Citation: Shuai-Shuai MA, Cheng-Juan HUANG, Yu-Qing ZONG, Jian-Dong GU, Zhao-Lian YE, Jin-Juan XUE. Preparation and Photocatalytic Activity of Ag/Ag₂MoO₄/Bi₂MoO₆ Composite Photocatalyst[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(3): 531-540. doi: 10.11862/CJIC.2021.055 shu

Preparation and Photocatalytic Activity of Ag/Ag₂MoO₄/Bi₂MoO₆ Composite Photocatalyst

1.
College of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou, Jiangsu 213001, China
2.
School of Environmental and Safety Engineering, Changzhou University, Changzhou, Jiangsu 213164, China

Corresponding author: Shuai-Shuai MA, machem@163.com Jin-Juan XUE, xuechem@163.com
Received Date: 24 August 2020
Revised Date: 19 November 2020

Figures(10)

A novel Ag/Ag₂MoO₄/Bi₂MoO₆ ternary photocatalyst was successfully prepared by hydrothermal, chemical deposition and in-situ photoreduction process. The as-prepared photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS) and UV-visible diffuse reflection spectroscopy (UV-Vis DRS) to investigate the composition, morphology, optical absorption characteristics and photoelectrochemical properties. The photocatalytic performance of Ag/Ag₂MoO₄/Bi₂MoO₆ photocatalyst was evaluated with tetracycline as the target pollutant under visible light. The research results show that, compared with pure Ag₂MoO₄ and Bi₂MoO₆, the surface plasmon resonance (SPR) effect of Ag significantly broadens the visible light absorption capacity and response range of the catalytic system. When the theoretical loading (mass fraction) of Ag₂MoO₄ was 24.6%, Ag/Ag₂MoO₄/Bi₂MoO₆ ternary photocatalyst could completely degrade tetracycline within 20 min, and maintained high catalytic activity after 5 cycles of use, showing good cycle stability.
- Ag₂MoO₄,
- Bi₂MoO₆,
- photocatalysis,
- degradation,
- antibiotic
1. [1]
  Xu J, Zhang B B, Jia L, Bi N, Zhao T Q. J. Hazard. Mater. , 2020, 386: 121630 doi: 10.1016/j.jhazmat.2019.121630
2. [2]
  Liu X H, Guo X C, Liu Y, Lu S Y, Xi B D, Zhang J, Wang Z, Bi B. Environ. Pollut. , 2019, 254: 112996 doi: 10.1016/j.envpol.2019.112996
3. [3]
  Yang Y Y, Song W J, Lin H, Wang W B, Du L N, Xing W. Environ. Int. , 2018, 116: 60-73 doi: 10.1016/j.envint.2018.04.011
4. [4]
  Wu Q F, Li Z H, Hong H L. Appl. Clay Sci. , 2013, 74: 66-73 doi: 10.1016/j.clay.2012.09.026
5. [5]
  ZHANG Y Q, ZENG X Y, YU K, LIU G F, CAO H L, LÜ J, CAO R. Chinese J. Inorg. Chem. , 2019, 35(11): 2185-2191 doi: 10.11862/CJIC.2019.243
6. [6]
  Yan X, Wang X Y, Gu W, Wu M M, Yan Y, Hu B, Che G B, Han D L, Yang J H, Fan W Q, Shi W D. Appl. Catal. B, 2015, 164: 297-304 doi: 10.1016/j.apcatb.2014.09.046
7. [7]
  Xu W H H, Zhang G, Wai O W H, Zou S C C, Li X D D. J. Soils Sediments, 2009, 9: 364-373 doi: 10.1007/s11368-009-0091-z
8. [8]
  Jiang D L, Xiao P, Shao L Q, Li D, Chen M. Ind. Eng. Chem. Res. , 2017, 56: 8823-8832 doi: 10.1021/acs.iecr.7b01840
