Citation: LIU Heng-Fa, XIE Yu, LIU Qi, CHENG Gao, SUN Ming, YU Lin. Preparation, Characterization and Catalytic Activity of 3D Heterogeneous α-MnO₂@Co₃O₄ Material[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(1): 47-54. doi: 10.11862/CJIC.2021.003 shu

Preparation, Characterization and Catalytic Activity of 3D Heterogeneous α-MnO₂@Co₃O₄ Material

School of Chemical Engineering and Light Industry, Key Laboratory of Clean Chemistry Technology of Guangdong Regular Higher Education, Guangzhou Key Laboratory of Clean Transportation Energy Chemistry, Guangdong University of Technology, Guangzhou 510006, China

Corresponding author: SUN Ming, sunmgz@gdut.edu.cn
Received Date: 8 June 2020
Revised Date: 21 September 2020

Figures(6)

The α-MnO₂ nanowires were used as the substrates for the in-situ growth of ZIF-67, and then converted into 3D α-MnO₂@Co₃O₄ heterogeneous material by calcination, and its catalytic combustion of toluene performance was studied. The results show that Co₃O₄ nanoparticles with a particle size of about 12 nm grew uniformly on the outer surface of MnO₂ nanowires, forming a heterogeneous interface. The composite material has better low-temperature reducibility and possesses more surface-active oxygen species. Compared with α-MnO₂ nanowires, α-MnO₂@Co₃O₄ exhibited more excellent toluene catalytic combustion performance with an ignition temperature (10% conversion) T₁₀ of 202℃ and a complete combustion temperature (90% conversion) T₉₀ of 235℃.
- manganese oxide,
- heterogeneous structure,
- controlling synthesis,
- catalytic combustion
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Preparation, Characterization and Catalytic Activity of 3D Heterogeneous α-MnO₂@Co₃O₄ Material