Citation: WANG Deng-Qiang, Chen Yu, LIU Xiao-Qing, BIAN Jian-Jian, YIN Xin-Ying, TENG Ming-Yu, RONG Mei-Zhu, WANG Zheng-Liang. Synthesis and Properties of Two Blue and Violet Light-Emitting Platinum(Ⅱ) Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(1): 33-38. doi: 10.11862/CJIC.2021.012 shu

Synthesis and Properties of Two Blue and Violet Light-Emitting Platinum(Ⅱ) Complexes

1.
Faculty of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650500, China
2.
School of Chemistry & Environment, Yunnan Minzu University, Kunming 650504, China

Corresponding author: TENG Ming-Yu, myteng@ynnu.edu.cn RONG Mei-Zhu, meizhurong@foxmail.com WANG Zheng-Liang, wangzhengliang@foxmail.com
Received Date: 24 January 2020
Revised Date: 28 October 2020

Figures(6)

With 2-(2-pyridyl)benzothiophene (btp) as the primary ligand, 2-(1H-imidazo[4, 5-f] [1, 10]phenanthrolin-2 -yl)phenol (ipap) and 3-methyl-6-phenylimidazo[2, 1-b]thiazole (mpmt) as the auxiliary ligands, two platinum(Ⅱ) complexes, [(btp)Pt(ipap)]Cl and (btp)Pt(mpmt)Cl were synthesized, and the crystal structure of (btp)Pt(mpmt)Cl was determined. The luminescence of the complexes which is attributed to the metal-to-ligand charge transfer (MLCT) emission has internal quantum efficiency about 60% with emission peaks at 426 nm (blue) and 381 nm (purple). The orbital energy levels of HOMO/LUMO were -4.69 eV/-2.55 eV and -4.80 eV/-2.21 eV, respectively. The crystal structure discloses that the low conjugation of these complexes results in their short wavelength emission. CCDC:1978721, (btp)Pt(mpmt)Cl.
1. [1]
  Zhang J, Wang L, Zhong A G, Huang G B, Wu F S, Li D, Teng M Y, Wang J L, Han D M. Dyes Pigm., 2019, 162:590-598 doi: 10.1016/j.dyepig.2018.10.053
2. [2]
  Lu J J, Liang X, Luo X F, Wu Z G, Zheng Y X. New J. Chem., 2020, 44:530-536 doi: 10.1039/C9NJ05218F
3. [3]
  Yin X Y, Yang Z Y, Huang G L, Bian J J, Wang D Q, Wang Q, Teng M Y, Wang Z L, Zhang J. New J. Chem., 2019, 43:5849-5856 doi: 10.1039/C8NJ06295A
4. [4]
  Ma X F, Luo X F, Yan Z P, Wu Z G, Zhao Y, Zheng Y X, Zuo J L. Organometallics, 2019, 38(19):3553-3559 doi: 10.1021/acs.organomet.9b00392
5. [5]
  Zhang L, Yan Z P, Tu Z L, Wu Z G, Zheng Y X. J. Mater. Chem. C, 2019, 7:11606-11611 doi: 10.1039/C9TC03937F
6. [6]
  Su N, Shen C Z, Zheng Y X. J. Organomet. Chem., 2019, 896:188-193 doi: 10.1016/j.jorganchem.2019.06.017
7. [7]
  Yan Z P, Liao K, Han H B, Su J, Zheng Y X. Zuo J L. Chem. Commun., 2019, 7:8215-8218
8. [8]
  Li T Y, Wu J, Wu G Z, Zheng Y X, Zuo J L, Pan Y. Coord. Chem. Rev., 2018, 374:55-91 doi: 10.1016/j.ccr.2018.06.014
9. [9]
  Li X M, Zhang J, Huang G L, Wang Y F, Rong M Z, Teng M Y, Liu J. Dyes Pigm., 2017, 141:1-4 doi: 10.1016/j.dyepig.2017.02.007
10. [10]
  ZHANG S, XUE L S, WU C, ZHENG Y X, ZUO J L. Chinese J. Inorg. Chem., 2014, 30(1):134-141
11. [11]
  Hamze R, Peltier J L, Sylvinson D, Jung M, Cardenas J, Haiges R, Soleilhavoup M, Jazzar R, Djurovich P I, Bertrand G, Thompson M E. Science, 2019, 363(6427):601-606 doi: 10.1126/science.aav2865
12. [12]
  Li X Y, Zhang J Y, Zhao Z F, Yu X, Li P C, Yao Y H, Liu Z W, Jin Q H, Bian Z Q, Lu Z H, Huang C H. ACS Appl. Mater. Interfaces, 2019, 11(3):3262-3270 doi: 10.1021/acsami.8b15897
13. [13]
  Lin L, Chen D H, Yu R M, Chen X L, Zhu W J, Liang D, Chang J F, Zhang Q, Lu C Z. J. Mater. Chem. C, 2017, 5:4495-4504 doi: 10.1039/C7TC00443E
14. [14]
  Wu F S, Tong H B, Wang K, Zhang X L, Zhang J, Wong W K, Zhu X J. J. Coord. Chem., 2016(6), 69:926-933
15. [15]
  Wu F S, Tong H B, Wang K, Zhang J, Xu Z B, Zhu X J. Inorg. Chem. Commun., 2015, 58:113-116 doi: 10.1016/j.inoche.2015.06.014
16. [16]
  Gu G, Shen Z L, Burrows P E, Forrest S R. Adv. Mater., 1997, 9(9):725-728 doi: 10.1002/adma.19970090910
17. [17]
  Zhou L, Kwong C L, Kwok C C, Cheng G, Zhang H J, Che C M. Chem. Asian J., 2014, 9(10):2984-2994 doi: 10.1002/asia.201402618
18. [18]
  Che C M, Kwok C C, Lai S W, Rausch A F, Finkenzeller W J, Zhu N Y, Yersin H. Chem. Eur. J., 2010, 16(1):233-247
19. [19]
  Xiang H F, Chan S C, Wu K K Y, Che C M, Lai P T. Chem. Commun., 2005, 11(11):1408-1410
20. [20]
