Citation: XU Jun-Ge, HONG Jun-Xian, HU Die. Composite Catalyst α-(Fe, Cu)OOH/RGO: Synthesis, Characterization and Removal of Ciprofloxacin Synergized with H₂O₂ under Visible Light[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(1): 55-64. doi: 10.11862/CJIC.2021.008 shu

Composite Catalyst α-(Fe, Cu)OOH/RGO: Synthesis, Characterization and Removal of Ciprofloxacin Synergized with H₂O₂ under Visible Light

College of Civil Engineering, Fuzhou University, Fuzhou 350116, China

Corresponding author: XU Jun-Ge, xujunge@163.com
Received Date: 15 June 2020
Revised Date: 17 September 2020

Figures(14)

The composite α-(Fe, Cu)OOH/RGO was synthesized via one-step reflux method. The as-obtained catalyst was analyzed by means of X-ray powder diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy and other characterization methods. With 30 mg·L^-1 ciprofloxacin (CIP) as the target pollutant, the effect of the catalyst obtained under different synthesis conditions on the removal of CIP by H₂O₂ under visible light was investigated. The results show that α-(Fe, Cu)OOH nanorods were grown in situ on two-dimensional graphene sheets. The visible light absorption edge of α-(Fe, Cu)OOH/RGO composite material was red-shifted and the band gap was changed from 2.02 to 1.76 eV. Graphene composite could not only enhance the adsorption capacity of pollutants, but also accelerate the separation and transfer rate of photogenerated electrons, as well as improve the efficiency of electron conduction in the reaction system. The best catalytic performance was gained when the composite content (mass fraction) of graphene was 1%. The CIP was completely removed after 120 min when the addition of catalyst was 0.40 g·L^-1 and the concentration of H₂O₂ was 0.10 mol·L^-1. The removal efficiency of CIP reached to 90% even after fivetime reuse, which indicates that the catalyst has strong catalytic activity and good stability.
- α-(Fe, Cu)OOH/RGO,
- graphene composite,
- photo-Fenton reaction,
- ciprofloxacin
1. [1]
  Mirzazadeh H, Lashanizadegan M. J. Serb. Chem. Soc., 2018, 83(2):221-236
2. [2]
  Zhou Q X, Wang M G, Tong Y Y, Wang H Y, Zhou X Q, Sheng X Y, Sun Y, Chen C M. Ecotoxicol. Environ. Saf., 2019, 182:109472 doi: 10.1016/j.ecoenv.2019.109472
3. [3]
  Saroyan H, Ntagiou D, Samanidou V, Deliyanni E. Chemosphere, 2019, 225:524-534 doi: 10.1016/j.chemosphere.2019.02.200
4. [4]
  Nawaz M, Moztahida M, Kim J, Shahzad A, Jang J, Miran W, Lee D S. Carbohydr. Polym., 2018, 199:109-118 doi: 10.1016/j.carbpol.2018.07.007
5. [5]
  Saroyan H, Ntagiou D, Rekos K, Deliyanni E. Appl. Sci.-Basel, 2019, 9(10):2167 doi: 10.3390/app9102167
6. [6]
  Israr M, Iqbal J, Arshad A, Aisida S O, Ahmad I. J. Phys. Chem. Solids, 2020, 140:109333 doi: 10.1016/j.jpcs.2020.109333
7. [7]
  Suwanchawalit C, Somjit V. Dig. J. Nanomater. Biostruct., 2015, 10(3):769-777
8. [8]
  Xu J G, Li Y Q, Yuan B L, Shen C H, Fu M L, Cui H J, Sun W J. Chem. Eng. J., 2016, 291:174-183 doi: 10.1016/j.cej.2016.01.059
9. [9]
  Krehula S, Ristić M, Petrović Ž, Mitar I, Musić S. J. Alloys Compd., 2019, 802:290-300 doi: 10.1016/j.jallcom.2019.06.133
10. [10]
  Nishida N, Amagasa S, Kobayashi Y, Yamada Y. J. Nanopart. Res., 2018, 20(7):181 doi: 10.1007/s11051-018-4275-6