9. [9]
  LIANG M J, DENG N, XIANG X Y, MEI Y, YANG Z Y, YANG Y, YANG S J. Chinese J. Inorg. Chem. , 2019, 35(2): 263-270
10. [10]
  Zhang L W, Xu T G, Zhao X, Zhu Y F. Appl. Catal. B, 2010, 98: 138146
11. [11]
  Wang S Y, Ding X, Yang N, Zhan G M, Zhang X H, Dong G H, Zhang L Z, Chen H. Appl. Catal. B, 2020, 265: 118585 doi: 10.1016/j.apcatb.2019.118585
12. [12]
  Dai Z, Qin F, Zhao H Q, Ding J, Liu Y L, Chen R. ACS Catal. , 2016, 6: 3180-3192 doi: 10.1021/acscatal.6b00490
13. [13]
  Guo L, Zhao Q, Shen H, Han X X, Zhang K L, Wang D J, Fu F, Xu B. Catal. Sci. Technol. , 2019, 9: 3193-3202 doi: 10.1039/C9CY00579J
14. [14]
  Zhang J J, Wang T, Chang X X, Li A, Gong J L. Chem. Sci. , 2016, 7: 6381-6386 doi: 10.1039/C6SC01803C
15. [15]
  Zhao Z W, Zhang W D, Sun Y J, Yu J Y, Zhang Y X, Wang H, Dong F, Wu Z B. J. Phys. Chem. C, 2016, 120: 11889-11898 doi: 10.1021/acs.jpcc.6b01188
16. [16]
  Long J L, Wang S C, Chang H J, Zhao B Z, Liu B T, Zhou Y G, Wei W, Wang X X, Huang L, Huang W. Small, 2014, 10: 2791-2795 doi: 10.1002/smll.201302950
17. [17]
  Ding X, Zhao K, Zhang L Z. Environ. Sci. Technol. , 2014, 48: 58235831
18. [18]
  Dong H J, Chen G, Sun J X, Li C M, Yu Y G, Chen D H. Appl. Catal. B, 2013, 134: 46-54
19. [19]
  Zheng B J, Wang X, Liu C, Tan K, Xie Z X, Zheng L S. J. Mater. Chem. A, 2013, 1: 12635-12640 doi: 10.1039/c3ta12946b
20. [20]
  Li D, Duan X C, Qin Q, Fan H M, Zheng W J. CrystEngComm, 2013, 15: 8933 doi: 10.1039/c3ce41365a
21. [21]
  Liu Y, Yu H B, Cai M, Sun J W. Catal. Commun. , 2012, 26: 63-67 doi: 10.1016/j.catcom.2012.04.017
22. [22]
  Gao S T, Feng T, Feng C, Shang N Z, Wang C. J. Colloid Interface Sci. , 2016, 466: 284-290 doi: 10.1016/j.jcis.2015.12.045
23. [23]
  Gao S T, Liu W H, Shang N Z, Feng C, Wu Q H, Wang Z, Wang C. RSC Adv. , 2014, 4(106): 61736-61742 doi: 10.1039/C4RA11364K
24. [24]
  Jiao Z Y, Zhang J L, Liu Z D, Ma Z. J. Photochem. Photobiol. A, 2019, 371: 67-75 doi: 10.1016/j.jphotochem.2018.11.003
25. [25]
  Zhang J L, Ma Z. J. Taiwan Inst. Chem. Eng. , 2017, 71: 156-164 doi: 10.1016/j.jtice.2016.11.030
26. [26]
  Xue J J, Huang C J, Zong Y Q, Gu J D, Wang M X, Ma S S. Appl. Organomet. Chem. , 2019, 33: e5187
27. [27]
  Li H P, Deng Q H, Liu J Y, Hou W G, Du N, Zhang R J, Tao X T. Catal. Sci. Technol. , 2014, 4: 1028-1037 doi: 10.1039/C3CY00940H
28. [28]
  Zhang M Y, Shao C L, Mu J B, Huang X M, Zhang Z Y, Guo Z C, Zhang P, Liu Y C. J. Mater. Chem. , 2012, 22: 577-584 doi: 10.1039/C1JM13470A
29. [29]
  Li Z Q, Chen X T, Xue Z L. CrystEngComm, 2013, 15: 498-508 doi: 10.1039/C2CE26260F
30. [30]
  Gao X M, Shang Y Y, Liu L B, Nie W, Fu F. J. Phys. Chem. Solids, 2018, 127: 186-193
31. [31]
  Wen X J, Shen C H, Niu C G, Lai D C, Zhu M S, Sun J, Fei Z H. J. Mol. Liq. , 2019, 288: 111063 doi: 10.1016/j.molliq.2019.111063
32. [32]
