Citation: WANG Yong-Juan, ZHOU Yu-Ming, HE Man, HE Qiang, ZHONG Yang-Yang. Layer-by-Layer Assembly and Infrared Emissivity of (LDH/DNA/LDH/LTO)_n Hybrid Films[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(10): 1977-1987. doi: 10.11862/CJIC.2020.221 shu

Layer-by-Layer Assembly and Infrared Emissivity of (LDH/DNA/LDH/LTO)_n Hybrid Films

School of Chemistry and Chemical Engineering, Southeast University, Jiangsu Optoelectronic Functional Materials and Engineering Laboratory, Nanjing 211189, China

Corresponding author: WANG Yong-Juan, wangyongjuan0630@126.com
Received Date: 31 March 2020
Revised Date: 6 August 2020

Figures(8)

Herein, by using sequentially electrostatic layer-by-layer (LBL) deposition method, the artificialdesigned hybrid films were fabricated through the alternatively assemble of negatively charged layered titanium oxide (LTO) nanosheets and DNA molecules with positively charged layered double hydroxide (LDH) nanosheets. The infrared emissivity values at the wavelength of 8~14 μm of the as-synthesized samples were investigated. The X-ray diffraction (XRD) results demonstrate that the (LDH/DNA/LDH/LTO)_n hybrid films were orderly stacked on the substrate in the normal direction, in which the DNA molecules and LTO nanosheets were accommodated as monolayer between the LDH nanosheets layers, respectively. It can be seen from the scanning electron microscope (SEM) and atomic force microscope (AFM) images that the surface morphology of the film was uniform and continuous. The energy dispersive X-ray spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS) analysis verify the composition, the homogenous element distribution, and the well-ordered structure in the multilayer films. This multilayered hybrid film with tetra-layer units possessed a low infrared emissivity value of 0.419 based on the synergistic effect of its multi-components, the interfacial interaction between different layers and the uniform and smooth surface. These results clearly demonstrate that the ordered LBL assembly of the artificial designed hybrid film is quite effective in decreasing the infrared emissivity value.
- LDH,
- DNA,
- layered titanium oxide,
- layer-by-layer,
- organic-inorganic hybrid composites,
- infrared emissivity
1. [1]
  Lang F P, Wang H, Zhang S J, et al. Int. J. Thermophys., 2017, 39(1):1-20
2. [2]
  Chu H T, Zhang Z C, Liu Y J, et al. Carbon, 2016, 98:557-566 doi: 10.1016/j.carbon.2015.11.036
3. [3]
  Yuan L, Weng X L, Deng L J. Infrared Phys. Technol., 2013, 56:25-29 doi: 10.1016/j.infrared.2012.09.004
4. [4]
  Wu G W, Yu D M. Prog. Org. Coat., 2013, 76(1):107-112 doi: 10.1016/j.porgcoat.2012.08.018
5. [5]
  Chen L, Lu C H, Fang Z G, et al. Mater. Lett., 2013, 93:308- 311 doi: 10.1016/j.matlet.2012.11.117
6. [6]
  Fang F, Jing W Q, Yang W. Infrared Phys. Technol., 2018, 93: 130-135 doi: 10.1016/j.infrared.2018.07.021
7. [7]
  Lyu J, Liu Z W, Wu X H, et al. ACS Nano, 2019, 13(2):2236- 2245
8. [8]
  Huang Z B, Zhou W C, Tang X F, et al. Thin Solid Films, 2011, 519(10):3100-3106 doi: 10.1016/j.tsf.2010.12.157
9. [9]
  Kato K, Omoto H, Tomioka T, et al. Sol. Energy Mater. Sol.Cells, 2011, 95(8):2352-2356 doi: 10.1016/j.solmat.2011.04.005
10. [10]
  Osada M, Sasaki T. J. Mater. Chem., 2009, 19(17):2503-2511 doi: 10.1039/b820160a
11. [11]
  Sun Y Q, Zhou Y M, Ye X Y, et al. Mater. Lett., 2008, 62(17/18):2943-2946
12. [12]
  Wang Y J, Zhou Y M, Zhang T, et al. J. Mater. Sci., 2014, 49 (20):6944-6951 doi: 10.1007/s10853-014-8399-5
13. [13]