11. [11]
  Kim J H, Kaneko H, Minegishi T, Kubota J, Domen K, Lee J S. ChemSusChem, 2016, 9(1):61-66 doi: 10.1002/cssc.201501401
12. [12]
  Wang Y, TianN H L, Yu Y G, Hu C Z. Chemosphere, 2018, 208:931-941 doi: 10.1016/j.chemosphere.2018.06.007
13. [13]
  Zhang Y X, Cheng Y X, Chen N N, Zhou Y Y, Li B Y, Gu W, Shi X H, Xian Y Z. J. Colloid Interface Sci., 2014, 421:85-92 doi: 10.1016/j.jcis.2014.01.022
14. [14]
  Zubir N A, Zhang X W, Yacou C, Da Costa J C D. Sci. Adv. Mater., 2014, 6(7):1382-1388 doi: 10.1166/sam.2014.1812
15. [15]
  Chong S, Zhang G M, Liu Y C, Zhang N, Huang G T, Wang H C. Desalin. Water Treat., 2017, 84:255-261 doi: 10.5004/dwt.2017.21192
16. [16]
  Feng Y, Yao T J, Yang Y, Zheng F R, Chen P, Wu J, Xin B F. ChemistrySelect, 2018, 3(31):9062-9070 doi: 10.1002/slct.201801840
17. [17]
  WANG Y Y, ZHAO H Y, HOU Z Y. Chem. J. Chinese Universities, 2018, 39(8):1750-1758
18. [18]
  Hummers W S, Offeman R E. J. Am. Chem. Soc., 1958, 80(6):1339 doi: 10.1021/ja01539a017
19. [19]
  Fu D D, He Z Q, Su S S, Xu B, Liu Y L, Zhao Y P. J. Colloid Interface Sci., 2017, 505:105-114 doi: 10.1016/j.jcis.2017.05.091
20. [20]
  Tian J J, Na W, Wang H, Gao W G. J. Cent. South Univ., 2014, 21(2):482-486 doi: 10.1007/s11771-014-1964-x
21. [21]
  Krehula S, Krehula L K, Musić S. J. Alloys Compd., 2013, 581:335-343 doi: 10.1016/j.jallcom.2013.07.076
22. [22]
  Andjelkovic I, Tran D N H, Kabiri S, Azari S, Markovic M, Losic D. ACS Appl. Mater. Interfaces, 2015, 7(18):9758-9766 doi: 10.1021/acsami.5b01624
23. [23]
  Pradhan G K, Padhi D K, Parida K M. ACS Appl. Mater. Interfaces, 2013, 5(18):9101-9110 doi: 10.1021/am402487h
24. [24]
  Padhi D K, Parida K. J. Mater. Chem. A, 2014, 2(26):10300-10312 doi: 10.1039/C4TA00931B
25. [25]
  Xu T, Hu J, Yang Y, Que W X, Yin X T, Wu H J, Chen L X. J. Mater. Sci. Mater. Electron., 2018, 29(6):4888-4894 doi: 10.1007/s10854-017-8447-4
26. [26]
  Nie Y L, Hu C, Qu J H, Zhao X. Appl. Catal. B, 2009, 87(1/2):30-36
27. [27]
  Zhang R, You H, Wu D H. Desalin. Water Treat., 2016, 57(26):12010-12018 doi: 10.1080/19443994.2015.1048535
28. [28]
  Yang Y, Ratner M A, Schatz G C. J. Phys. Chem. C, 2014, 118(50):29196-29208 doi: 10.1021/jp5052672
29. [29]
  YAO Z P, CHEN C J, WAGN J K, XIA Q X, LI C X, JIANG Z H. Chinese J. Inorg. Chem., 2017, 33(10):1797-1804 doi: 10.11862/CJIC.2017.197
30. [30]
  Zhang X F, Zhang B Y, Liu S S, Kang H W, Kong W Q, Zhang S R, Shen Y, Yang B C. Appl. Surf. Sci., 2018, 436:974-980 doi: 10.1016/j.apsusc.2017.12.078
31. [31]
  Kuang L Y, Liu Y Y, Fu D D, Zhao Y P. J. Colloid Interface Sci., 2017, 490:259-269 doi: 10.1016/j.jcis.2016.11.071
32. [32]
  Han S C, Hu L F, Liang Z Q, Wageh S, Al-Ghamdi A A, Chen Y S, Fang X S. Adv. Funct. Mater., 2014, 24(36):5719-5727 doi: 10.1002/adfm.201401279
33. [33]
  Wang Y, Tian H L, Yu Y G, Hu C Z. Chemosphere, 2018, 208:931-941 doi: 10.1016/j.chemosphere.2018.06.007
34. [34]
  Zhang W, Hu C, Tan J, Fan Z J, Chi F L, Sun Y X, Ran S L, Liu X G, Lv Y H. NANO, 2016, 11(6):109-117
35. [35]
  Lin F J, Yuan M, Chen Y, Huang Y P, Lian J B, Qiu J X, Xu H, Li H M, Yuan S Q, Zhao Y, Cao S S. Electrochim. Acta, 2019, 320:UNSP 134580 doi: 10.1016/j.electacta.2019.134580
36. [36]
