Citation: KANG Ya-Chao, HUANG Yuan-Yuan, SUN Hua-Zhen, ZHENG Wan-Li, MA Xian-Li, JIANG Dong-Li. Nitric Acid Assisted Synthesis of Water-Soluble Green Fluorescent Carbon Dots for pH Measurement and Fe³⁺ Ions Detection[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(9): 1744-1752. doi: 10.11862/CJIC.2020.194 shu

Nitric Acid Assisted Synthesis of Water-Soluble Green Fluorescent Carbon Dots for pH Measurement and Fe³⁺ Ions Detection

1.
Pharmacy College, Guilin Medical University, Guilin, Guangxi 541100, China
2.
College of Materials Science and Engineering, Guilin University of Technology, Guilin, Guangxi 541004, China

Corresponding author: JIANG Dong-Li, auqfai@glmc.edu.cn
Received Date: 27 December 2019
Revised Date: 22 April 2020

Figures(5)

A green fluorescent carbon dots (CDs) was synthesized from citric acid, formamide and concentrated nitric acid. The phase compositions, morphologies and fluorescence properties were characterized. The applications of the as-prepared CDs in ion detection and fluorescence imaging were studied as well. The results show that the as-synthesized CDs presented a good water-solubility and emitted bright green fluorescence with an excitation-independent photoluminescence (PL) behavior when the excitation wavelength ranged from 360 to 460 nm. The quantum yield was as high as 44.2%. Meanwhile, the green fluorescent CDs was pH sensitive and the normalized fluorescence intensity was linearly proportional to the pH values of solutions in a range of 4.5~8.5. Furthermore, the CDs also exhibited excellent selective response to Fe³⁺ with a good linear relationship between the fluorescence quenching efficiency (I₀/I) and the Fe³⁺ concentration in a range of 0~1 000 μmol·L^-1, and the detection limit was calculated to be 9.8 μmol·L^-1.
- green fluorescent carbon dots,
- water-soluble,
- fluorescent imaging material,
- iron ion detection,
- pH response
1. [1]
  Li N, Liang X F, Wang L L, et al. J. Nanopart. Res., 2012, 14(10):1-9
2. [2]
  Zhang B, Maimaiti H, Zhang D D, et al. J. Photochem. Photo-biol. A, 2017, 345:54-62 doi: 10.1016/j.jphotochem.2017.05.031
3. [3]
  Chen J, Liu W, Mao L H, et al. J. Mater. Sci., 2014, 49(21):7391-7398 doi: 10.1007/s10853-014-8413-y
4. [4]
  Chen P C, Chen Y N, Hsu P C, et al. Chem. Commun., 2013, 49(16):1639-1641 doi: 10.1039/c3cc38486a
5. [5]
  Xiong Y, Schneider J L, Reckmeier C J, et al. Nanoscale, 2017, 9(32):11730-11738 doi: 10.1039/C7NR03648E
6. [6]
  Jun Y W, Kim H R, Reo Y J, et al. Chem. Sci., 2017, 8(11):7696-7704 doi: 10.1039/C7SC03362A
7. [7]
  Yu C, Peng R Y. Mil. Med. Res., 2018, 4(1):24
8. [8]
  Gao D, Liu X L, Jiang D L, et al. Sens. Actuator B, 2018, 277:373-380 doi: 10.1016/j.snb.2018.09.031
9. [9]
  Ding H, Yu S B, Wei J S, et al. ACS Nano, 2016, 10(1):484-491 doi: 10.1021/acsnano.5b05406
10. [10]
  LU Si-Yu, YANG Bai. Acta Polym. Sin., 2017(7):1200-1206
11. [11]
  Xu Q, Zhang M R, Liu Y, et al. New J. Chem., 2018, 42(12):10400-10405 doi: 10.1039/C8NJ01639A