  Che C M, Chan S C, Xiang H F, Chan M C W, Liu Y, Wang Y. Chem. Commun., 2004, 10(13):1484-1485
21. [21]
  Zhang J, Zhu X J, Zhong A G, Jia W P, Wu F S, Li D, Tong H B, Wu C L, Tang W Y, Zhang P, Wang L, Han D M. Org. Electron., 2017, 42:153-162 doi: 10.1016/j.orgel.2016.12.024
22. [22]
  Zhang J, Dai G L, Wu F S, Li D, Gao D C, Jin H W, Chen S, Zhu X J, Huang C X, Han D M. J. Photochem. Photobiol. A, 2016, 316:12-18 doi: 10.1016/j.jphotochem.2015.09.018
23. [23]
  Zhang J, Zhao F C, Zhu X J, Wong W K, Ma D G, Wong W Y. J. Mater. Chem., 2012, 22:16448-16457 doi: 10.1039/c2jm32266h
24. [24]
  Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1997.
25. [25]
  Zhang J, Xu L L, Wong W Y. Coord. Chem. Rev., 2018, 355:180-198 doi: 10.1016/j.ccr.2017.08.007
26. [26]
  King K A, Spellane P J, Watts R J. J. Am. Chem. Soc., 1985, 107(5):1431-1432 doi: 10.1021/ja00291a064
27. [27]
  PAN M, LI S H, CHENG M L, HU Y Y, SHI P, XU J Y, TONG B H, FENG M Q, ZHANG Q F. Chinese J. Inorg. Chem., 2018, 34(4):627-632
28. [28]
  Wong W Y, Ho C L, Gao Z Q, Mi B X, Chen C H, Cheah K W, Lin Z Y. Angew. Chem. Int. Ed., 2006, 45(46):7800-7803 doi: 10.1002/anie.200602906
29. [29]
  Ashraf R S, Shahid M, Klemm E, Al-Ibrahim M, Sensfuss S. Macromol. Rapid Commun., 2006, 27(17):1454-1459 doi: 10.1002/marc.200600314
1. [1]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
2. [2]
  Zehua Zhang , Haitao Yu , Yanyu Qi . 多重共振TADF分子的设计策略. Acta Physico-Chimica Sinica, 2025, 41(1): 2309042-. doi: 10.3866/PKU.WHXB202309042
3. [3]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
4. [4]
  Yihao Zhao , Jitian Rao , Jie Han . Synthesis and Photochromic Properties of 3,3-Diphenyl-3H-Naphthopyran: Design and Teaching Practice of a Comprehensive Organic Experiment. University Chemistry, 2024, 39(10): 149-155. doi: 10.3866/PKU.DXHX202402050
5. [5]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
6. [6]
  Shiyang He , Dandan Chu , Zhixin Pang , Yuhang Du , Jiayi Wang , Yuhong Chen , Yumeng Su , Jianhua Qin , Xiangrong Pan , Zhan Zhou , Jingguo Li , Lufang Ma , Chaoliang Tan . 铂单原子功能化的二维Al-TCPP金属-有机框架纳米片用于增强光动力抗菌治疗. Acta Physico-Chimica Sinica, 2025, 41(5): 100046-. doi: 10.1016/j.actphy.2025.100046
7. [7]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
8. [8]
  Wenjie SHI , Fan LU , Mengwei CHEN , Jin WANG , Yingfeng HAN . Synthesis and host-guest properties of imidazolium-functionalized zirconium metal-organic cage. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 105-113. doi: 10.11862/CJIC.20240360
9. [9]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
10. [10]
  Yinwu Su , Xuanwen Zheng , Jianghui Du , Boda Li , Tao Wang , Zhiyan Huang . Green Synthesis of 1,3-Dibromoacetone Using Halogen Exchange Method: Recommending a Basic Organic Synthesis Teaching Experiment. University Chemistry, 2024, 39(5): 307-314. doi: 10.3866/PKU.DXHX202311092
11. [11]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
12. [12]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
13. [13]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
14. [14]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
15. [15]
  Mengzhen JIANG , Qian WANG , Junfeng BAI . Research progress on low-cost ligand-based metal-organic frameworks for carbon dioxide capture from industrial flue gas. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 1-13. doi: 10.11862/CJIC.20240355
16. [16]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
17. [17]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
18. [18]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
19. [19]
  Yanglin Jiang , Mingqing Chen , Min Liang , Yige Yao , Yan Zhang , Peng Wang , Jianping Zhang . Experimental and Theoretical Investigations of Solvent Polarity Effect on ESIPT Mechanism in 4′-N,N-diethylamino-3-hydroxybenzoflavone. Acta Physico-Chimica Sinica, 2025, 41(2): 100012-. doi: 10.3866/PKU.WHXB202309027
20. [20]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096

Get Citation

PDF

XML

Metrics

PDF Downloads(13)
Abstract views(1425)
HTML views(338)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142