  Peng F M, Luo T, Qiu L G, Yuan Y P. Mater. Res. Bull., 2013, 48(6):2180-2185 doi: 10.1016/j.materresbull.2013.02.056
37. [37]
  Zhang X X, Li R P, Jia M K, Wang S L, Huang Y P, Chen C C. Chem. Eng. J., 2015, 274:290-297 doi: 10.1016/j.cej.2015.03.077
1. [1]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
2. [2]
  Yujia LI , Tianyu WANG , Fuxue WANG , Chongchen WANG . Direct Z-scheme MIL-100(Fe)/BiOBr heterojunctions: Construction and photo-Fenton degradation for sulfamethoxazole. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 481-495. doi: 10.11862/CJIC.20230314
3. [3]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
4. [4]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
5. [5]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
6. [6]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
7. [7]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
8. [8]
  Yuan ZHU , Xiaoda ZHANG , Shasha WANG , Peng WEI , Tao YI . Conditionally restricted fluorescent probe for Fe³⁺ and Cu²⁺ based on the naphthalimide structure. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 183-192. doi: 10.11862/CJIC.20240232
9. [9]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
10. [10]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
11. [11]
  Tianqi Bai , Kun Huang , Fachen Liu , Ruochen Shi , Wencai Ren , Songfeng Pei , Peng Gao , Zhongfan Liu . 石墨烯厚膜热扩散系数与微观结构的关系. Acta Physico-Chimica Sinica, 2025, 41(3): 2404024-. doi: 10.3866/PKU.WHXB202404024
12. [12]
  Jiahao Lu , Xin Ming , Yingjun Liu , Yuanyuan Hao , Peijuan Zhang , Songhan Shi , Yi Mao , Yue Yu , Shengying Cai , Zhen Xu , Chao Gao . 基于稳态电热法的石墨烯膜导热系数的精确可靠测量. Acta Physico-Chimica Sinica, 2025, 41(5): 100045-. doi: 10.1016/j.actphy.2025.100045
13. [13]
  Rui Gao , Ying Zhou , Yifan Hu , Siyuan Chen , Shouhong Xu , Qianfu Luo , Wenqing Zhang . Design, Synthesis and Performance Experiment of Novel Photoswitchable Hybrid Tetraarylethenes. University Chemistry, 2024, 39(5): 125-133. doi: 10.3866/PKU.DXHX202310050
14. [14]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
15. [15]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
16. [16]
  Yongpo Zhang , Xinfeng Li , Yafei Song , Mengyao Sun , Congcong Yin , Chunyan Gao , Jinzhong Zhao . Synthesis of Chlorine-Bridged Binuclear Cu(I) Complexes Based on Conjugation-Driven Cu(II) Oxidized Secondary Amines. University Chemistry, 2024, 39(5): 44-51. doi: 10.3866/PKU.DXHX202309092
17. [17]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
18. [18]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
19. [19]
  Fangfang WANG , Jiaqi CHEN , Weiyin SUN . CuBi@Cu-MOF composite catalysts for electrocatalytic CO₂ reduction to HCOOH. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 97-104. doi: 10.11862/CJIC.20240350
20. [20]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252

Get Citation

PDF

XML

Metrics

PDF Downloads(8)
Abstract views(1523)
HTML views(293)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Composite Catalyst α-(Fe, Cu)OOH/RGO: Synthesis, Characterization and Removal of Ciprofloxacin Synergized with H2O2 under Visible Light

Metrics

通讯作者: 陈斌, bchen63@163.com

Composite Catalyst α-(Fe, Cu)OOH/RGO: Synthesis, Characterization and Removal of Ciprofloxacin Synergized with H₂O₂ under Visible Light