Citation: Lu-lu WU, Wei-wei JIANG, Guo-yu DING, Ya-hui LI, Zhen ZHU, Xin-guo JING, Feng-qian YAN, Guo-jun XU, Zhi-hao YUE, Xiao-min LI, Fu-gen SUN, Lang ZHOU. In-Situ Construction of Cu₃P Nanoflake Array@Cu Foam 3D Frameworks for High Performance Li-Metal Anodes[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(4): 709-716. doi: 10.11862/CJIC.2021.056 shu

In-Situ Construction of Cu₃P Nanoflake Array@Cu Foam 3D Frameworks for High Performance Li-Metal Anodes

Institute of Photovoltaics, Nanchang University, Nanchang 330031, China

Corresponding author: Fu-gen SUN, sunfugen@ncu.edu.cn
Received Date: 16 November 2020
Revised Date: 29 December 2020

Figures(6)

The Cu₃P nanoflake array was uniformly coated onto the commercial Cu foam skeleton(NF-Cu₃P@Cu)through an in-situ growth method, and then used as a highly efficient 3D host for stable lithium metal anodes. The Cu₃P nanoflake array with high lithiophilicity could provide abundant and homogenous active-sites for Li nucleation, leading to the fast nucleation and homogenous deposition of Li metal into the NF-Cu₃P@Cu. Furthermore, during the electrochemical deposition process of Li metal, the Cu₃P nanoflake array could be lithiated to form the fastion conductor Li₃P, which ensures fast and uniform diffusion of Li⁺ in the NF-Cu₃P@Cu, thus resulting in the effective suppression of Li dendrite growth. Therefore, the obtained Li@NF-Cu₃P@Cu composite anode exhibited excellent cycling stability in both the symmetric and full cells.
- energy storage technology,
- lithium batteries,
- lithium metal anode,
- Cu foam,
- lithium dendrite
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沈阳化工大学材料科学与工程学院沈阳 110142

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南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com

In-Situ Construction of Cu₃P Nanoflake Array@Cu Foam 3D Frameworks for High Performance Li-Metal Anodes