Citation: DING Qi-Hui, LIU Yao-Yao, LI Lu-Chao, HUANG Yong-Qing, ZHAO Yue. Syntheses, Structures and Optical Band Gaps of Three Zn(Ⅱ)/Co(Ⅱ) Coordination Polymers[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(11): 2014-2022. doi: 10.11862/CJIC.2020.245 shu

Syntheses, Structures and Optical Band Gaps of Three Zn(Ⅱ)/Co(Ⅱ) Coordination Polymers

1.
Key Laboratory of Mining Disaster Prevention and Control Co-founded by Shandong Province and the Ministry of Science and Technology, College of Chemical and Biological Engineering, Shandong University of Science and Technology, Qingdao, Shandong 266590, China
2.
State Key Laboratory of Coordination Chemistry, School of Chemical and Chemical Engineering, Nanjing 210023, China

Corresponding author: HUANG Yong-Qing, yqhuangskd@163.com ZHAO Yue, zhaoyue@nju.edu.cn
Received Date: 7 May 2020
Revised Date: 14 September 2020

Figures(11)

Three new coordination polymers with formulas[Zn(L1)(L2)_0.5Cl]_n (1), [Co(L1)(L2)_0.5Cl]_n (2) and {[Zn(L1) (L3)]ClO₄·1.7H₂O}_n (3) have been prepared via the combination of zwitterionic carboxylic ligand with Zn(Ⅱ) and Co (Ⅱ) salts under the participation of two bridging imidazole-based isomers, where L1, L2 and L3 are 4-carboxy-1-(4-carboxybenzyl)-pyridinium, 1, 4-bis(imidazole-1-ylmethyl)benzene and 1, 3-bis(imidazole-1-ylmethyl)benzene, respectively. Complexes 1 and 2 are isostructural and feature an undulated 2D herringbone layer structure with (6, 3) topology, exhibiting a rare 2D→3D inclined polycatenated structure. Compared with 1 and 2, complex 3 displays 1D catenated chain structure, which are further assembled into 2D layer via abundant π-π interactions. It is noteworthy that 1~3 can all be considered as consisting of 1D[M(L1)]_n chains and bridging bis-imidazole-based ligands. For 1 and 2, the 1D[M(L1)]_n chains take helical form and bridging L2 ligands adopting Z-shape. In contrast, the 1D[M(L1)]_n chains in 3 exhibit zigzag form and bridging L3 ligands having C-configuration. The results reveal that different N-donor ancillary ligands and anions have a subtle effect on the final structures. The study of optical band gaps showed that the band gaps of 1~3 were 2.96, 1.72 and 3.16 eV, respectively, which indicates that 1~3 have properties of potential wide-band-gap semiconductors.CCDC: 1973985, 1; 1973986, 2; 1973987, 3.
- Zn(Ⅱ) complex,
- Co(Ⅱ) complex,
- coordination polymer,
- crystal structure,
- optical band gap
1. [1]
  Hong X J, Song C L, Yang Y, et al. ACS Nano, 2019, 13:1923-1931
2. [2]
  Noori Y, Akhbari K. RSC Adv., 2017, 7:1782-1808 doi: 10.1039/C6RA24958B
3. [3]
  Pan M, Su C Y. CrystEngComm, 2014, 16:7847-7859 doi: 10.1039/C4CE00616J
4. [4]
  Calbo J, Golomb M J, Walsh A. J. Mater. Chem. A, 2019, 7:16571-16597 doi: 10.1039/C9TA04680A
5. [5]
  Huang Y Q, Chen H Y, Wang Y, et al. RSC Adv., 2018, 8:21444-21450 doi: 10.1039/C8RA02809E
6. [6]
  Amarajothi D, Abdullah M A, Hermenegildo G. ACS Catal., 2017, 7:2896-2919 doi: 10.1021/acscatal.6b03386
7. [7]
  Lustig W P, Mukherjee S, Rudd N D, et al. Chem. Soc. Rev., 2017, 46:3242-3285 doi: 10.1039/C6CS00930A
8. [8]
  Mingabudinova L R, Vinogradov Ⅴ Ⅴ, Milichko Ⅴ A, et al. Chem. Soc. Rev., 2016, 45:5408-5431 doi: 10.1039/C6CS00395H
9. [9]
  Yu S, Zhang Q H, Hu H C, et al. RSC Adv., 2020, 10:11831-11835 doi: 10.1039/D0RA01604G
10. [10]
