Citation: SUN Zhen-Zhou, SUN Ling-Zhi, ZHU Ning, KUANG Xiao-Nan, YANG Yu-Ping, LI Zhong-Feng, JIN Qiong-Hua, ZHANG Jiang-Wei. Syntheses, Crystal Structures and Terahertz Spectra of Two Copper(Ⅰ) Complexes Based on Mixed Diimines and Diphosphine Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(12): 2261-2270. doi: 10.11862/CJIC.2020.251 shu

Syntheses, Crystal Structures and Terahertz Spectra of Two Copper(Ⅰ) Complexes Based on Mixed Diimines and Diphosphine Ligands

1.
Department of Chemistry, Capital Normal University, Beijing 100048, China
2.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
3.
School of Science, Minzu University of China, Beijing 100081, China
4.
Dalian National Laboratory for Clean Energy & State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences(CAS), Dalian, Liaoning 116023, China

Corresponding author: JIN Qiong-Hua, jinqh@cnu.edu.cn ZHANG Jiang-Wei, jwzhang@dicp.ac.cn
Received Date: 30 March 2020
Revised Date: 8 September 2020

Figures(9)

Two copper (Ⅰ) complexes with diimine and diphosphine ligands, [Cu₂(Dpq)₂(dppBz)₂] (SCN)₂·0.5Dpq·3CH₃OH (1) and [Cu₂(Dppz)₂(dppb)₂](BF₄)₂·2CH₃OH·2H₂O (2) (Dppz=dipyrido[3, 2-a:2', 3'-c]phenazine, Dpq=pyrazino[2, 3-f]^{[1, 10]}phenanthroline, dppBz=1, 2-bis(diphenylphosphino)benzene, dppb=1, 3-bis(diphenylphosphine)butane), were prepared in the mixed solution of methanol and dichloromethane. The structure of these two complexes were determined by X-ray single crystal diffraction and characterized by elemental analysis, NMR, FT-IR, UV-Vis absorption spectrum, fluorescence spectrum and terahertz time-domain spectroscopy (THz-TDS). The unit cell of 1 contains two independent metal centers and half uncoordinated Dpq molecule, and similar structures are very rare. However, complex 2 are novel binuclear structure formed by the bisphosphine ligand. Through the analysis of intermolecular forces, 1 is a three-dimensional stacked structure, which contains unique C-S…π interactions. But 2 forms one-dimensional infinite chain through C-H…π and π…π. The existence of a large number of weak interactions makes the complexes more stable. The emission spectra showed that the peak of complex 1 was at 578 nm, however, complex 2 emitted green light (at 547 nm). The sharp peak at 1.2 THz in THz-TDS spectrum of complex 2 is caused by the interactions of C-H…F.CCDC: 1991845, 1; 1991844, 2.
- copper (Ⅰ) complexes,
- fluorescence,
- intermolecular force,
- terahertz time-domain spectroscopy
1. [1]
  Xu L L, Mou F Z, Gong H T, et al. Chem. Soc. Rev., 2017, 46(22):6905-6926 doi: 10.1039/C7CS00516D
2. [2]
  Ho C L, Yu Z Q, Wong W Y. Chem. Soc. Rev., 2016, 45(19):5264-5295 doi: 10.1039/C6CS00226A
3. [3]
  ZENG Xue-Hua, LUO Yan-Sheng, CHEN Jing-Lin, et al. Chinese J. Inorg. Chem., 2017, 33(10):1810-1816
4. [4]
  MAO Pan-Dong, HAN Xue-Feng, WU Wei-Na, et al. Chinese J. Inorg. Chem., 2016, 32(1):161-166
5. [5]
  Ahamad M N, Shahid M, Ahmad M, et al. ACS Omega, 2019, 4:7738-7749 doi: 10.1021/acsomega.9b00715
6. [6]
  Nicholls T P, Caporale C, Massi M, et al. Dalton Trans., 2019, 48(21):7290-7301 doi: 10.1039/C8DT04116D
7. [7]
  Kubicek V, Bohmova Z, Sevcikova R, et al. Inorg. Chem., 2018, 57:3061-3072 doi: 10.1021/acs.inorgchem.7b02929
8. [8]
  Romanov A S, Yang L, Jones S T E, et al. Chem. Mater., 2019, 31(10):3613-3623 doi: 10.1021/acs.chemmater.8b05112
9. [9]
  Liang D, Chen X L, Liao J Z, et al. Inorg. Chem., 2016, 55:7467-7475 doi: 10.1021/acs.inorgchem.6b00763
10. [10]
  Hasegawa T, Kobayashi A, Ohara H, et al. Inorg. Chem., 2017, 56:4928-4936 doi: 10.1021/acs.inorgchem.6b03122
11. [11]
  Hamze R, Peltier J L, Sylvinson D, et al. Science, 2019, 363:601-606 doi: 10.1126/science.aav2865
12. [12]
  Zhang Y, Schulz M, Wächtler M, et al. Coord. Chem. Rev., 2018, 356:127-146 doi: 10.1016/j.ccr.2017.10.016
13. [13]
  McIntosh A I, Yang B, Goldup S M, et al. Chem. Soc. Rev., 2012, 41:2072-2082 doi: 10.1039/C1CS15277G
14. [14]
  Zaczek A J, Korter T M. Cryst. Growth Des., 2017, 17:4458-4466 doi: 10.1021/acs.cgd.7b00854
15. [15]
  Ferguson B, Zhang X C. Nat. Mater., 2002, 1:26-33 doi: 10.1038/nmat708
16. [16]
  Kampfrath T, Tanaka K, Nelson K A. Nat. Photonics, 2013, 7:680-690 doi: 10.1038/nphoton.2013.184
17. [17]
