Citation: Qing LIU, Jun-Ming GUO, Xiao-Fang LIU, Hong-Li BAI, Ming-Wu XIANG, Wei BAI, Kai-Jiao DUAN. Preparation and Long Cycle Electrochemical Properties of B-Doped Spinel LiMn₂O₄ Cathode Material[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(2): 276-284. doi: 10.11862/CJIC.2021.046 shu

Preparation and Long Cycle Electrochemical Properties of B-Doped Spinel LiMn₂O₄ Cathode Material

Qing LIU ^{1, 2} ,
Jun-Ming GUO ^{1, 2,,} ,
Xiao-Fang LIU ^{1, 2} ,
Hong-Li BAI ^{1, 2} ,
Ming-Wu XIANG ^{1, 2} ,
Wei BAI ^{1, 2} ,
Kai-Jiao DUAN ^{1, 2}

1.
National and Local Joint Engineering Research Center for Green Preparation Technology of Biobased Materials, Yunnan Minzu University, Kunming 650500, China
2.
Key Laboratory of Green-Chemical Materials in University of Yunnan Province, Yunnan Minzu University, Kunming 650500, China

Corresponding author: Jun-Ming GUO, guojunming@tsinghua.org.cn
Received Date: 26 August 2020
Revised Date: 8 December 2020

Figures(7)

A single crystal polyhedron LiMn_1.94B_0.06O₄ cathode material was prepared by a solid-state combustion synthesis, their structural and electrochemical properties were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and charge-discharge test. The results show that Bdoping did not change the crystal structure of spinel LiMn₂O₄, and it could promote the preferential growth of (440) and (400) crystal facets. Inducing the formation of the single crystal polyhedron LiMn_1.94B_0.06O₄ material with the highly exposed (111) facets and a small part of (110) and (100) facets, as well as a particle size of 160~350 nm, which enabled minimal Mn dissolution and provided more lithium ions channels. The LiMn_1.94B_0.06O₄ delivered the initial discharge capacity of 103 mAh·g^-1 with a good capacity retention rate of 57.7% after 2 000 cycles at 10C and 25℃. At high current rate of 15C, it showed the initial discharge capacity of 67.1 mAh·g^-1, and the capacity retention rates of 46.2% was obtained after 1 500 cycles. Moreover, at 1C and high temperature of 55℃, the initial discharge capacity of 125.2 mAh·g^-1 was also maintained, showing good high temperature performance. The B-doping can effectively improve the high rate performance and cycle life of spinel LiMn₂O₄, stabilize the crystal structure, inhibit the Jahn-Teller effect and relieve the Mn dissolution.
- spinel LiMn₂O₄,
- single crystal polyhedron,
- B-doping,
- Jahn-Teller effect,
- Mn dissolution,
- electrochemistry,
- kinetics,
- cathode material
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Preparation and Long Cycle Electrochemical Properties of B-Doped Spinel LiMn₂O₄ Cathode Material