Citation: YU Fan, HU Bing-Qian, XIONG Xin, LU Wang-Ting, LI Bao. Amorphous Cobalt Sulfide Derived From Metal-Organic Framework and Its Water Splitting Properties[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(10): 1873-1880. doi: 10.11862/CJIC.2020.222 shu

Amorphous Cobalt Sulfide Derived From Metal-Organic Framework and Its Water Splitting Properties

YU Fan ^1,, ,
HU Bing-Qian ¹ ,
XIONG Xin ¹ ,
LU Wang-Ting ¹ ,
LI Bao ^2,,

1.
Key Laboratory of Optoelectronic Chemical Materials and Devices(Ministry of Education), School of Chemical and Environmental Engineering, Jianghan University, Wuhan 430056, China
2.
School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China

Corresponding author: YU Fan, yufan0714@163.com LI Bao, libao@hust.edu.cn
Received Date: 29 March 2020
Revised Date: 28 August 2020

Figures(9)

Herein, we report the preparation of amorphous cobalt sulfide electrode materials using MOF as template and its application in electrocatalytic decomposition of water. Firstly, a new cobalt-based metal-organic framework was prepared by using nitrogen -containing system. Then, a series of amorphous cobalt sulfide samples were prepared by changing curing time, temperature and sulfur sources, such as sodium sulfide and thioacetamide. The materials were characterized by powder X-ray diffraction, scanning electron microscope, X-ray photoelectron spectroscopy and infrared spectra, and their structural characteristics were explained. The electrolysis performance of each sample was characterized in detail, and the structure-activity relationship of each system was established. Combined with various structural characterization and electrochemical performance tests, it was found that when the sulfuration temperature and sulfuration time were controlled to 60℃ and 6 h, respectively, the related samples exhibited the hydrogen evolution reaction and oxygen evolution reaction potential of 178 and 246 mV when the current density was 10 mA·cm^-2 in 1.0 mol·L^-1 KOH solution, along with the excellent durability. CCDC:2010582.
- metal-organic framework,
- cobalt sulfide,
- hydrogen energy,
- water electrolysis
1. [1]
  Amali A, Sun J, Xu Q.Chem.Commun., 2014, 50:1519-1522 doi: 10.1039/C3CC48112C
2. [2]
  TianX M, YaoS L, QiuC Q, et al.Inorg.Chem., 2020, 59:2803-2810 doi: 10.1021/acs.inorgchem.9b03152
3. [3]
  Cao X, Hong Y, Zhang N, et al.ACSCatal., 2018, 8:8273-8289
4. [4]
  Zhao Y Q, Jin B, Vasileff A, et al.J.Mater.Chem.A, 2019, 7:8117-8121 doi: 10.1039/C9TA01903K
5. [5]
  Yao S L, Liu S J, Tian X M, et al.Inorg.Chem., 2019, 58:3578-3581 doi: 10.1021/acs.inorgchem.8b03316
6. [6]
  Wang X D, Cao Y, Teng Y, et al.ACSAppl.Mater.Interfaces, 2017, 9:32812-32819 doi: 10.1021/acsami.7b10893
7. [7]
  Yao S L, Tian X M, Li L Q, et al.Chem. Asian J., 2019, 14:3648-3654 doi: 10.1002/asia.201900739
8. [8]
  Jiao Y, Zheng Y, Jaroniec M, et al.Chem.Soc.Rev., 2015, 44:2060-2086 doi: 10.1039/C4CS00470A
9. [9]
  Reier T, Oezaslan M, Strasser P.ACSCatal., 2012, 2:1765-1772 doi: 10.1021/acscatal.5b00494
10. [10]
  Wu Y Y, Li G D, Liu Y P, et al.Adv.Funct.Mater., 2016, 26:4839-4847 doi: 10.1002/adfm.201601315
11. [11]
  Yuan C Z, Sun Z T, Jiang Y F, et al.Small, 2017, 13:1604161 doi: 10.1002/smll.201604161
12. [12]
  Xiong X L, You C, Liu Z, et al.ACSSustainableChem.Eng., 2018, 6:2883-2887
13. [13]
  Xie M, Xiong X, Yang L, et al.Chem.Commun., 2018, 54:2300-2303 doi: 10.1039/C7CC09105B
14. [14]
  Cui Z, Ge Y C, Chu H, et al.J.Mater.Chem.A, 2017, 5:1595-1602 doi: 10.1039/C6TA09853C
15. [15]
  Yang L, Wu X L, Zhu X S, et al.Appl.Surf.Sci., 2015, 341:149-156 doi: 10.1016/j.apsusc.2015.03.018
16. [16]
