Citation: FENG Rui, HU Xiao-Yan, YAN Xin-Long, WU Jian-Jun. Preparation of Boron and Fluorine Doped ZSM-5 Zeolites for Methanol to Propylene Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(9): 1791-1803. doi: 10.11862/CJIC.2020.209 shu

Preparation of Boron and Fluorine Doped ZSM-5 Zeolites for Methanol to Propylene Reaction

School of Chemical and Engineering, China University of Mining & Technology, Xuzhou, Jiangsu 221116, China

Corresponding author: FENG Rui, feng2007115@163.com
Received Date: 22 March 2020
Revised Date: 17 July 2020

Figures(9)

A series of boron and/or fluorine containing ZSM-5 zeolites were synthesized and used for the methanol to propylene (MTP) reaction. The as-synthesized ZSM-5 were characterized by X-ray diffraction, N₂ adsorption-desorption, ²⁹Si solid nuclear magnetic resonance, Fourier transform infrared spectroscopy, scanning electron micro-scope, and ammonia temperature-programmed desorption methods. The ZSM-5 molecular sieve with higher crystal-linity can be synthesized under the conditions of boron and fluorine doping. The heteroatom doping improves the SiO₂/Al₂O₃ ratio (n_SiO₂/n_Al₂O₃) of the molecular sieve. Boron and fluorine doped ZSM-5 possessed reduced Lewis acid sites but increased Brønsted acid sites. Besides, the particle size of ZSM-5 decreased with both boron and fluorine doping. In the MTP reaction, the enhanced catalyst lifetime could be attributed to the low content of Lewis acid sites and less strong Brønsted acid sites on the ZSM-5 catalysts. NH₄BF₄ modified ZSM-5 catalyst (Z5-BF2) with reduced Lewis acid sites and appropriate Brønsted acid sites exhibited relatively high propylene selectivity and long catalyst lifetime.
- ZSM-5,
- methanol to propylene,
- lewis acid sites,
- boron,
- fluorine
1. [1]
  Martínez-Espín J S, de Wispelaere K, Janssens T V W, et al. ACS Catal., 2017, 7(9):5773-5780 doi: 10.1021/acscatal.7b01643
2. [2]
  Müller S, Liu Y, Kirchberger F M, et al. J. Am. Chem. Soc., 2016, 138(49):15994-16003 doi: 10.1021/jacs.6b09605
3. [3]
  Feng R, Wang X, Lin J, et al. Microporous Mesoporous Mater., 2018, 270:57-66 doi: 10.1016/j.micromeso.2018.05.003
4. [4]
  Mei C, Wen P, Liu Z, et al. J. Catal., 2008, 258(1):243-249 doi: 10.1016/j.jcat.2008.06.019
5. [5]
  Kim W, Ryoo R. Catal. Lett., 2014, 144(7):1164-1169 doi: 10.1007/s10562-014-1274-9
6. [6]
  Rojo-Gama D, Signorile M, Bonino F, et al. J. Catal., 2017, 351:33-48 doi: 10.1016/j.jcat.2017.04.015
7. [7]
  Olsbye U, Svelle S, Bjørgen M, et al. Angew. Chem. Int. Ed., 2012, 51(24):5810-5831 doi: 10.1002/anie.201103657
8. [8]
  Liu J, Zhang C, Shen Z, et al. Catal. Commun., 2009, 10(11):1506-1509 doi: 10.1016/j.catcom.2009.04.004
