Citation: Qiang HE, Xiao-Gang SUN, Jing-Yi ZOU, Rui LI. Three-Dimensional Porous Carbon Loading Tin Oxide and Cooperating with Lithium Fluoride to Prepare High Performance Lithium Ion Anode[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(3): 473-481. doi: 10.11862/CJIC.2021.059 shu

Three-Dimensional Porous Carbon Loading Tin Oxide and Cooperating with Lithium Fluoride to Prepare High Performance Lithium Ion Anode

School of Mechanical and Electrical Engineering, Nanchang University, Nanchang 330031, China

Corresponding author: Xiao-Gang SUN, xiaogangsun@163.com
Received Date: 16 September 2020
Revised Date: 7 January 2021

Figures(8)

New porous carbon nanosheets/carbon nanotubes (PC/CNT) materials showed a rich hierarchical pore structure with high tin oxide (SnO₂) loading. The three-dimensional structure formed by the cross-linking of PC and CNT can improve Li⁺ transmission rate and electron conduction. In addition, lithium fluoride (LiF) doped in the electrode can not only reduce the charge transfer resistance of the SnO₂-PC/CNT-LiF electrode, but also supplement the Li⁺ consumed during the formation of the SEI film, reduce the irreversible capacity and enhance the stability of the SEI film. The first reversible specific capacity of SnO₂-PC/CNT-LiF electrode reached 1 642.98 mAh·g^-1 at current density of 100 mA·g^-1, and the utilization rate of active material was as high as 90.12%. After 100 cycles, the specific discharge capacity still reached above 745.11 mAh·g^-1, and the coulombic efficiency remained above 95.1%, showing excellent rate and cycle performance.
- tin oxide,
- porous carbon nanosheets,
- carbon nanotubes,
- lithium fluoride
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