Citation: ZHOU Meng-Xue, REN Ning, ZHANG Jian-Jun. Four Rare Earth Complexes with Chlorinated Carboxylic Acids and Bipyridine Ligands: Crystal Structures, Thermal Analysis and Luminescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(12): 2349-2358. doi: 10.11862/CJIC.2020.258 shu

Four Rare Earth Complexes with Chlorinated Carboxylic Acids and Bipyridine Ligands: Crystal Structures, Thermal Analysis and Luminescence Properties

ZHOU Meng-Xue ^1,2 ,
REN Ning ^3,, ,
ZHANG Jian-Jun ^1,2,,

1.
Testing and Analysis Center, Hebei Normal University, Shijiazhuang 050024, China
2.
College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050024, China
3.
College of Chemical Engineering & Material, Hebei Key Laboratory of Heterocyclic Compounds, Handan University, Handan, Hebei 056005, China

Corresponding author: REN Ning, ningren9@163.com ZHANG Jian-Jun, jjzhang6@126.com
Received Date: 29 April 2020
Revised Date: 21 September 2020

Figures(10)

Four new complexes were successfully synthesized by solvothermal method or conventional solution method, namely [Ln₂(5, 5'-DM-2, 2'-bipy)₂(3, 4-DClBA)₆(H₂O)(C₂H₅OH)] (Ln=Sm (1), Eu (2)) and [Ln(5, 5'-DM-2, 2'-bipy) (3, 5-DClBA)₃]₂ (Ln=Sm (3), Eu (4); 3, 4-HDClBA=3, 4-dichlorobenzoic acid, 3, 5-HDClBA=3, 5-dichlorobenzoic acid, 5, 5'-DM-2, 2'-bipy=5, 5'-dimethyl-2, 2'-bipyridine). Complexes 1 and 2 are isostructure and each metal center is eight-coordinated forming a distorted square antiprismatic. Complexes 1 and 2 are connected to form 2D supermolecular structure by C-H…Cl hydrogen bonding and π-π interactions. The geometry of complex 3 is a nine coordinated distorted monocapped square antiprismatic, and the two-dimensional supramolecular structure is formed by different π-π stacking interactions between molecules. Thermogravimetric-infrared combined technology revealed the thermal stability and thermal decomposition mechanism of complexes 1~4. The fluorescence and lifetime of complexes 2 and 4 were studied. The results showed that both complexes could emit the characteristic fluorescence of Eu³⁺ ions. CCDC: 1939324, 1; 1939325, 2; 1939326, 3.
- rare earth complexes,
- synthesis,
- crystal structures,
- thermal analysis,
- luminescent properties
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