  Usman M, Mendiratta S, Lu K L. Adv. Mater., 2017, 29:1605071 doi: 10.1002/adma.201605071
11. [11]
  Alvaro M, Carbonell E, Ferrer B, et al. Chem. Eur. J., 2007, 13:5106-5112 doi: 10.1002/chem.200601003
12. [12]
  Choi J H, Choi Y J, Lee J W, et al. Phys. Chem. Chem. Phys., 2009, 11:628-631 doi: 10.1039/B816668D
13. [13]
  Li H L, Eddaoudi M, O'Keeffe M, et al. Nature, 1999, 402:276-279 doi: 10.1038/46248
14. [14]
  Hosseini M W. Acc. Chem. Res., 2005, 38:313-323 doi: 10.1021/ar0401799
15. [15]
  Hosseini M W. CrystEngComm, 2004, 6:318-322 doi: 10.1039/b412125m
16. [16]
  Bello L, Quintero M, Mora A J, et al. CrystEngComm, 2015, 17:5921-5931 doi: 10.1039/C5CE00646E
17. [17]
  Huang Y Q, Shen Z L, Okamura T, et al. Dalton Trans., 2008:204-213
18. [18]
  Huang Y Q, Zhao W, Chen J G, et al. Z. Anorg. Allg. Chem., 2012, 638:679-682 doi: 10.1002/zaac.201100310
19. [19]
  Huang Y Q, Wan Y, Cheng H D, et al. Chin. J. Struct. Chem., 2014, 33:928-934
20. [20]
  Liao W M, Zeng Q, He Y H, et al. J. Solid. State Chem., 2019, 277:448-453 doi: 10.1016/j.jssc.2019.07.003
21. [21]
  Bhattacharya B, Ghoshal D. CrystEngComm, 2015, 17:8388-8413 doi: 10.1039/C5CE01246E
22. [22]
  Zhang J Y, Wang K, Li X B, et al. Inorg. Chem., 2014, 53:9306-9314 doi: 10.1021/ic5014279
23. [23]
  Qu Y J, Li J, Duan S E. J. Mol. Struct., 2018, 1166:155-158 doi: 10.1016/j.molstruc.2018.04.029
24. [24]
  Kan W Q, Ma J F, Liu Y Y, et al. CrystEngComm, 2012, 14:2316-2326 doi: 10.1039/c2ce06176g
25. [25]
  Huang Y Q, Li Z G, Chen H Y, et al. CrystEngComm, 2017, 19:6686-6693 doi: 10.1039/C7CE01568B
26. [26]
  Huang Y Q, Chen H Y, Li Z G, et al. Inorg. Chim. Acta, 2017, 466:71-77 doi: 10.1016/j.ica.2017.05.039
27. [27]
  Ezuhara T, Endo K, Aoyama Y. J. Am. Chem. Soc., 1999, 121:3279-3283 doi: 10.1021/ja9819918
28. [28]
  Kong G Q, Wu C D. Cryst. Growth Des., 2010, 10:4590-4595 doi: 10.1021/cg100885e
29. [29]
  Xu G C, Ding Y J, Huang Y Q, et al. Microporous Mesopo-rous Mater., 2008, 113:511-522 doi: 10.1016/j.micromeso.2007.12.012
30. [30]
  Sheldrick G M. SHELX-97, An Integrated System for Solving Crystal Structures from Diffraction Data, University of Göttingen, Germany, 1997.
31. [31]
  Sheldrick G M. SHELX-97, An Integrated System for Refin-ing Crystal Structures from Diffraction Data, University of Göttingen, Germany, 1997.
32. [32]
  Sheldrick G M. SHELXTL, Version 6.10, Bruker AXS Inc., Madison, Wisconsin, USA, 2000.
33. [33]
  Lacroix P G, Averseng F, Malfant Ⅰ, et al. Inorg. Chim. Acta, 2004, 357:3825-3835 doi: 10.1016/j.ica.2004.03.004
34. [34]
  Batten S R, Robson R. Angew. Chem. Int. Ed., 1998, 37:1460-1494 doi: 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO;2-Z
35. [35]
  Wang R M, Zhang M H, Wang W, et al. Chin. J. Struct. Chem., 2016, 35:1714-1722
36. [36]
  Erer H, Yeşilel O Z, Arıcı M, et al. J. Solid State Chem., 2014, 210:261-266 doi: 10.1016/j.jssc.2013.11.036
37. [37]
  Huang Y Q, Wan Y, Chen H Y, et al. New J. Chem., 2016, 40:7587-7595 doi: 10.1039/C6NJ01231K
38. [38]
  Du P, Yang Y, Yang J, et al. Dalton Trans., 2013, 42:1567-1580 doi: 10.1039/C2DT31964K
39. [39]
  Ji W J, Zhai Q G, Li S N, et al. Inorg. Chem. Commun., 2012, 24:209-211 doi: 10.1016/j.inoche.2012.07.014
40. [40]
  Sippel P, Denysenko D, Loidl A, et al. Adv. Funct. Mater., 2014, 24:3885-3896 doi: 10.1002/adfm.201400083
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1.
沈阳化工大学材料科学与工程学院沈阳 110142