Citation: FENG Rui, HU Xiao-Yan, YAN Xin-Long, WU Jian-Jun. Preparation of Boron and Fluorine Doped ZSM-5 Zeolites for Methanol to Propylene Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(9): 1791-1803. doi: 10.11862/CJIC.2020.209 shu

Preparation of Boron and Fluorine Doped ZSM-5 Zeolites for Methanol to Propylene Reaction

School of Chemical and Engineering, China University of Mining & Technology, Xuzhou, Jiangsu 221116, China

Corresponding author: FENG Rui, feng2007115@163.com
Received Date: 22 March 2020
Revised Date: 17 July 2020

Figures(9)

A series of boron and/or fluorine containing ZSM-5 zeolites were synthesized and used for the methanol to propylene (MTP) reaction. The as-synthesized ZSM-5 were characterized by X-ray diffraction, N₂ adsorption-desorption, ²⁹Si solid nuclear magnetic resonance, Fourier transform infrared spectroscopy, scanning electron micro-scope, and ammonia temperature-programmed desorption methods. The ZSM-5 molecular sieve with higher crystal-linity can be synthesized under the conditions of boron and fluorine doping. The heteroatom doping improves the SiO₂/Al₂O₃ ratio (n_SiO₂/n_Al₂O₃) of the molecular sieve. Boron and fluorine doped ZSM-5 possessed reduced Lewis acid sites but increased Brønsted acid sites. Besides, the particle size of ZSM-5 decreased with both boron and fluorine doping. In the MTP reaction, the enhanced catalyst lifetime could be attributed to the low content of Lewis acid sites and less strong Brønsted acid sites on the ZSM-5 catalysts. NH₄BF₄ modified ZSM-5 catalyst (Z5-BF2) with reduced Lewis acid sites and appropriate Brønsted acid sites exhibited relatively high propylene selectivity and long catalyst lifetime.
- ZSM-5,
- methanol to propylene,
- lewis acid sites,
- boron,
- fluorine
1. [1]
  Martínez-Espín J S, de Wispelaere K, Janssens T V W, et al. ACS Catal., 2017, 7(9):5773-5780 doi: 10.1021/acscatal.7b01643
2. [2]
  Müller S, Liu Y, Kirchberger F M, et al. J. Am. Chem. Soc., 2016, 138(49):15994-16003 doi: 10.1021/jacs.6b09605
3. [3]
  Feng R, Wang X, Lin J, et al. Microporous Mesoporous Mater., 2018, 270:57-66 doi: 10.1016/j.micromeso.2018.05.003
4. [4]
  Mei C, Wen P, Liu Z, et al. J. Catal., 2008, 258(1):243-249 doi: 10.1016/j.jcat.2008.06.019
5. [5]
  Kim W, Ryoo R. Catal. Lett., 2014, 144(7):1164-1169 doi: 10.1007/s10562-014-1274-9
6. [6]
  Rojo-Gama D, Signorile M, Bonino F, et al. J. Catal., 2017, 351:33-48 doi: 10.1016/j.jcat.2017.04.015
7. [7]
  Olsbye U, Svelle S, Bjørgen M, et al. Angew. Chem. Int. Ed., 2012, 51(24):5810-5831 doi: 10.1002/anie.201103657
8. [8]
  Liu J, Zhang C, Shen Z, et al. Catal. Commun., 2009, 10(11):1506-1509 doi: 10.1016/j.catcom.2009.04.004
9. [9]
  Feng R, Liu S, Bai P, et al. J. Phys. Chem. C, 2014, 118(12):6226-6234 doi: 10.1021/jp411405r
10. [10]
  Feng R, Yan X, Hu X, et al. Microporous Mesoporous Mater., 2017, 243:319-330 doi: 10.1016/j.micromeso.2017.02.041
11. [11]
  Feng R, Yan X, Hu X, et al. Catal. Commun., 2018, 109:1-5 doi: 10.1016/j.catcom.2018.02.005
12. [12]
  Li Q, Creaser D, Sterte J. Microporous Mesoporous Mater., 1999, 31(1/2):141-150
13. [13]
  Beck J, Vartuli J, Roth W, et al. J. Am. Chem. Soc., 1992, 114(27):10834-10843 doi: 10.1021/ja00053a020
14. [14]
  Tao Y, Kanoh H, Kaneko K. J. Am. Chem. Soc., 2003, 125(20):6044-6045 doi: 10.1021/ja0299405
15. [15]
  Hu Z, Zhang H, Wang L, et al. Catal. Sci. Technol., 2014, 4:2891-2895 doi: 10.1039/C4CY00376D
