Citation: CAO Yang-Zheng, XU Hao, PAN Wei, ZENG Xiang-Hua, ZHANG Jun-Yong, GUO Hai-Yang, LIAO Jin-Sheng, LIU Sui-Jun, XIE Jing-Li. Fabrication of Hybrid Materials Containing Keggin-Type Polyoxometalates Units and 2-Picolinic Acid: Synthesis, Structures and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(9): 1613-1619. doi: 10.11862/CJIC.2020.196 shu

Fabrication of Hybrid Materials Containing Keggin-Type Polyoxometalates Units and 2-Picolinic Acid: Synthesis, Structures and Properties

CAO Yang-Zheng ^1,2,3,4 ,
XU Hao ^2,3 ,
PAN Wei ^2,3 ,
ZENG Xiang-Hua ² ,
ZHANG Jun-Yong ^2,, ,
GUO Hai-Yang ² ,
LIAO Jin-Sheng ^1,, ,
LIU Sui-Jun ^1,, ,
XIE Jing-Li ^1,2,3,4,,

1.
School of Chemistry and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China
2.
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China
3.
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
4.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: ZHANG Jun-Yong, zhangjy@mail.zjxu.edu.cn LIAO Jin-Sheng, jsliao1209@126.com LIU Sui-Jun, sjliu@jxust.edu.cn XIE Jing-Li, jlxie@mail.zjxu.edu.cn
Received Date: 8 March 2020
Revised Date: 15 May 2020

Figures(6)

2-Picolinic acid (2-PA) has been integrated with Keggin-type[SiW₁₂O₄₀]^4- and[PMo₁₂O₄₀]^3- polyoxometalates units to achieve final products:H₂[(CH₃)₄N]₆[Cu(2-PA)₂(SiW₁₂O₄₀)₂] (1) and (H₃O)[Cu₆(2-PA)₉(PMo₁₂O₄₀)(NO₃)] (2). These two inorganic-organic hybrid compounds have been characterized by single-crystal X-ray diffraction, infrared spectroscopy and powder X-ray diffraction. Compound 1 crystalizes in monoclinic system with space group P2₁/c, and the asymmetric unit is composed of one Cu(Ⅱ) ion, two 2-PA ligands and two[SiW₁₂O₄₀]^4- Keggin-type polyoxometalate anions. Compound 1 is a zero-dimensional structure. The cyclic voltammogram of 1-CPE(the bulk-modified carbon paste electrode) showed that the half-wave potentials (E_1/2=(E_cp+E_ap)/2) of Ⅰ-Ⅰ', Ⅱ-Ⅱ' and Ⅲ-Ⅲ' were -270, -516 and -708 mV, respectively, when the sweep speed was 100 mV·s^-1. Compound 2 crystallizes in trigonal system with space group R3c, there are two crystallographically independent Cu ions with two kinds of coordination modes in 2 and it is a two-dimensional networks containing hexanuclear clusters.
- polyoxometalate,
- 2-picolinic acid,
- Keggin unit,
- crystal structure
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