Citation: WANG Xiao-Hui, LI Gui-Fang, WEI Yun-Ge, GUAN Xu-Feng. Morphology-Controlled Synthesis and Luminescence Properties of Red-Emitting NaCaGd(WO₄)₃: Eu³⁺ Phosphors[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(10): 1881-1890. doi: 10.11862/CJIC.2020.216 shu

Morphology-Controlled Synthesis and Luminescence Properties of Red-Emitting NaCaGd(WO₄)₃: Eu³⁺ Phosphors

School of Advanced Materials and Nano Technology, Xidian University, Xi'an 710071, China

Corresponding author: LI Gui-Fang, gfli@mail.xidian.edu.cn
Received Date: 1 April 2020
Revised Date: 21 August 2020

Figures(12)

NaCaGd(WO₄)₃:Eu³⁺ red phosphors with controllable morphology were synthesized via the hydrothermal method. The influences of pH value, reaction temperature and Eu³⁺ concentration on the crystal structure, morphology and photoluminescence properties of NaCaGd(WO₄)₃:Eu³⁺ phosphors were investigated in detail. The results show that the pure tetragonal sheelite structure NaCaGd(WO₄)₃ with uniform tetragonal plate-like nanocrystallines was obtained when pH value was 9 and reaction temperature of 180℃. Under the excitation of 394 nm, the phosphors displayed a bright red emission corresponding to the characteristic 4f-4f transitions of Eu³⁺, and the intensity of emission peak mainly depends on the pH value, the reaction temperature and Eu³⁺ doped concentration. The optimum photoluminescence performance is achieved for NaCaEu(WO₄)₃ (x=1.0) phosphors synthesized at pH=9 under the reaction temperature 180℃. In addition, the thermal stability of the phosphors was analyzed under different ambient temperatures between 303 and 513 K. The result exhibits that the emission intensity of phosphor decreases with the increase of ambient temperature. Finally, the corresponding chromaticity coordinate and color purity were calculated to (0.658, 0.341) and 96.1%, which is close to the standard CIE chromaticity coordiante values for red light (0.673, 0.327).
- hydrothermal method,
- photoluminescence,
- phosphors,
- Eu³⁺ doping concentration
1. [1]
  WU Jin-Xiu, LI Mei, CUI Song-Song. Chinese J. Inorg. Chem., 2017, 33(2):219 -226 doi: 10.3321/j.issn:1001-4861.1999.03.001
2. [2]
  Li X W, Xu H L, Xia X M, et al. Ceram. Int., 2019, 45:10461- 10467 doi: 10.1016/j.ceramint.2019.02.107
3. [3]
  Shi Y R, Liu B T, Li C Y, et al. Mater. Res. Bull., 2018, 101: 319-323 doi: 10.1016/j.materresbull.2018.01.048
4. [4]
  Chen G Q, Wang F L, Ji W C, et al. Superlattices Microstruct., 2016, 90:30-37 doi: 10.1016/j.spmi.2015.11.037
5. [5]
  Jiang Z H, Cai P Q, Chen C L, et al. Mater. Chem. Phys., 2017, 193:227-233 doi: 10.1016/j.matchemphys.2017.02.032
6. [6]
  Li G F, Wei Y G, Li Z M, et al. Opt. Mater., 2017, 66:253-260 doi: 10.1016/j.optmat.2017.02.018
7. [7]
  Wang Y Q, Tang J Q, Huang X Y, et al. J. Rare Earths, 2016, 34(2):118-124 doi: 10.1016/S1002-0721(16)60002-9
8. [8]
  Bin J X, Liu H K, Mei L F, et al. Ceram. Int., 2019, 45:1837- 1845 doi: 10.1016/j.ceramint.2018.10.074
9. [9]
  Qin D, Tang W J. RSC Adv., 2016, 6:45376-45385 doi: 10.1039/C6RA10763J
10. [10]
  Shannon R D. Acta Cryst., 1976, A32:751-767
11. [11]
  Li J G, Wu Z Y, Sun X Y, et al. J. Mater. Sci., 2017, 52:3110- 3123 doi: 10.1007/s10853-016-0598-9
12. [12]
  CHEN Dong-Ju, TANG Li, LIN Li-Tian, et al. Chinese J. Inorg. Chem.2015, 31(12):2279-2284
13. [13]
  Xia M F, Ju Z H, Yang H A, et al. J. Alloys Compd., 2018, 739:439-446 doi: 10.1016/j.jallcom.2017.12.242
14. [14]
  Abrams B L, Holloway P H. Chem. Rev., 2004, 104(12):5783- 5801 doi: 10.1021/cr020351r
15. [15]
  Zhai Y Q, Zhao X, Sun Q L, et al. J. Mater. Sci. Mater. - Electron., 2018, 29:5034-5041 doi: 10.1007/s10854-017-8465-2
16. [16]
  Chien T C, Yang J C, Hwang C S, et al. J. Alloys Compd., 2016, 676:286-291 doi: 10.1016/j.jallcom.2016.03.083
17. [17]
  Li L, Zhou X J, Zhao C L. J. Alloys Compd., 2016, 685:917- 926 doi: 10.1016/j.jallcom.2016.06.255
18. [18]
  Shruthi D L, Reddy A J, Anil Kumar G N, et al. J. Lumin., 2020, 222:117167 doi: 10.1016/j.jlumin.2020.117167
19. [19]
  Yang Q, Li G F, Wei Y G, et al. J. Lumin., 2018, 199:323- 330 doi: 10.1016/j.jlumin.2018.03.011
