Citation: LÜ Guang-Yu, WANG Ting-Wei, WANG Wen-Yuan, ZHANG Rui, LIU Jian. Synthesis and Properties of Luminescent Materials Based on Pinene-Substituted Phenol-Pyridyl Aza-fluoroboric Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(9): 1669-1674. doi: 10.11862/CJIC.2020.189 shu

Synthesis and Properties of Luminescent Materials Based on Pinene-Substituted Phenol-Pyridyl Aza-fluoroboric Complexes

College of Chemical Engineering, Nanjing Forestry University, Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Jiangsu Key Laboratory of Biomass Energy and Materials, Nanjing 210037, China

Corresponding author: ZHANG Rui, liu.jian@njfu.edu.cn LIU Jian, zhangrui@njfu.edu.cn
Received Date: 17 February 2020
Revised Date: 31 March 2020

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A series of blue-emission materials based on phenol-pyridyl aza-fluoroboric complexes have been developed and investigated. The natural chiral building block (α-pinene) was successfully introduced into the present fluoroboric complexes, resulting in enhancement of fluorescence quantum efficiency of the complexes. Moreover, the effect of auxiliary substituents on the optical properties of these chiral complexes has also been investigated, involving absorption and emission spectra, photoluminescence decay, as well as fluorescence quantum efficiency. Based on the chirality of pinene group, we also investigated the circular dichroism spectra of the presented enantiomers.
- fluoroboric complex,
- luminescent material,
- pinene
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