Citation: SUN Zhi-Yu, CAO Shuai, HUANG Xiao-Qin, FAN Xiao-Ming, YANG Ze-Heng, ZHANG Wei-Xin. Preparation of Co₃O₄@NiMn-LDH Heterostructured Arrays as Efficient Oxygen Evolution Electrocatalyst[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(10): 1899-1905. doi: 10.11862/CJIC.2020.188 shu

Preparation of Co₃O₄@NiMn-LDH Heterostructured Arrays as Efficient Oxygen Evolution Electrocatalyst

School of Chemistry and Chemical Engineering, Hefei University of Technology, Anhui Provincial Key Laboratory of Advanced Catalytic Materials and Reaction Engineering, Hefei 230009, China

Corresponding author: FAN Xiao-Ming, xmfan@hfut.edu.cn ZHANG Wei-Xin, wxzhang@hfut.edu.cn
Received Date: 15 April 2020
Revised Date: 7 June 2020

Figures(5)

In this paper, we report the rational design and preparation of a new type of high-performance oxygen evolution electrocatalyst, namely 3D heterostructured Co₃O₄@NiMn-LDH (layered double metal hydroxide) arrays supported on Ni foam (Co₃O₄@NiMn-LDH/NF). It was prepared via facile two-step hydrothermal reactions. Compared with Co₃O₄, NiMn-LDH and traditional RuO₂ electrocatalysts, the as-prepared Co₃O₄@NiMn-LDH/NF presents better electrocatalytic oxygen evolution performance, achieving a low overpotential of 282 mV at 50 mA·cm^-2 with a Tafel slope of 64 mV·dec^-1 in 1 mol·L^-1 KOH solution. Through designing effective interface engineering, the Co₃O₄@NiMn-LDH/NF combines synergistically the excellent electrocatalytic activity of Co₃O₄ and NiMn-LDH. The Co₃O₄ nanowire array based on Ni foam as a core structure with abundant void spaces not only exposes more active sites, but also ensures easy diffusion of electrolyte and fast release of gas products. And the NiMn-LDH nanosheets on the Co₃O₄ nanowire array provide rich hydrophilic groups and active sites for easy access of water molecules, thus facilitating efficient oxygen evolution reaction.
- electrocatalytic oxygen evolution,
- Co₃O₄@NiMn-LDH,
- hydrothermal,
- heterostructure
1. [1]
  Shi Q R, Zhu C Z, Du D, et al. Chem. Soc. Rev., 2019, 48:3181-3192 doi: 10.1039/C8CS00671G
2. [2]
  Suen N T, Hung S F, Quan Q, et al. Chem. Soc. Rev., 2017, 46(2):337-365
3. [3]
  Hu C L, Zhang L, Zhao Z J, et al. Adv. Mater., 2017, 29:1701820 doi: 10.1002/adma.201701820
4. [4]
  ZHOU Qi, DUAN De-Dong, FENG Ji-Wei. Chinese J. Inorg. Chem., 2019, 35(12):2301-2310
5. [5]
  Zhong D Z, Zhang L, Li C C, et al. J. Mater. Chem. A, 2018, 6:16810-16817 doi: 10.1039/C8TA04721A
6. [6]
  Yu H J, Shang L, Bian T, et al. Adv. Mater., 2016, 28(25):5080-5086 doi: 10.1002/adma.201600398
7. [7]
  Ma X J, Kong L B, Zhang W B, et al. Electrochim. Acta, 2014, 130:660-669 doi: 10.1016/j.electacta.2014.03.080
8. [8]
  Xu Y Q, Zang W F, Li Y G, et al. J. Energy Chem., 2020, 43:52-57 doi: 10.1016/j.jechem.2019.08.006
9. [9]
  LiuY, Fan D Q, Chen Z P, et al. Sci. Bull., 2020, 65:460-466 doi: 10.1016/j.scib.2019.12.020
10. [10]
  Zhong Y T, Pan Z H, Wang X, et al. Adv. Sci., 2019, 6(11):1802243 doi: 10.1002/advs.201802243
11. [11]
  Liu J, Wang J S, Zhang B, et al. ACS Appl. Mater. Interfaces, 2017, 9(18):15364-15372 doi: 10.1021/acsami.7b00019
12. [12]
  Lv L, Yang Z X, Chen K, et al. Adv. Energy Mater., 2019, 9(17):1803358 doi: 10.1002/aenm.201803358
13. [13]
  Song F, Hu X L. Nat. Commun., 2014, 5:4477 doi: 10.1038/ncomms5477
14. [14]
  Zhao Y X, Chang C, Teng F, et al. Adv. Energy Mater., 2017, 7:1700005-1700011 doi: 10.1002/aenm.201700005
15. [15]
  Jia D D, Gao H Y, Xing L W, et al. Inorg. Chem., 2019, 58(10):6758-6764 doi: 10.1021/acs.inorgchem.9b00162
16. [16]
  Liu J, Wang J S, Zhang B, et al. ACS Appl. Mater. Interfaces, 2017, 9(18):15364-15372 doi: 10.1021/acsami.7b00019
17. [17]
  Yuan Y, Zhou J, Rafiq M I, et al. Electrochim. Acta, 2019, 295:82-91 doi: 10.1016/j.electacta.2018.10.090
18. [18]
  Guo X L, Zhang J M, Xu W N, et al. J. Mater. Chem. A, 2017, 5:20579-20587 doi: 10.1039/C7TA04382A
19. [19]
  Guo X L, Liu X Y, Hao X D, et al. Electrochim. Acta, 2016, 194:179-186 doi: 10.1016/j.electacta.2016.02.080
