Citation: Yu-Xia LI, Shuai-Shuai LI, Xiao-Qin LIU, Lin-Bing SUN. Preparation of CuCl@MIL-101(Cr) by Double-Solvent Method and Investigation on Adsorptive Desulfurization Performance[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(2): 259-266. doi: 10.11862/CJIC.2021.016 shu

Preparation of CuCl@MIL-101(Cr) by Double-Solvent Method and Investigation on Adsorptive Desulfurization Performance

State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China

Corresponding author: Lin-Bing SUN, lbsun@njtech.edu.cn
Received Date: 14 August 2020
Revised Date: 16 November 2020

Figures(11)

Herein, a representative metal-organic framework (MOF), MIL-101(Cr), with a large specific surface area and good hydrothermal stability, has been chosen as porous support. The introducing of Cu(Ⅱ) precursor and reduction to Cu(Ⅰ) were sequentially occurred in the pores of MIL-101(Cr) via double-solvent method (DSM) in which the CuCl₂ was directly used for reduction and vitamin C was employed as a green reductant. The DSM is effective in preparing Cu(Ⅰ) sites on support MIL-101(Cr). By using the DSM, it can ensure that the structure of support material was maintained on account of mild operating conditions and all copper species in MIL-101(Cr) were reduced to Cu (Ⅰ). When CuCl content was 2.85 mmol·g^-1, the obtained Cu(Ⅰ)-containing materials exhibited a thiophene adsorption capacity (up to 0.175 mmol·g^-1), obviously higher than that of pristine MIL 101(Cr) (0.112 mmol·g^-1). This method thus offers a useful, controllable and green approach to form Cu(Ⅰ) sites within MOFs under relatively facile conditions. The resultant adsorbents exhibit obviously enhanced adsorptive desulfurization performance because of the specific interaction between Cu(Ⅰ) and thiophenic sulfur compounds.
- desulfurization,
- adsorption,
- π interactions,
- metal-organic frameworks,
- reduction
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