Citation: ZHAO Tian, ZHU He-Xin, DONG Ming, ZHAO Yi. Framework Isomerism in Chromium-Benzenedicarboxylate MOF: MIL-88B(Cr) and MIL-101(Cr)[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(1): 103-109. doi: 10.11862/CJIC.2021.018 shu

Framework Isomerism in Chromium-Benzenedicarboxylate MOF: MIL-88B(Cr) and MIL-101(Cr)

School of Packaging and Materials Engineering, Hunan University of Technology, Zhuzhou, Hunan 412007, China

Corresponding author: ZHAO Tian, tian_zhao@hut.edu.cn
Received Date: 10 August 2020
Revised Date: 27 October 2020

Figures(8)

Two metal-organic frameworks (MOFs) of the same family, MIL-88B(Cr) and MIL-101(Cr), can be prepared under similar hydrothermal synthetic conditions via adjusting the concentration of acetic acid. Nanocrystals of MIL-101(Cr) with 100 nm average size and excellent S_BET (3 543 m²·g^-1) were obtained at relatively lower concentrations of acetic acid, while at higher concentrations the micro-sized MIL-88B(Cr) product with 'breathe' structure was formed. The products were characterized by powder X-ray diffraction, scanning electron microscopy, nitrogen physisorption measurement and thermal gravimetric analysis.
- MIL-88B(Cr),
- MIL-101(Cr),
- metal-organic frameworks,
- acetic acid
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