16. [16]
  Zhai Y, Zhang S, Shang Y, et al. Catal. Sci. Technol., 2019, 9:659-671 doi: 10.1039/C8CY02177E
17. [17]
  Feng R, Yan X, Hu X, et al. Appl. Catal. A, 2020, 594:117464-117472 doi: 10.1016/j.apcata.2020.117464
18. [18]
  Feng R, Yan X, Hu X, et al. Microporous Mesoporous Mater., 2020, 302:110246-110253 doi: 10.1016/j.micromeso.2020.110246
19. [19]
  Fild C, Shantz D F, Lobo R F, et al. Phys. Chem. Chem. Phys., 2000, 2:3091-3098 doi: 10.1039/b002134m
20. [20]
  Rojas A, Gómez-Hortigüela L, Camblor M A. J. Am. Chem. Soc., 2012, 134(8):3845-3856 doi: 10.1021/ja210703y
21. [21]
  Lopes C W, Gómez-Hortigüela L, Rojas A, et al. Microporous Mesoporous Mater., 2017, 252:29-36 doi: 10.1016/j.micromeso.2017.06.017
22. [22]
  Zhang F, Zheng Y, Hu L, et al. J. Membr. Sci., 2014, 456:107-116 doi: 10.1016/j.memsci.2014.01.023
23. [23]
  Kao H M, Chen Y C. J. Phys. Chem. B, 2003, 107(15):3367-3375 doi: 10.1021/jp021680q
24. [24]
  Zhang B, Douthwaite M, Liu Q, et al. Green Chem., 2020, 22:1630-1638 doi: 10.1039/C9GC03622A
25. [25]
  Yu L, Huang S, Miao S, et al. Chem. Eur. J., 2015, 21(3):1048-1054 doi: 10.1002/chem.201404817
26. [26]
  Phung T K, Proietti Hernández L, Lagazzo A, et al. Appl. Catal. A, 2015, 493:77-89 doi: 10.1016/j.apcata.2014.12.047
27. [27]
  Feng R, Hu X, Yan X, et al. Microporous Mesoporous Mater., 2017, 241:89-97 doi: 10.1016/j.micromeso.2016.11.035
28. [28]
  Emeis C A. J. Catal., 1993, 141(2):347-354 doi: 10.1006/jcat.1993.1145
29. [29]
  Bevilacqua M, Montanari T, Finocchio E, et al. Catal. Today, 2006, 116(2):132-142 doi: 10.1016/j.cattod.2006.01.024
30. [30]
  Rostamizadeh M, Taeb A. J. Ind. Eng. Chem., 2015, 27:297-306 doi: 10.1016/j.jiec.2015.01.004
31. [31]
  Gil B, Mokrzycki Ł, Sulikowski B, et al. Catal. Today, 2010, 152(1/2/3/4):24-32
32. [32]
  ZHAI Yan-Liang, ZHANG Shao-Long, ZHANG Luo-Min, et al. Acta Phys.-Chim. Sin., 2019, 35(11):1248-1258
33. [33]
  Qin Z, Lakiss L, Gilson J P, et al. Chem. Mater., 2013, 25(14):2759-2766 doi: 10.1021/cm400719z
34. [34]
  Qin Z, Pinard L, Benghalem M A, et al. Chem. Mater., 2019, 31(13):4639-4648 doi: 10.1021/acs.chemmater.8b04970
35. [35]
  Sun X, Mueller S, Liu Y, et al. J. Catal., 2014, 317:185-197 doi: 10.1016/j.jcat.2014.06.017
36. [36]
  Feng R, Yan X, Hu X, et al. Appl. Catal. A, 2020, 592:117429-117440 doi: 10.1016/j.apcata.2020.117429
37. [37]
  Bleken F L, Chavan S, Olsbye U, et al. Appl. Catal. A, 2012, 447-448:178-185 doi: 10.1016/j.apcata.2012.09.025
38. [38]
  Müller S, Liu Y, Vishnuvarthan M, et al. J. Catal., 2015, 325:48-59 doi: 10.1016/j.jcat.2015.02.013
39. [39]
  Wu Z, Zhao K, Zhang Y, et al. Ind. Eng. Chem. Res., 2019, 58(25):10737-10749 doi: 10.1021/acs.iecr.9b00502
40. [40]
  Sugimoto M, Katsuno H, Takatsu K, et al. Zeolites, 1987, 7(6):503-507 doi: 10.1016/0144-2449(87)90087-X
41. [41]
  Cai D, Wang N, Chen X, et al. Nanoscale, 2019, 11:8096-8101 doi: 10.1039/C8NR10371B
42. [42]
  Khare R, Millar D, Bhan A. J. Catal., 2015, 321:23-32 doi: 10.1016/j.jcat.2014.10.016
43. [43]
  Carr R T, Neurock M, Iglesia E. J. Catal., 2011, 278(1):78-93 doi: 10.1016/j.jcat.2010.11.017
44. [44]
  Ono Y, Mori T. J. Chem. Soc. Faraday Trans., 1981, 77:2209-2221 doi: 10.1039/f19817702209
45. [45]
  Gayubo A G, Alonso A, Valle B, et al. Chem. Eng. J., 2011, 167(1):262-277 doi: 10.1016/j.cej.2010.12.058
46. [46]
  Zhang J, Zhang H, Yang X, et al. J. Nat. Gas Chem., 2011, 20(3):266-270 doi: 10.1016/S1003-9953(10)60183-1