20. [20]
  Rasu K K, Balaji D, Babu S M. J. Lumin., 2016, 170:547-555 doi: 10.1016/j.jlumin.2015.10.006
21. [21]
  Huang D C, Zhou Y F, Xu W T, et al. J. Lumin., 2012, 132: 2788-2793 doi: 10.1016/j.jlumin.2012.05.022
22. [22]
  Zhu H K, Fang M H, Huang Z H, et al. J. Lumin., 2016, 172: 180-184 doi: 10.1016/j.jlumin.2015.12.021
23. [23]
  Xie J H, Cheng L Q, Tang H, et al. J. Lumin., 2020, 219: 116841 doi: 10.1016/j.jlumin.2019.116841
24. [24]
  Liu Q, Li X B, Guo J K, et al. Dyes Pigm., 2019, 160:165-171 doi: 10.1016/j.dyepig.2018.08.013
25. [25]
  Xin S Y, Wang Y H, Zhu G, et al. Dalton Trans., 2015, 44: 16099-16105 doi: 10.1039/C5DT02099A
26. [26]
  Zhu G, Ci Z P, Shi Y R, et al. J. Mater. Chem. C, 2013, 1: 5960-5965 doi: 10.1039/c3tc31263a
27. [27]
  Rasu K K, Babu S M. Solid State Sci. , 2019, 98:106028 doi: 10.1016/j.solidstatesciences.2019.106028
1. [1]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
2. [2]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
3. [3]
  Yan ZHAO , Jiaxu WANG , Zhonghu LI , Changli LIU , Xingsheng ZHAO , Hengwei ZHOU , Xiaokang JIANG . Gd³⁺-doped Sc₂W3O₁₂: Eu³⁺ red phosphor: Preparation and luminescence performance. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 461-468. doi: 10.11862/CJIC.20240316
4. [4]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
5. [5]
  Yan ZHAO , Xiaokang JIANG , Zhonghui LI , Jiaxu WANG , Hengwei ZHOU , Hai GUO . Preparation and fluorescence properties of Eu³⁺-doped CaLaGaO₄ red-emitting phosphors. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1861-1868. doi: 10.11862/CJIC.20240242
6. [6]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
7. [7]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
8. [8]
  Zishuo Yi , Peng Liu , Yan Xu . Fluorescent “Chameleon”: A Popular Science Experiment Based on Dynamic Luminescence. University Chemistry, 2024, 39(9): 304-310. doi: 10.12461/PKU.DXHX202311079
9. [9]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
10. [10]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
11. [11]
  Hongzhi Zhang , Hong Li , Asif Ali Haider , Junpeng Li , Zhi Xie , Hongming Jiang , Conglin Liu , Rui Wang , Jing Zhu . An unexpected role of lanthanide substitution in thermally responsive phosphors NaLnTe2O7: Eu3+ (Ln = Y and Gd). Chinese Journal of Structural Chemistry, 2025, 44(2): 100509-100509. doi: 10.1016/j.cjsc.2024.100509
12. [12]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
13. [13]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
14. [14]
  Qin Li , Kexin Yang , Qinglin Yang , Xiangjin Zhu , Xiaole Han , Tao Huang . Illuminating Chlorophyll: Innovative Chemistry Popularization Experiment. University Chemistry, 2024, 39(9): 359-368. doi: 10.3866/PKU.DXHX202309059
15. [15]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
16. [16]
  Yang YANG , Pengcheng LI , Zhan SHU , Nengrong TU , Zonghua WANG . Plasmon-enhanced upconversion luminescence and application of molecular detection. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 877-884. doi: 10.11862/CJIC.20230440
17. [17]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
18. [18]
  Borong Yu , Huijiao Zhang , Xinyu Zhang , Xiaoying Li , Shuming Chen , Zhangang Han . The Blue Elf in the Dark: Gradient Science Popularization Experiments on Chemiluminescence. University Chemistry, 2024, 39(9): 295-303. doi: 10.12461/PKU.DXHX202403107
19. [19]
  Xiaxue Chen , Yuxuan Yang , Ruolin Yang , Yizhu Wang , Hongyun Liu . Adjustable Polychromatic Fluorescence: Investigating the Photoluminescent Properties of Copper Nanoclusters. University Chemistry, 2024, 39(9): 328-337. doi: 10.3866/PKU.DXHX202308019
20. [20]
  YanYuan Jia , Rong Rong , Jie Liu , Jing Guo , GuoYu Jiang , Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(599)
HTML views(66)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Morphology-Controlled Synthesis and Luminescence Properties of Red-Emitting NaCaGd(WO4)3: Eu3+ Phosphors

Metrics

通讯作者: 陈斌, bchen63@163.com

Morphology-Controlled Synthesis and Luminescence Properties of Red-Emitting NaCaGd(WO₄)₃: Eu³⁺ Phosphors