12. [12]
  Miao X, Qu D, Yang D X, et al. Adv. Mater., 2017, 30(1):1704740
13. [13]
  Mu X Y, Li Q, Dong P, et al. Biosens. Bioelectron., 2013, 49:249-255 doi: 10.1016/j.bios.2013.05.019
14. [14]
  Senol M A, Onganer Y, Meral K. Sens. Actuator B, 2017, 239:343-351 doi: 10.1016/j.snb.2016.08.025
15. [15]
  Bazmandegan-Shamili A, Haji Shabani A M, Dadfarnia S, et al. J. Iran. Chem. Soc., 2017, 4(4):843-851
16. [16]
  Su C K, Chen Y T, Sun Y C. Microchem. J., 2019, 146:835-841 doi: 10.1016/j.microc.2019.02.015
17. [17]
  Wang R, Wang W, Ren H, et al. Biosens. Bioelectron., 2014, 57:179-185 doi: 10.1016/j.bios.2014.01.056
18. [18]
  Węgiel K, Robak J, Baś B. RSC Adv., 2017, 7(36):22027-22033 doi: 10.1039/C7RA03019C
19. [19]
  Zhao X W, Zhang J L, Shi L H, et al. RSC Adv., 2017, 7(67):42159-42167 doi: 10.1039/C7RA07002K
20. [20]
  Zan M H, Rao L, Huang H M, et al. Sens. Actuator B, 2018, 262:555-561 doi: 10.1016/j.snb.2017.12.177
21. [21]
  Qu S N, Wang X Y, Lu Q P, et al. Angew. Chem. Int. Ed., 2012, 51(49):12215-12218 doi: 10.1002/anie.201206791
22. [22]
  Wu M B, Wang Y, Wu W T, et al. Carbon, 2014, 78:480-489 doi: 10.1016/j.carbon.2014.07.029
23. [23]
  ZHANG Xiao-Zhe, ZHANG Wen-Jun, ZHANG Zu-Xing, et al. Chinese J. Inorg. Chem., 2015, 31(1):1-6
24. [24]
  Miao X, Yan X L, Qu D, et al. ACS Appl. Mater. Interfaces, 2017, 9(22):18549-18556 doi: 10.1021/acsami.7b04514
25. [25]
  Wang H, Sun C, Chen X R, et al. Nanoscale, 2017, 9(5):1909-1915 doi: 10.1039/C6NR09200D
26. [26]
  Shang J Z, Ma L, Li J W, et al. Sci. Rep., 2012, 2(6108):792
27. [27]
  Liu W, Diao H P, Chang H H, et al. Sens. Actuator B, 2017, 241:190-198 doi: 10.1016/j.snb.2016.10.068
28. [28]
  Zhu S J, Meng Q N, Wang L et al. Angew. Chem., 2013, 125(14):4045-4049 doi: 10.1002/ange.201300519
29. [29]
  Das P, Bose M, Ganguly S, et al. Nanotechnology, 2017, 28(19):195501 doi: 10.1088/1361-6528/aa6714
30. [30]
  Zhai X Y, Zhang P, Liu C J, et al. Chem. Commun., 2012, 48(64):7955-7957 doi: 10.1039/c2cc33869f
31. [31]
  Chen J L, Yan X P. Chem. Commun., 2011, 47(11):3135-3137 doi: 10.1039/c0cc03999c
32. [32]
  Jia X F, Li J, Wang E. Nanoscale, 2012, 4(18):5572-5575 doi: 10.1039/c2nr31319g
33. [33]
  Geethanjali H S, Nagaraja D, Melavanki R M, et al. J. Lumin., 2015, 167:216-221 doi: 10.1016/j.jlumin.2015.06.040
34. [34]
  Liu Q, Huang A, Wang N, et al. J. Lumin., 2015, 161:374-381 doi: 10.1016/j.jlumin.2015.01.045
35. [35]
  Yang R, Guo X F, Jia L H, et al. Appl. Surf. Sci., 2017, 423:426-432 doi: 10.1016/j.apsusc.2017.05.252
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Nitric Acid Assisted Synthesis of Water-Soluble Green Fluorescent Carbon Dots for pH Measurement and Fe3+ Ions Detection

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通讯作者: 陈斌, bchen63@163.com

Nitric Acid Assisted Synthesis of Water-Soluble Green Fluorescent Carbon Dots for pH Measurement and Fe³⁺ Ions Detection