Citation: CHEN Shao-Kai, LI Xin, GUO Chen-Chen, WEI Yi-Xuan, YUAN Sai-Wei, SONG Hui-Hua. Chiral Discrimination Tyrosine Enantiomers Based on N-Acetyl-L-cysteine Modified ZnFe₂O₄@SiO₂ Nanoparticles[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(11): 2169-2178. doi: 10.11862/CJIC.2020.235 shu

Chiral Discrimination Tyrosine Enantiomers Based on N-Acetyl-L-cysteine Modified ZnFe₂O₄@SiO₂ Nanoparticles

College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang 050024, China

Corresponding author: SONG Hui-Hua, songhuihua@mail.hebtu.edu.cn
Received Date: 28 March 2020
Revised Date: 28 August 2020

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N-acetyl-L-cysteine (NALC) functionalized ZnFe₂O₄@SiO₂ (ZnFe₂O₄@SiO₂-NALC) was synthesized and exhibited simplicity, rapidity and high selectivity in the separation of chiral tyrosine (Tyr) enantiomers. The chiral nanocomposite of ZnFe₂O₄@SiO₂-NALC was characterized by X-ray powder diffraction (XRD), infrared spectroscopy (FT-IR), energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM) and vibrating sample magnetometer (VSM). This is the first synthesis of ZnFe₂O₄@SiO₂-NALC for chiral recognition. The proposed optical spectroscopic techniques (UV-Vis spectrum and fluorescence spectra) showed excellent enantiospecificity for Tyr enantiomers. Furthermore, the experimental parameters such as the Tyr concentration and the pH values were optimized.
- chiral recognition,
- ZnFe₂O₄@SiO₂-NALC,
- chiral nanoparticles,
- tyrosine
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Chiral Discrimination Tyrosine Enantiomers Based on N-Acetyl-L-cysteine Modified ZnFe₂O₄@SiO₂ Nanoparticles