Citation: ZHU De-Cheng, CHEN Yi-Xin, JI Chong-Xing, ZHU Xian-Yu, LI De-Cheng. Effect of Pickling Treatment on Structure, Morphology and Electrochemical Performance of NaEuTiO₄[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(9): 1690-1700. doi: 10.11862/CJIC.2020.201 shu

Effect of Pickling Treatment on Structure, Morphology and Electrochemical Performance of NaEuTiO₄

College of Energy, Soochow University, Suzhou, Jiangsu 215006, China

Corresponding author: LI De-Cheng, lidecheng@suda.edu.cn
Received Date: 8 March 2020
Revised Date: 25 June 2020

Figures(15)

NaEuTiO₄ (NETO) with layered perovskite structure was synthesized by sol-gel method. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS), cyclic voltammogram (CV) and charge-discharge test were used to characterize its structural, morphological and electrochemical properties of the NETO treated with dilute nitric acid. The results show that there was an ion exchange path of Na⁺→H⁺→Li⁺ for NETO beside the reported Na⁺→Li⁺ path. That is to say, Na⁺ could be exchanged with H⁺ in dilute acid to form HETO. Then HETO could transform to LETO by means of charge-discharge cycling. The LETO obtained by this route also had an excellent electrochemical performance. NETO-12 h showed the best electrochemical properties with the reversible capacity of about 213.2 mAh·g^-1 after 300 cycles. Moreover, it exhibited a good rate capability.
- lithium-ion battery,
- anode material,
- rare earth,
- titanium based,
- pickling
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通讯作者: 陈斌, bchen63@163.com

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Effect of Pickling Treatment on Structure, Morphology and Electrochemical Performance of NaEuTiO4

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通讯作者: 陈斌, bchen63@163.com

Effect of Pickling Treatment on Structure, Morphology and Electrochemical Performance of NaEuTiO₄