Citation: JING Nan, ZHOU An-Nan, WANG Guo-Hui, WANG Run-Wei, XU Qing-Hong. Ni(OH)₂ with Super-Small Nanoscale: Synthesis and Application in Li⁺ Adsorptions[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(1): 131-139. doi: 10.11862/CJIC.2021.015 shu

Ni(OH)₂ with Super-Small Nanoscale: Synthesis and Application in Li⁺ Adsorptions

1.
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
2.
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China

Corresponding author: XU Qing-Hong, xuqh@mail.buct.edu.cn
Received Date: 28 February 2020
Revised Date: 9 November 2020

Figures(10)

α-Ni(OH)₂ nanoparticles with 5 nm average diameter were prepared under the existence of glucose in water solution, and the size of α-Ni(OH)₂ nanoparticles was found to be controlled by the concentration of glucose. A possible mechanism of the preparation process was proposed. When the synthesis was processed without existence of the glucose, β-Ni(OH)₂ was obtained. The super-small α-Ni(OH)₂ nanoparticles showed strong adsorption ability to Li⁺ ions when pH value of the solution was about 7.0 under room temperature. Maximum adsorption capacity of the super-small α-Ni(OH)₂ nanoparticles to Li⁺ was about 214 mg·g^-1; however, the β-Ni(OH)₂ with diameter above 1.0 μm was low than 30 mg·g^-1. Freundlich equation analysis and SEM images of the adsorption products indicate multilayers' adsorption process to Li⁺ of α-Ni(OH)₂ nanoparticles.
- nickel hydroxide,
- super-small nanoparticle,
- lithium ion,
- adsorption
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Ni(OH)₂ with Super-Small Nanoscale: Synthesis and Application in Li⁺ Adsorptions