  Sheldrick G M. SHELXS-97 and SHELXL-97, Software for Crystal Structure Analysis, Siemens Analytical X-ray Instru-ments Inc., Wisconsin, Madison, USA, 1997.
18. [18]
  Sheldrick G M. SHELXTL NT Version 5.1, Program for Solu-tion and Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
19. [19]
  Spek A L. J. Appl. Crystallogr., 2003, 36:7 doi: 10.1107/S0021889802022112
20. [20]
  Brown C M, Carta V, Wolf M O. Chem. Mater., 2018, 30:5786-5795 doi: 10.1021/acs.chemmater.8b02821
21. [21]
  Kaeser A, Mohankumar M, Mohanraj J, et al. Inorg. Chem., 2013, 52:12140-12151 doi: 10.1021/ic4020042
22. [22]
  Jia J H, Chen X L, Liao J Z, et al. Dalton Trans., 2019, 48:1418 doi: 10.1039/C8DT03452D
23. [23]
  Hou R B, Huang T H, Wang X J, et al. Dalton Trans., 2011, 40:7551-7558 doi: 10.1039/c1dt10358j
24. [24]
  Rahaman S A, Hossain M S, Baburaj S, et al. Org. Biomol. Chem., 2019, 17:5153-5160 doi: 10.1039/C9OB00781D
25. [25]
  Xu S, Liu M, Yang Y P, et al. Polyhedron, 2015, 87:293-301 doi: 10.1016/j.poly.2014.11.022
1. [1]
  Shuang Meng , Haixin Long , Zhou Zhou , Meizhu Rong . Inorganic Chemistry Curriculum Design and Implementation of Based on “Stepped-Task Driven + Multi-Dimensional Output” Model: A Case Study on Intermolecular Forces. University Chemistry, 2024, 39(3): 122-131. doi: 10.3866/PKU.DXHX202309008
2. [2]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
3. [3]
  Zehua Zhang , Haitao Yu , Yanyu Qi . 多重共振TADF分子的设计策略. Acta Physico-Chimica Sinica, 2025, 41(1): 2309042-. doi: 10.3866/PKU.WHXB202309042
4. [4]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
5. [5]
  Feng Lu , Tao Wang , Qi Wang . Preparation and Characterization of Water-Soluble Silver Nanoclusters: A New Design and Teaching Practice in Materials Chemistry Experiment. University Chemistry, 2025, 40(4): 375-381. doi: 10.12461/PKU.DXHX202406005
6. [6]
  YanYuan Jia , Rong Rong , Jie Liu , Jing Guo , GuoYu Jiang , Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035
7. [7]
  Qin Li , Kexin Yang , Qinglin Yang , Xiangjin Zhu , Xiaole Han , Tao Huang . Illuminating Chlorophyll: Innovative Chemistry Popularization Experiment. University Chemistry, 2024, 39(9): 359-368. doi: 10.3866/PKU.DXHX202309059
8. [8]
  Qin Hou , Jiayi Hou , Aiju Shi , Xingliang Xu , Yuanhong Zhang , Yijing Li , Juying Hou , Yanfang Wang . Preparation of Cuprous Iodide Coordination Polymer and Fluorescent Detection of Nitrite: A Comprehensive Chemical Design Experiment. University Chemistry, 2024, 39(8): 221-229. doi: 10.3866/PKU.DXHX202312056
9. [9]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
10. [10]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
11. [11]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098
12. [12]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
13. [13]
  Dongdong YANG , Jianhua XUE , Yuanyu YANG , Meixia WU , Yujia BAI , Zongxuan WANG , Qi MA . Design and synthesis of two coordination polymers for the rapid detection of ciprofloxacin based on triphenylpolycarboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2466-2474. doi: 10.11862/CJIC.20240266
14. [14]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
15. [15]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
16. [16]
  Chun-Lin Sun , Yaole Jiang , Yu Chen , Rongjing Guo , Yongwen Shen , Xinping Hui , Baoxin Zhang , Xiaobo Pan . Construction, Performance Testing, and Practical Applications of a Home-Made Open Fluorescence Spectrometer. University Chemistry, 2024, 39(5): 287-295. doi: 10.3866/PKU.DXHX202311096
17. [17]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
18. [18]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
19. [19]
  Cheng Zheng , Shiying Zheng , Yanping Zhang , Shoutian Zheng , Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, 2024, 39(7): 322-329. doi: 10.3866/PKU.DXHX202310131
20. [20]
  Tingyu Zhu , Hui Zhang , Wenwei Zhang . Exploration and Practice of Ideological and Political Education in the Course of Experiments on Chemical Functional Molecules: Synthesis and Catalytic Performance Study of Chiral Mn(III)Cl-Salen Complex. University Chemistry, 2024, 39(4): 75-80. doi: 10.3866/PKU.DXHX202311011

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(1813)
HTML views(537)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142