  Ren J T, Yuan Z Y.ACSSustainableChem.Eng., 2017, 5:7203-7210
17. [17]
  Wu Y Y, Liu Y P, Li G D, et al.NanoEnergy, 2017, 35:161-170 doi: 10.1016/j.nanoen.2011.12.004
18. [18]
  Bandal H A, Jadhav A R, Tamboli A H, et al.Electrochim.Acta, 2017, 249:253-262 doi: 10.1016/j.electacta.2017.07.178
19. [19]
  Feng L L, Yu G T, Wu Y Y, et al.J.Am.Chem.Soc., 2015, 137:14023-14026 doi: 10.1021/jacs.5b08186
20. [20]
  Ming F, Liang H, Shi H, et al.J.Mater.Chem.A, 2016, 4:15148-15155 doi: 10.1039/C6TA06496E
21. [21]
  Liu T T, Xie L S, Yang J H, et al.ChemElectroChem, 2017, 4:1840-1845 doi: 10.1002/celc.201700392
22. [22]
  Liu S J, Han S D, Zhao J P, et al.Coord.Chem.Rev., 2019, 394:39-52 doi: 10.1016/j.ccr.2019.05.009
23. [23]
  Liu S J, Cao C, Yao S L, et al.DaltonTrans., 2017, 46:64-70 doi: 10.1039/C6DT03589B
24. [24]
  Liu S J, Cao C, Xie C C, et al.DaltonTrans., 2016, 45:9209-9215 doi: 10.1039/C6DT01349J
25. [25]
  Chen Y Z, Wang C M, Wu Z Y, et al.Adv.Mater., 2015, 27:5010-5016 doi: 10.1002/adma.201502315
26. [26]
  Sheberla D, Bachman J C, Elias J S, et al.Nat.Mater., 2017, 16:220-224 doi: 10.1038/nmat4766
27. [27]
  Sun L, Campbell M G, Dinca M.Angew.Chem.Int.Ed., 2016, 55:3566-3579 doi: 10.1002/anie.201506219
28. [28]
  Zhao S L, Yin H J, Du L, et al.ACSNano, 2014, 8:12660-12668 doi: 10.1021/acsnano.7b02035
1. [1]
  Hong CAI , Jiewen WU , Jingyun LI , Lixian CHEN , Siqi XIAO , Dan LI . Synthesis of a zinc-cobalt bimetallic adenine metal-organic framework for the recognition of sulfur-containing amino acids. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 114-122. doi: 10.11862/CJIC.20240382
2. [2]
  Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co₉S₈/Ni₃S₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
3. [3]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
4. [4]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
5. [5]
  Jianchun Wang , Ruyu Xie . The Fantastical Dance of Miss Electron: Contra-Thermodynamic Electrocatalytic Reactions. University Chemistry, 2025, 40(4): 331-339. doi: 10.12461/PKU.DXHX202406082
6. [6]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
7. [7]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
8. [8]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
9. [9]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
10. [10]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
11. [11]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044
12. [12]
  Xiaofang DONG , Yue YANG , Shen WANG , Xiaofang HAO , Yuxia WANG , Peng CHENG . Research progress of conductive metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 14-34. doi: 10.11862/CJIC.20240388
13. [13]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
14. [14]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044
15. [15]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
16. [16]
  Shiyang He , Dandan Chu , Zhixin Pang , Yuhang Du , Jiayi Wang , Yuhong Chen , Yumeng Su , Jianhua Qin , Xiangrong Pan , Zhan Zhou , Jingguo Li , Lufang Ma , Chaoliang Tan . 铂单原子功能化的二维Al-TCPP金属-有机框架纳米片用于增强光动力抗菌治疗. Acta Physico-Chimica Sinica, 2025, 41(5): 100046-. doi: 10.1016/j.actphy.2025.100046
17. [17]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
18. [18]
  Aiai WANG , Lu ZHAO , Yunfeng BAI , Feng FENG . Research progress of bimetallic organic framework in tumor diagnosis and treatment. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1825-1839. doi: 10.11862/CJIC.20240225
19. [19]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
20. [20]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(1373)
HTML views(355)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142