Citation: YING Jun, ZHANG Bao-Yue, TIAN Ai-Xiang. Four Keggin Compounds Modified by Tri-and Tetra-nuclear Metal-Organic Clusters: Structures, Selective Photocatalytic and Hg²⁺ Recognition Characteristics[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(10): 1831-1844. doi: 10.11862/CJIC.2020.218 shu

Four Keggin Compounds Modified by Tri-and Tetra-nuclear Metal-Organic Clusters: Structures, Selective Photocatalytic and Hg²⁺ Recognition Characteristics

Department of Chemistry, Bohai University, Jinzhou, Liaoning 121013, China

Corresponding author: TIAN Ai-Xiang, tian@bhu.edu.cn
Received Date: 15 March 2020
Revised Date: 28 July 2020

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By using a flexible S-containing ligand 4-(2-thiophen-2-yl-ethyl)-4H-[1, 2, 4]triazole (L), four Kegginbased compounds, namely[Cu₃^ⅠL₃(PMo₁₂O₄₀)] (1), [Cu₄^ⅠL₆(SiW₁₂O₄₀)] (2), [Cu₄^ⅠL₆(SiMo₁₂O₄₀)] (3) and[Zn₄L₆ (SiW₁₂O₄₀)] (4), were successfully synthesized by controlling the reaction parameters and well characterized by single -crystal X-ray diffraction, elemental analyses, and IR spectra. In compound 1, three Cu⁺ ions are fused by three L ligands inducing a cyclic tri-nuclear Cu⁺ cluster. The Keggin anions link the tri-nuclear clusters to construct a 2D layer. Compounds 2, 3 and 4 are isostructural, including a tetra-nuclear[M₄L₆]⁴⁺ cluster with six L ligands connected by four M ions (M=Cu in 2 and 3, Zn in 4). The Keggin anion offers two O atoms to link two[Cu₄L₆]⁴⁺ clusters and a 1D chain is formed. The title compounds exhibited good selective degradation of cationic methylene blue (MB) dye in wastewater. Additionally, the 2-CPE (carbon paste electrodes) could act as an amperometric sensor for detection of hydrogen peroxide and nitrite. Compounds 1, 2 and 4 also showed Hg²⁺ recognition properties.
- polyoxometalate,
- electrochemical properties,
- selective photocatalysis,
- Hg²⁺ recognition
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通讯作者: 陈斌, bchen63@163.com

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Four Keggin Compounds Modified by Tri-and Tetra-nuclear Metal-Organic Clusters: Structures, Selective Photocatalytic and Hg2+ Recognition Characteristics

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通讯作者: 陈斌, bchen63@163.com

Four Keggin Compounds Modified by Tri-and Tetra-nuclear Metal-Organic Clusters: Structures, Selective Photocatalytic and Hg²⁺ Recognition Characteristics