  Wang Y J, Zhou Y M, Zhang T, et al. Appl. Surf. Sci., 2014, 288:710-717 doi: 10.1016/j.apsusc.2013.10.109
14. [14]
  Williams G R, Ohare D. J. Mater. Chem., 2006, 16(30):3065- 3074 doi: 10.1039/b604895a
15. [15]
  Evans D, Slade R. Structural Aspects of Layered Double Hydroxides Layered Double Hydroxides. Berlin/Heidelberg:Springer, 2006:1-87
16. [16]
  Ogawa M, Asai S. Chem. Mater., 2000, 12(11):3253-3255 doi: 10.1021/cm000455n
17. [17]
  Choy J H, Kwak S Y, Jeong Y J, et al. Angew. Chem. Int.Ed., 2000, 39(22):4041-4045 doi: 10.1002/1521-3773(20001117)39:22<4041::AID-ANIE4041>3.0.CO;2-C
18. [18]
  Nyambo C, Songtipya P, Manias E, et al. J. Mater. Chem., 2008, 18(40):4827-4838 doi: 10.1039/b806531d
19. [19]
  Li L, Ma R Z, Iyi N, et al. Chem. Commun., 2006, 29:3125- 3127
20. [20]
  Li L, Ma R, Ebina Y, et al. J. Am. Chem. Soc., 2007, 129(25):8000-8007 doi: 10.1021/ja0719172
21. [21]
  Chen D, Wang X Y, Liu T X, et al. ACS Appl. Mater. Interfaces, 2010, 2(7):2005-2011 doi: 10.1021/am100307v
22. [22]
  Liu Z P, Ma R Z, Osada M, et al. J. Am. Chem. Soc., 2006, 128(14):4872-4880 doi: 10.1021/ja0584471
23. [23]
  Kong X G, Rao X Y, Han J B, et al. Biosens. Bioelectron., 2010, 26(2):549-554 doi: 10.1016/j.bios.2010.07.045
24. [24]
  Zhao Z P, Qi Y L, Wei M, et al. Mater. Lett., 2012, 78:62-65 doi: 10.1016/j.matlet.2012.03.064
25. [25]
  Li H J, Deng L J, Zhu G, et al. Mater. Sci. Eng. B, 2012, 177(1):8-13
26. [26]
  Wang Y J, Zhou Y M, Zhang T, et al. RSC Adv., 2014, 4(57):29968-29974 doi: 10.1039/C3RA47728B
27. [27]
  Matsumoto Y, Unal U, Kimura Y, et al. J. Phys. Chem. B, 2005, 109(26):12748-12754 doi: 10.1021/jp0517089
28. [28]
  Sasaki T, Kooli F, Iida M, et al. Chem. Mater., 1998, 10(12):4123-4128 doi: 10.1021/cm980535f
29. [29]
  Sasaki T, Ebina Y, Kitami Y, et al. J. Phys. Chem. B, 2001, 105(26):6116-6121 doi: 10.1021/jp010421i
30. [30]
  Choy J H, Kwak S Y, Park J S, et al. J. Am. Chem. Soc., 1999, 121(6):1399-1400 doi: 10.1021/ja981823f
31. [31]
  Sasaki T, Ebina Y, Watanabe M, et al. Chem. Commun., 2000, 21:2163-2164
32. [32]
  Khan A Ⅰ, Ohare D. J. Mater. Chem., 2002, 12(11):3191-3198 doi: 10.1039/B204076J
33. [33]
  Lin L Y, Yu J L, Cheng S Y, et al. Chin. Phys. B, 2015, 24(7):078103 doi: 10.1088/1674-1056/24/7/078103
34. [34]
  Hu H J, Liu J Y, Xu Z H, et al. Appl. Surf. Sci., 2019, 478:981-990 doi: 10.1016/j.apsusc.2019.02.008
35. [35]
  Zhao Y F, Wang C J, Gao W, et al. J. Mater. Chem. B, 2013, 1:5988-5994 doi: 10.1039/c3tb21059f
36. [36]
  Guo C X, Xie J L, Wang B, et al. Sci. Rep., 2013, 3:2957 - 2963 doi: 10.1038/srep02957
37. [37]
  Wang Y J, Zhou Y M, Zhang T, et al. Chem. Eng. J., 2015, 266:199-202 doi: 10.1016/j.cej.2014.12.067
38. [38]
  Chen J, Zhou Y M, Nan Q L, et al. Appl. Surf. Sci., 2007, 253 (23):9154-9158 doi: 10.1016/j.apsusc.2007.05.046
39. [39]
  Yang Y, Sun C, Zhou Y M, et al. Polym. J., 2016, 48(7):807- 812 doi: 10.1038/pj.2016.33
40. [40]
  Yong Y, Zhou Y M, Wang T H. Mater. Lett., 2014, 133:269-273 doi: 10.1016/j.matlet.2014.06.184
41. [41]
  Zhang M Y, Zhou Y M, He M, et al. RSC Adv., 2016, 6(9):7439-7447 doi: 10.1039/C5RA24052B
42. [42]
  Bu X H, Zhou Y M, Zhang T, et al. J. Mater. Sci., 2014, 49 (20):7133-7142 doi: 10.1007/s10853-014-8421-y
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Layer-by-Layer Assembly and Infrared Emissivity of (LDH/DNA/LDH/LTO)n Hybrid Films

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通讯作者: 陈斌, bchen63@163.com

Layer-by-Layer Assembly and Infrared Emissivity of (LDH/DNA/LDH/LTO)_n Hybrid Films