Citation: LI Li. Preparation, Structures and Thermal Stabilities of Four Transition Metal Complexes Constructed by 3, 7-Di(3-pyridyl)-1, 5-dioxa-3, 7-diazacyclooctane Bipyridine Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(1): 121-130. doi: 10.11862/CJIC.2021.009 shu

Preparation, Structures and Thermal Stabilities of Four Transition Metal Complexes Constructed by 3, 7-Di(3-pyridyl)-1, 5-dioxa-3, 7-diazacyclooctane Bipyridine Ligand

LI Li ^,

School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou, Jiangsu 215009, China

Corresponding author: LI Li, leeleaa@163.com
Received Date: 11 February 2020
Revised Date: 27 October 2020

Figures(7)

Four transition metal complexes, [Co(NO₃) (H₂O)₂(L)₂]NO₃ (1), [Co₂Cl₄(L)₂] ·CH₂Cl₂ (2), [Cd₂(AcO)₄(L)₂] ·4CH₃OH (3) and[Cd₂(NO₃)₂(CH₃OH)₂(H2O)₂(L)2](NO₃)₂·2H₂O (4), were synthesized by employing a clamplike bipyridine ligand 3, 7-di(3-pyridyl)-1, 5-dioxa-3, 7-diazacyclooctane (L). Single-crystal X-ray analysis reveals that complex 1 is mononuclear structure; 2 is macrocyclic dimer; wheras 3 and 4 are rectangular dinuclear structures. The ligand molecules in these complexes has shown three types of coordination mode including mono-dentate, trans-bridge and cis-bridge. All of the complexes were also characterized by elemental analysis, IR, thermal stabilities and singlecrystal structure analysis.CCDC: 940778, 1; 915840, 2; 1446573, 3; 1446574, 4.
- cobalt,
- cadmium,
- 3, 7-di(3-pyridyl)-1, 5-dioxa-3, 7-diazacyclooctane,
- bipyridine,
- crystal structure
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