Citation: ZHANG Chun-Hua, WANG Ying, TANG Hai-Jun, DENG Yi-Fang, CHEN Man-Sheng. Syntheses, Crystal Structures and Properties of Two Zn(Ⅱ) Complexes Constructed from Flexible 1, 5-Bis(imidazol-2-methyl)pentane Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(11): 2197-2204. doi: 10.11862/CJIC.2020.250 shu

Syntheses, Crystal Structures and Properties of Two Zn(Ⅱ) Complexes Constructed from Flexible 1, 5-Bis(imidazol-2-methyl)pentane Ligand

Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, College of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008, China

Corresponding author: CHEN Man-Sheng, cmsniu@163.com
Received Date: 14 June 2020
Revised Date: 4 September 2020

Figures(5)

Hydrothermal assembly reactions of Zn(NO₃)₂·6H₂O, 1, 5-bis-(2-methyl-imidazol)pentane (BMIP) and 5-hydroxyisophthalic acid (5-OHH₂IP) or 5-bromoisophthalic acid (5-BrH₂IP) ligands resulted in the formation of complexes[Zn(5-OHIP)(BMIP)]_n (1) and[Zn(5-BrIP)(BMIP)]_n (2), respectively. The resulting complexes were characterized by IR spectrum, elemental analysis and single-crystal X-ray diffraction. Crystal structure analysis shows that complex 1 crystallizes in the monoclinic system, space group P2₁/n with β=101.363(10)°. Complex 1 displays a two-dimensional layer net constructed by 5-hydroxyisophthalic acid and 1, 5-bis-(2-methyl-imidazol)pentane. For 2, 5-bromoisophthalic acid and 1, 5-bis-(2-methyl-imidazol)pentane link Zinc ion into a two-dimensional layers, which are pillared by the other BMIP ligands to result in the three-dimensional framework from another direction. Finally, it exhibits a fascinating three-fold interpenetrating net with dmp topology. Both complexes exhibit a strong photolu-minescence in the solid state at room temperature. Moreover, two complexes present good photocatalytic activities in methylene blue (MB) degradation reactions.CCDC: 1502156, 1; 1502157, 2.
- 1, 5-bis(2-methy-imidazolyl)pentane,
- crystal structure,
- fluorescence,
- degradation
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