Citation: LIU Hong-Juan, WEI Xiao-Kang, YI Rui, HUANG Chao, ZHU Bi-Xue. Synthesis and Methanol Vapor Adsorption of Hg(Ⅱ)/Cd(Ⅱ) Complexes Derived from a Bis-pyridylhydrazone Schiff Base[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(9): 1631-1638. doi: 10.11862/CJIC.2020.203 shu

Synthesis and Methanol Vapor Adsorption of Hg(Ⅱ)/Cd(Ⅱ) Complexes Derived from a Bis-pyridylhydrazone Schiff Base

Key Laboratory of Macrocycle and Supramolecular Chemistry, Guizhou University, Guiyang 550025, China

Corresponding author: ZHU Bi-Xue, bxzhu@gzu.edu.cn
Received Date: 6 January 2020
Revised Date: 24 May 2020

Figures(6)

A bis-pyridyhylhydrazone Schiff base ligand (L) was synthesized and characterized by ¹H NMR, MS, FT-IR and elemental analysis. Two complexes, {[Cd(L)₂Cl₂]·2DMF·6H₂O}_n (1) and[Hg(L)Cl₂]_n (2), were synthesized from the reaction of the ligand with CdCl₂ and HgCl₂, respectively. The structures of the ligand and two complexes were determined via X-ray single crystal diffraction, which show that both of the two complexes have 1D-chain structures. Furthermore, the thermal stabilities and vapor adsorption for MeOH at room temperature were investigated. The results demonstrate that complex 2 has a better thermal stability than complex 1, while complex 1 has a better adsorption for MeOH because of its pore structures.
- pyridylhydrazone,
- complex,
- crystal structure,
- 1D chain,
- adsorption
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