47. [47]
  Sazama P, Wichterlova B, Dedecek J, et al. Microporous Mesoporous Mater., 2011, 143(1):87-96 doi: 10.1016/j.micromeso.2011.02.013
48. [48]
  Feng R, Yan X, Hu X, et al. J. Porous Mater., 2018, 25(6):1743-1756 doi: 10.1007/s10934-018-0587-2
49. [49]
  Jiang L, Li C, Xu M, et al. J. Chin. J. Chem. Eng., 2018, 26(10):2102-2111 doi: 10.1016/j.cjche.2018.09.010
50. [50]
  Yang Y, Sun C, Du J, et al. Catal. Commun., 2012, 24:44-47 doi: 10.1016/j.catcom.2012.03.013
51. [51]
  Li J, Liu M, Guo X, et al. Ind. Eng. Chem. Res., 2018, 57(24):8190-8199 doi: 10.1021/acs.iecr.8b00513
52. [52]
  Yaripour F, Shariatinia Z, Sahebdelfar S, et al. Microporous Mesoporous Mater., 2015, 203:41-53 doi: 10.1016/j.micromeso.2014.10.024
53. [53]
  Ding J, Jia Y, Chen P, et al. Chem. Eng. J., 2019, 361:588-598 doi: 10.1016/j.cej.2018.12.108
54. [54]
  Li J, Liu M, Guo X, et al. J. Energy Chem., 2018, 27(4):1225-1230 doi: 10.1016/j.jechem.2017.08.018
55. [55]
  Zhang L, Song Y, Li G, et al. RSC Adv., 2015, 5:61354-61363 doi: 10.1039/C5RA09561A
1. [1]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
2. [2]
  Xinyu You , Xin Zhang , Shican Jiang , Yiru Ye , Lin Gu , Hexun Zhou , Pandong Ma , Jamal Ftouni , Abhishek Dutta Chowdhury . Efficacy of Ca/ZSM-5 zeolites derived from precipitated calcium carbonate in the methanol-to-olefin process. Chinese Journal of Structural Chemistry, 2024, 43(4): 100265-100265. doi: 10.1016/j.cjsc.2024.100265
3. [3]
  Luyan Shi , Ke Zhu , Yuting Yang , Qinrui Liang , Qimin Peng , Shuqing Zhou , Tayirjan Taylor Isimjan , Xiulin Yang . Phytic acid-derivative Co₂B-CoPO_x coralloidal structure with delicate boron vacancy for enhanced hydrogen generation from sodium borohydride. Chinese Chemical Letters, 2024, 35(4): 109222-. doi: 10.1016/j.cclet.2023.109222
4. [4]
  Runze Liu , Yankai Bian , Weili Dai . Qualitative and quantitative analysis of Brønsted and Lewis acid sites in zeolites: A combined probe-assisted 1H MAS NMR and NH3-TPD investigation. Chinese Journal of Structural Chemistry, 2024, 43(4): 100250-100250. doi: 10.1016/j.cjsc.2024.100250
5. [5]
  Qian Wang , Yeping Bian , Gagan Dhawan , Wei Zhang , Alexander E. Sorochinsky , Ata Makarem , Vadim A. Soloshonok , Jianlin Han . FDA approved fluorine-containing drugs in 2023. Chinese Chemical Letters, 2024, 35(11): 109780-. doi: 10.1016/j.cclet.2024.109780
6. [6]
  Junying LI , Xinyan CHEN , Xihui DIAO , Muhammad Yaseen , Chao CHEN , Hao WANG , Chuansong QI , Wei LI . Chiral fluorescent sensor Tb³⁺@Cd-CP based on camphoric acid for the enantioselective recognition of R- and S-propylene glycol. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2497-2504. doi: 10.11862/CJIC.20240084
7. [7]
  Qiang Fu , Shouhong Sun , Kangzhi Lu , Ning Li , Zhanhua Dong . Boron-doped carbon dots: Doping strategies, performance effects, and applications. Chinese Chemical Letters, 2024, 35(7): 109136-. doi: 10.1016/j.cclet.2023.109136
8. [8]
  Qihang Wu , Hui Wen , Wenhai Lin , Tingting Sun , Zhigang Xie . Alkyl chain engineering of boron dipyrromethenes for efficient photodynamic antibacterial treatment. Chinese Chemical Letters, 2024, 35(12): 109692-. doi: 10.1016/j.cclet.2024.109692
9. [9]
  Jiajun Lu , Zhehui Liao , Tongxiang Cao , Shifa Zhu . Synergistic Brønsted/Lewis acid catalyzed atroposelective synthesis of aryl-β-naphthol. Chinese Chemical Letters, 2025, 36(1): 109842-. doi: 10.1016/j.cclet.2024.109842
10. [10]
