Ya LU, Min-Zhi ZHANG, Gang-Feng LIANG, Chun-Xia LI, Guo-Liang ZHAO. Preparation and Fluorescent Properties of LiBa_0.95-yBO₃: 0.05Tb³⁺, yBi³⁺[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(3): 516-524. doi: 10.11862/CJIC.2021.066 shu

Preparation and Fluorescent Properties of LiBa_0.95-yBO₃: 0.05Tb³⁺, yBi³⁺

1.
Xingzhi College, Zhejiang Normal University, Jinhua, Zhejiang 321004, China
2.
College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: Guo-Liang ZHAO, sky53@zjnu.cn
Received Date: 20 September 2020
Revised Date: 13 January 2021

Figures(12)

Two series of phosphors of Tb³⁺ single doped LiBa_1-xBO₃: xTb³⁺ (molar fraction x=0.02, 0.03, 0.04, 0.05, 0.06, 0.07) and Bi³⁺/Tb³⁺ co-doped LiBa_0.95-yBO₃: 0.05Tb³⁺, yBi³⁺ (molar fraction y=0.02, 0.03, 0.04, 0.05, 0.06, 0.07) of which can be effectively excited by (near) ultraviolet at 369, 254 nm light were prepared by high temperature solid state reaction from boric acid and carbonates. The structures and morphology of the samples were characterized by powder X-ray diffraction (PXRD) and scanning electron microscopy. PXRD measurement shows that the products of the two series are pure phase LiBaBO₃. By measuring the fluorescent spectra of the first series of products, the product with the best luminescent intensity was screened out, and the optimal doping amount of Tb³⁺ was determined accordingly; on this basis, the second series of phosphors with different doping amounts of Bi³⁺ were prepared. The experimental results of fluorescent spectra show that the luminescent intensity of Tb³⁺/Bi³⁺ co doped phosphors was better than that of Tb³⁺ single-doped phosphors, indicating that Bi³⁺ sensitizes to Tb³⁺; the fluorescent intensity of the products increased first and then decreased with the increase of Bi³⁺ content, and the luminescence intensity of the products reached the maximum when the doped molar fraction y of Bi³⁺ was 0.03. The energy transfer from Bi³⁺ to Tb³⁺ ions is attributed to the dipole quadrupole interaction. The CIE chromaticity coordinates of the phosphors show that the luminescent color exhibited a gradual trend from green to white in some degree.
- borate,
- co-doped,
- terbium,
- bismuth,
- phosphor,
- fluorescent property
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Fluorescent Properties of LiBa0.95-yBO3: 0.05Tb3+, yBi3+

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通讯作者: 陈斌, bchen63@163.com

Preparation and Fluorescent Properties of LiBa_0.95-yBO₃: 0.05Tb³⁺, yBi³⁺