20. [20]
  Wang Y C, Zhou T, Jiang K, et al. Adv. Energy Mater., 2014, 4(16):1400696 doi: 10.1002/aenm.201400696
21. [21]
  Li H Y, Chen S M, Zhang Y, et al. Nat. Commun., 2018, 9:2452 doi: 10.1038/s41467-018-04888-0
22. [22]
  Xu C H, Guo X L, Zheng T X, et al. J. Mater. Chem. A, 2018, 6:10243-10252 doi: 10.1039/C8TA02608D
23. [23]
  Wu H T, Sun W, Shen J R, et al. Nanoscale, 2018, 10(21):10221-10231 doi: 10.1039/C8NR02376J
24. [24]
  Xu L, Jiang Q Q, Xiao Z H, et al. Angew. Chem. Int. Ed., 2016, 55(17):5277-5281 doi: 10.1002/anie.201600687
25. [25]
  Dong D, Liu Y, Li J H, et al. Part. Part. Syst. Char., 2016, 33(12):887-895 doi: 10.1002/ppsc.201600191
26. [26]
  Jia G, Hu Y F, Qian Q F, et al. ACS Appl. Mater. Interfaces, 2016, 8:14527-14534 doi: 10.1021/acsami.6b02733
27. [27]
  Cheng F R, Fan X M, Chen X K, et al. Ind. Eng. Chem. Res., 2019, 58:16581-16587 doi: 10.1021/acs.iecr.9b02626
28. [28]
  LIU Guang, YAO Rui, ZHAO Yong, et al. Chinese J. Inorg. Chem., 2018, 34(8):1494-1500
29. [29]
  Guo X L, Hu X L, Wu D, et al. ACS Appl. Mater. Interfaces, 2019, 11:21506-21514 doi: 10.1021/acsami.9b04217
30. [30]
  Zhang H, Li X, Haehnel A, et al. Adv. Funct. Mater., 2018, 28(14):1706847-1706858 doi: 10.1002/adfm.201706847
1. [1]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
2. [2]
  Liyong DU , Yi LIU , Guoli YANG . Preparation and triethylamine sensing performance of ZnSnO₃/NiO heterostructur. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 729-740. doi: 10.11862/CJIC.20240404
3. [3]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
4. [4]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
5. [5]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
6. [6]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . 软模板法诱导Cu/Al₂O₃深孔道结构促进等离子催化CO₂加氢制二甲醚. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
7. [7]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
8. [8]
  Xinyu Miao , Hao Yang , Jie He , Jing Wang , Zhiliang Jin . 调整Keggin型多金属氧酸盐电子结构构建S型异质结用于光催化析氢. Acta Physico-Chimica Sinica, 2025, 41(6): 100051-. doi: 10.1016/j.actphy.2025.100051
9. [9]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
10. [10]
  Yaping Li , Sai An , Aiqing Cao , Shilong Li , Ming Lei . The Application of Molecular Simulation Software in Structural Chemistry Education: First-Principles Calculation of NiFe Layered Double Hydroxide. University Chemistry, 2025, 40(3): 160-170. doi: 10.12461/PKU.DXHX202405185
11. [11]
  Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co₉S₈/Ni₃S₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
12. [12]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
13. [13]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
14. [14]
  Jinwang Wu , Qijing Xie , Chengliang Zhang , Haifeng Shi . 自旋极化增强ZnFe_1.2Co_0.8O₄/BiVO₄ S型异质结光催化性能降解四环素. Acta Physico-Chimica Sinica, 2025, 41(5): 100050-. doi: 10.1016/j.actphy.2025.100050
15. [15]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
16. [16]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
17. [17]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
18. [18]
  Yadan Luo , Hao Zheng , Xin Li , Fengmin Li , Hua Tang , Xilin She . 调节O,S共掺杂C₃N₄中的活性氧生成以促进光催化降解微塑料. Acta Physico-Chimica Sinica, 2025, 41(6): 100052-. doi: 10.1016/j.actphy.2025.100052
19. [19]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
20. [20]
  Kun Rong , Cuilian Wen , Jiansen Wen , Xiong Li , Qiugang Liao , Siqing Yan , Chao Xu , Xiaoliang Zhang , Baisheng Sa , Zhimei Sun . 层状MoS₂/Ti₃C₂T_x异质结光热转换材料用于太阳能驱动水蒸发. Acta Physico-Chimica Sinica, 2025, 41(6): 100053-. doi: 10.1016/j.actphy.2025.100053

Get Citation

PDF

XML

Metrics

PDF Downloads(35)
Abstract views(2252)
HTML views(692)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Co3O4@NiMn-LDH Heterostructured Arrays as Efficient Oxygen Evolution Electrocatalyst

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of Co₃O₄@NiMn-LDH Heterostructured Arrays as Efficient Oxygen Evolution Electrocatalyst