  Boran Cheng , Lei Cao , Chen Li , Fang-Yi Huo , Qian-Fang Meng , Ganglin Tong , Xuan Wu , Lin-Lin Bu , Lang Rao , Shubin Wang . Fluorine-doped carbon quantum dots with deep-red emission for hypochlorite determination and cancer cell imaging. Chinese Chemical Letters, 2024, 35(6): 108969-. doi: 10.1016/j.cclet.2023.108969
11. [11]
  Yu-Yu Tan , Lin-Heng He , Wei-Min He . Copper-mediated assembly of SO₂F group via radical fluorine-atom transfer strategy. Chinese Chemical Letters, 2024, 35(9): 109986-. doi: 10.1016/j.cclet.2024.109986
12. [12]
  Jia-Ru Li , Ning Li , Li-Ling He , Jun He . Fluorine-functionalized zirconium-organic cages for efficient photocatalytic oxidation of thioanisole. Chinese Chemical Letters, 2025, 36(1): 109934-. doi: 10.1016/j.cclet.2024.109934
13. [13]
  Qianqian Song , Yunting Zhang , Jianli Liang , Si Liu , Jian Zhu , Xingbin Yan . Boron nitride nanofibers enhanced composite PEO-based solid-state polymer electrolytes for lithium metal batteries. Chinese Chemical Letters, 2024, 35(6): 108797-. doi: 10.1016/j.cclet.2023.108797
14. [14]
  Yang Yang , Jing-Li Luo , Xian-Zhu Fu . Water-oxidation intermediates enabling electrochemical propylene epoxidation. Chinese Journal of Structural Chemistry, 2024, 43(5): 100269-100269. doi: 10.1016/j.cjsc.2024.100269
15. [15]
  Tingting Huang , Zhuanlong Ding , Hao Liu , Ping-An Chen , Longfeng Zhao , Yuanyuan Hu , Yifan Yao , Kun Yang , Zebing Zeng . Electron-transporting boron-doped polycyclic aromatic hydrocarbons: Facile synthesis and heteroatom doping positions-modulated optoelectronic properties. Chinese Chemical Letters, 2024, 35(4): 109117-. doi: 10.1016/j.cclet.2023.109117
16. [16]
  Jiaojiao Liang , Youming Peng , Zhichao Xu , Yufei Wang , Menglong Liu , Xin Liu , Di Huang , Yuehua Wei , Zengxi Wei . Boron/phosphorus co-doped nitrogen-rich carbon nanofiber with flexible anode for robust sodium-ion battery. Chinese Chemical Letters, 2025, 36(1): 110452-. doi: 10.1016/j.cclet.2024.110452
17. [17]
  Xiao Yu , Dongyue Cui , Mengmeng Wang , Zhaojin Wang , Mengzhu Wang , Deshuang Tu , Vladimir Bregadze , Changsheng Lu , Qiang Zhao , Runfeng Chen , Hong Yan . Boron cluster-based TADF emitter via through-space charge transfer enabling efficient orange-red electroluminescence. Chinese Chemical Letters, 2025, 36(3): 110520-. doi: 10.1016/j.cclet.2024.110520
18. [18]
  Zhuangzhuang Zhang , Yaru Qiao , Jun Zhao , Dai-Huo Liu , Mengmin Jia , Hongwei Tang , Liang Wang , Dongmei Dai , Bao Li . Fluorine-doped K_0.39Mn_0.77Ni_0.23O_1.9F_0.1 microspheres with highly reversible oxygen redox reaction for potassium-ion battery cathode. Chinese Chemical Letters, 2025, 36(3): 109907-. doi: 10.1016/j.cclet.2024.109907
19. [19]
  Zhen Liu , Zhi-Yuan Ren , Chen Yang , Xiangyi Shao , Li Chen , Xin Li . Asymmetric alkenylation reaction of benzoxazinones with diarylethylenes catalyzed by B(C₆F₅)₃/chiral phosphoric acid. Chinese Chemical Letters, 2024, 35(5): 108939-. doi: 10.1016/j.cclet.2023.108939
20. [20]
  Wenhao Yan , Shuaiya Xue , Xuerui Zhao , Wei Zhang , Jian Li . Hexagonal boron nitride based slippery liquid infused porous surface with anti-corrosion, anti-contaminant and anti-icing properties for protecting magnesium alloy. Chinese Chemical Letters, 2024, 35(4): 109224-. doi: 10.1016/j.cclet.2023.109224

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(808)
HTML views(80)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142