Citation: Zhou-Rong XIAO, Fang HOU, Xiang-Wen ZHANG, Li WANG, Guo-Zhu LI. Preparation of Ordered Mesoporous Nitrogen Doped Carbon Supported Fe₂O₃ for Oxygen Reduction Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(2): 243-250. doi: 10.11862/CJIC.2021.024 shu

Preparation of Ordered Mesoporous Nitrogen Doped Carbon Supported Fe₂O₃ for Oxygen Reduction Reaction

Zhou-Rong XIAO ¹ ,
Fang HOU ¹ ,
Xiang-Wen ZHANG ^{1, 2} ,
Li WANG ^{1, 2} ,
Guo-Zhu LI ^{1, 2,,}

1.
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
2.
Collaborative Innovation Center of Chemical Science & Engineering, Tianjin University, Tianjin 300072, China

Corresponding author: Guo-Zhu LI, gzli@tju.edu.cn
Received Date: 30 July 2020
Revised Date: 27 October 2020

Figures(11)

Ordered mesoporous nitrogen doped carbon supported iron oxide was prepared, which effectively reduced the overpotential of oxygen reduction. The physicochemical properties of the as-prepared catalysts were characterized by scanning electron microscopy, transmission electron microscopy, nitrogen adsorption-desorption test, powder X-ray diffraction, X-ray photoelectron spectroscopy and Raman spectroscopy. In addition, the activity and selectivity for oxygen reduction reaction was tested by rotating disc electrode under alkaline conditions. The results show that iron was loaded in ordered mesoporous nitrogen doped carbon in the form of Fe₂O₃ after nitrogen pyrolysis, and its specific surface area reached 755 cm²·g^-1. The results of Raman and X-ray photoelectron spectroscopy show that the graphitization degree of the catalyst increased with adding iron precursor. The impedance was decreased and its conductivity was increased. Under alkaline conditions, Fe₂O₃@NC exhibited a 4-electron oxygen reduction reaction, and its initial potential (-0.01 V vs Ag/AgCl) and half slope potential (-0.13 V vs Ag/AgCl) were comparable to those of commercial 20% Pt/C. In addition, the catalyst had superior methanol resistance and excellent constant voltage stability compared with commercial Pt/C. The discharge power of Fe₂O₃@NC reached 88 mW·cm^-2, which was 1.29 times that of commercial Pt/C.
- oxygen reduction reaction,
- fuel cell,
- Fe₂O₃,
- nitrogen doped carbon,
- mesoporous
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Preparation of Ordered Mesoporous Nitrogen Doped Carbon Supported Fe₂O₃ for Oxygen Reduction Reaction