  Zhu M S, Chen P L, Liu M H. J. Mater. Chem. , 2012, 22: 2148721494
33. [33]
  Zong X, Yan H J, Wu G P, Ma G J, Wen F Y, Wang L, Li C. J. Am. Chem. Soc. , 2008, 130: 7176-7177 doi: 10.1021/ja8007825
34. [34]
  Zhang J L, Zhang L S, Shen X F, Xu P F, Liu J S. CrystEngComm, 2016, 18: 3856-3865 doi: 10.1039/C6CE00824K
35. [35]
  YANG B Y, LI H S, NING Z, FENG C, GAO S T, WANG C. Chinese J. Inorg. Chem. , 2017, 33(3): 396-404
36. [36]
  Zhao D X, Cai C. Inorg. Chem. Front. , 2020, 7(15): 2799-2808 doi: 10.1039/D0QI00540A
37. [37]
  Kang L, Pang Y P, Lu Q F. Inorg. Chem. Front. , 2019, 6(11): 3215-3224 doi: 10.1039/C9QI00950G
38. [38]
  Li S J, Hu S W, Jiang W, Zhang J L, Xu K B, Wang Z H. J. Colloid Interface Sci. , 2019, 556: 335-344 doi: 10.1016/j.jcis.2019.08.077
39. [39]
  Zhang L H, Shen Q H, Yu L X, Huang F L, Zhang C T, Sheng J S, Zhang F, Cheng D, Yang H. CrystEngComm, 2020, 22(33): 5481-5490 doi: 10.1039/D0CE00761G
40. [40]
  Shi W L, Li M Y, Huang X L, Ren H J, Guo F, Tang Y B, Lu C Y. Chem. Eng. J. , 2020, 394: 125009 doi: 10.1016/j.cej.2020.125009
41. [41]
  Tao R, Shao C L, Li X H, Li X W, Liu S, Yang S, Zhao C C, Liu Y C. J. Colloid Interface Sci. , 2018, 529: 404-414 doi: 10.1016/j.jcis.2018.06.035
42. [42]
  Li Z Q, Chen X T, Xue Z L. Sci. China Chem. , 2013, 56: 443-450 doi: 10.1007/s11426-013-4845-5
43. [43]
  Wang Z L, Huo Y, Zhang J F, Lu C, Dai K, Liang C H, Zhu G P. J. Alloys Compd. , 2017, 729: 100-108 doi: 10.1016/j.jallcom.2017.09.152
44. [44]
  Wang J J, Tang L, Zeng G M, Liu Y N, Zhou Y Y, Deng Y C, Wang J J, Peng B. ACS Sustainable Chem. Eng. , 2017, 5: 1062-1072 doi: 10.1021/acssuschemeng.6b02351
45. [45]
  Linic S, Christopher P, Ingram D B. Nat. Mater. , 2011, 10(12): 911921
1. [1]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
2. [2]
  Meijuan Chen , Liyun Zhao , Xianjin Shi , Wei Wang , Yu Huang , Lijuan Fu , Lijun Ma . Synthesis of carbon quantum dots decorating Bi₂MoO₆ microspherical heterostructure and its efficient photocatalytic degradation of antibiotic norfloxacin. Chinese Chemical Letters, 2024, 35(8): 109336-. doi: 10.1016/j.cclet.2023.109336
3. [3]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
4. [4]
  Wenda WANG , Jinku MA , Yuzhu WEI , Shuaishuai MA . Waste biomass-derived carbon modified porous graphite carbon nitride heterojunction for efficient photodegradation of oxytetracycline in seawater. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 809-822. doi: 10.11862/CJIC.20230353
5. [5]
  Xin Wang , Changzhao Chen , Qishen Wang , Kai Dai . Graphene quantum dot modified Bi2MoO6 nanoflower for efficient degradation of BPA under visible light. Chinese Journal of Structural Chemistry, 2024, 43(12): 100473-100473. doi: 10.1016/j.cjsc.2024.100473
6. [6]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
7. [7]