9. [9]
  Feng R, Liu S, Bai P, et al. J. Phys. Chem. C, 2014, 118(12):6226-6234 doi: 10.1021/jp411405r
10. [10]
  Feng R, Yan X, Hu X, et al. Microporous Mesoporous Mater., 2017, 243:319-330 doi: 10.1016/j.micromeso.2017.02.041
11. [11]
  Feng R, Yan X, Hu X, et al. Catal. Commun., 2018, 109:1-5 doi: 10.1016/j.catcom.2018.02.005
12. [12]
  Li Q, Creaser D, Sterte J. Microporous Mesoporous Mater., 1999, 31(1/2):141-150
13. [13]
  Beck J, Vartuli J, Roth W, et al. J. Am. Chem. Soc., 1992, 114(27):10834-10843 doi: 10.1021/ja00053a020
14. [14]
  Tao Y, Kanoh H, Kaneko K. J. Am. Chem. Soc., 2003, 125(20):6044-6045 doi: 10.1021/ja0299405
15. [15]
  Hu Z, Zhang H, Wang L, et al. Catal. Sci. Technol., 2014, 4:2891-2895 doi: 10.1039/C4CY00376D
16. [16]
  Zhai Y, Zhang S, Shang Y, et al. Catal. Sci. Technol., 2019, 9:659-671 doi: 10.1039/C8CY02177E
17. [17]
  Feng R, Yan X, Hu X, et al. Appl. Catal. A, 2020, 594:117464-117472 doi: 10.1016/j.apcata.2020.117464
18. [18]
  Feng R, Yan X, Hu X, et al. Microporous Mesoporous Mater., 2020, 302:110246-110253 doi: 10.1016/j.micromeso.2020.110246
19. [19]
  Fild C, Shantz D F, Lobo R F, et al. Phys. Chem. Chem. Phys., 2000, 2:3091-3098 doi: 10.1039/b002134m
20. [20]
  Rojas A, Gómez-Hortigüela L, Camblor M A. J. Am. Chem. Soc., 2012, 134(8):3845-3856 doi: 10.1021/ja210703y
21. [21]
  Lopes C W, Gómez-Hortigüela L, Rojas A, et al. Microporous Mesoporous Mater., 2017, 252:29-36 doi: 10.1016/j.micromeso.2017.06.017
22. [22]
  Zhang F, Zheng Y, Hu L, et al. J. Membr. Sci., 2014, 456:107-116 doi: 10.1016/j.memsci.2014.01.023
23. [23]
  Kao H M, Chen Y C. J. Phys. Chem. B, 2003, 107(15):3367-3375 doi: 10.1021/jp021680q
24. [24]
  Zhang B, Douthwaite M, Liu Q, et al. Green Chem., 2020, 22:1630-1638 doi: 10.1039/C9GC03622A
25. [25]
  Yu L, Huang S, Miao S, et al. Chem. Eur. J., 2015, 21(3):1048-1054 doi: 10.1002/chem.201404817
26. [26]
  Phung T K, Proietti Hernández L, Lagazzo A, et al. Appl. Catal. A, 2015, 493:77-89 doi: 10.1016/j.apcata.2014.12.047
27. [27]
  Feng R, Hu X, Yan X, et al. Microporous Mesoporous Mater., 2017, 241:89-97 doi: 10.1016/j.micromeso.2016.11.035
28. [28]
  Emeis C A. J. Catal., 1993, 141(2):347-354 doi: 10.1006/jcat.1993.1145
29. [29]
  Bevilacqua M, Montanari T, Finocchio E, et al. Catal. Today, 2006, 116(2):132-142 doi: 10.1016/j.cattod.2006.01.024
30. [30]
  Rostamizadeh M, Taeb A. J. Ind. Eng. Chem., 2015, 27:297-306 doi: 10.1016/j.jiec.2015.01.004
31. [31]
  Gil B, Mokrzycki Ł, Sulikowski B, et al. Catal. Today, 2010, 152(1/2/3/4):24-32
32. [32]
  ZHAI Yan-Liang, ZHANG Shao-Long, ZHANG Luo-Min, et al. Acta Phys.-Chim. Sin., 2019, 35(11):1248-1258
33. [33]