  Huirong LIU , Hao XU , Dunru ZHU , Junyong ZHANG , Chunhua GONG , Jingli XIE . Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1368-1376. doi: 10.11862/CJIC.20240066
8. [8]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
9. [9]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
10. [10]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
11. [11]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
12. [12]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
13. [13]
  Zhinan GUO , Junli WANG , Qiang ZHAO , Zhifang JIA , Zuopeng LI , Kewei WANG , Yong GUO . Cu₂O/Bi₂CrO₆ Z-scheme heterojunction: Construction and photocatalytic degradation properties for tetracycline. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 741-752. doi: 10.11862/CJIC.20240403
14. [14]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
15. [15]
  Huizhong Wu , Ruiheng Liang , Ge Song , Zhongzheng Hu , Xuyang Zhang , Minghua Zhou . Enhanced interfacial charge transfer on Bi metal@defective Bi₂Sn₂O₇ quantum dots towards improved full-spectrum photocatalysis: A combined experimental and theoretical investigation. Chinese Chemical Letters, 2024, 35(6): 109131-. doi: 10.1016/j.cclet.2023.109131
16. [16]
  Yuan Teng , Zichun Zhou , Jinghua Chen , Siying Huang , Hongyan Chen , Daibin Kuang . Dual atom-bridge effect promoting interfacial charge transfer in 2D/2D Cs₃Bi₂Br₉/BiOBr epitaxial heterojunction for efficient photocatalysis. Chinese Chemical Letters, 2025, 36(2): 110430-. doi: 10.1016/j.cclet.2024.110430
17. [17]
  Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
18. [18]
  Zhi Zhu , Xiaohan Xing , Qi Qi , Wenjing Shen , Hongyue Wu , Dongyi Li , Binrong Li , Jialin Liang , Xu Tang , Jun Zhao , Hongping Li , Pengwei Huo . Fabrication of graphene modified CeO2/g-C3N4 heterostructures for photocatalytic degradation of organic pollutants. Chinese Journal of Structural Chemistry, 2023, 42(12): 100194-100194. doi: 10.1016/j.cjsc.2023.100194
19. [19]
  Yiqian Jiang , Zihan Yang , Xiuru Bi , Nan Yao , Peiqing Zhao , Xu Meng . Mediated electron transfer process in α-MnO₂ catalyzed Fenton-like reaction for oxytetracycline degradation. Chinese Chemical Letters, 2024, 35(8): 109331-. doi: 10.1016/j.cclet.2023.109331
20. [20]
  Wenhao Wang , Guangpu Zhang , Qiufeng Wang , Fancang Meng , Hongbin Jia , Wei Jiang , Qingmin Ji . Hybrid nanoarchitectonics of TiO₂/aramid nanofiber membranes with softness and durability for photocatalytic dye degradation. Chinese Chemical Letters, 2024, 35(7): 109193-. doi: 10.1016/j.cclet.2023.109193

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(950)
HTML views(202)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Photocatalytic Activity of Ag/Ag2MoO4/Bi2MoO6 Composite Photocatalyst

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Photocatalytic Activity of Ag/Ag₂MoO₄/Bi₂MoO₆ Composite Photocatalyst