  Qin Z, Lakiss L, Gilson J P, et al. Chem. Mater., 2013, 25(14):2759-2766 doi: 10.1021/cm400719z
34. [34]
  Qin Z, Pinard L, Benghalem M A, et al. Chem. Mater., 2019, 31(13):4639-4648 doi: 10.1021/acs.chemmater.8b04970
35. [35]
  Sun X, Mueller S, Liu Y, et al. J. Catal., 2014, 317:185-197 doi: 10.1016/j.jcat.2014.06.017
36. [36]
  Feng R, Yan X, Hu X, et al. Appl. Catal. A, 2020, 592:117429-117440 doi: 10.1016/j.apcata.2020.117429
37. [37]
  Bleken F L, Chavan S, Olsbye U, et al. Appl. Catal. A, 2012, 447-448:178-185 doi: 10.1016/j.apcata.2012.09.025
38. [38]
  Müller S, Liu Y, Vishnuvarthan M, et al. J. Catal., 2015, 325:48-59 doi: 10.1016/j.jcat.2015.02.013
39. [39]
  Wu Z, Zhao K, Zhang Y, et al. Ind. Eng. Chem. Res., 2019, 58(25):10737-10749 doi: 10.1021/acs.iecr.9b00502
40. [40]
  Sugimoto M, Katsuno H, Takatsu K, et al. Zeolites, 1987, 7(6):503-507 doi: 10.1016/0144-2449(87)90087-X
41. [41]
  Cai D, Wang N, Chen X, et al. Nanoscale, 2019, 11:8096-8101 doi: 10.1039/C8NR10371B
42. [42]
  Khare R, Millar D, Bhan A. J. Catal., 2015, 321:23-32 doi: 10.1016/j.jcat.2014.10.016
43. [43]
  Carr R T, Neurock M, Iglesia E. J. Catal., 2011, 278(1):78-93 doi: 10.1016/j.jcat.2010.11.017
44. [44]
  Ono Y, Mori T. J. Chem. Soc. Faraday Trans., 1981, 77:2209-2221 doi: 10.1039/f19817702209
45. [45]
  Gayubo A G, Alonso A, Valle B, et al. Chem. Eng. J., 2011, 167(1):262-277 doi: 10.1016/j.cej.2010.12.058
46. [46]
  Zhang J, Zhang H, Yang X, et al. J. Nat. Gas Chem., 2011, 20(3):266-270 doi: 10.1016/S1003-9953(10)60183-1
47. [47]
  Sazama P, Wichterlova B, Dedecek J, et al. Microporous Mesoporous Mater., 2011, 143(1):87-96 doi: 10.1016/j.micromeso.2011.02.013
48. [48]
  Feng R, Yan X, Hu X, et al. J. Porous Mater., 2018, 25(6):1743-1756 doi: 10.1007/s10934-018-0587-2
49. [49]
  Jiang L, Li C, Xu M, et al. J. Chin. J. Chem. Eng., 2018, 26(10):2102-2111 doi: 10.1016/j.cjche.2018.09.010
50. [50]
  Yang Y, Sun C, Du J, et al. Catal. Commun., 2012, 24:44-47 doi: 10.1016/j.catcom.2012.03.013
51. [51]
  Li J, Liu M, Guo X, et al. Ind. Eng. Chem. Res., 2018, 57(24):8190-8199 doi: 10.1021/acs.iecr.8b00513
52. [52]
  Yaripour F, Shariatinia Z, Sahebdelfar S, et al. Microporous Mesoporous Mater., 2015, 203:41-53 doi: 10.1016/j.micromeso.2014.10.024
53. [53]
  Ding J, Jia Y, Chen P, et al. Chem. Eng. J., 2019, 361:588-598 doi: 10.1016/j.cej.2018.12.108
54. [54]
  Li J, Liu M, Guo X, et al. J. Energy Chem., 2018, 27(4):1225-1230 doi: 10.1016/j.jechem.2017.08.018
55. [55]
  Zhang L, Song Y, Li G, et al. RSC Adv., 2015, 5:61354-61363 doi: 10.1039/C5RA09561A
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2. [2]
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