Citation: CHEN Shu-Xuan, JIA Li-Hua, GUO Xiang-Feng, ZHAO Zhen-Long, YANG Rui, WANG Xin. MOFs Self-Sacrifice Template Preparation and NO₂ Gas Sensing Performance of ZnO[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(9): 1639-1648. doi: 10.11862/CJIC.2020.187 shu

MOFs Self-Sacrifice Template Preparation and NO₂ Gas Sensing Performance of ZnO

1.
College of Chemistry & Chemical Engineering, Key Laboratory of Fine Chemicals of College of Heilongjiang Province, Qiqihar University, Qiqihar, Heilongjiang 161006, China
2.
College of Chemistry, Guangdong University of Petrochemical Technology, Maoming, Guangdong 525000, China

Corresponding author: JIA Li-Hua, jlh29@163.com; xfguo@163.com GUO Xiang-Feng, xfguo@163.com
Received Date: 8 January 2020
Revised Date: 9 June 2020

Figures(13)

An efficient self-sacrifice template method of Zn-MOF-74 was used to fabricate ZnO nanomaterials which exhibited selective and sensitive gas sensing response to NO₂. Herein, the precursor of Zn-MOF-74 was synthesized via solvothermal strategy, and subsequently calcinated at different temperatures to gain ZnO nanomaterials. The structure, morphology, and sensing property of ZnO nanomaterials were investigated using thermogravimetric-differential scanning calorimetry (TG-DSC), X-ray diffraction (XRD), infrared spectroscopy (FT-IR), X-ray photo-electron spectroscopy (XPS), nitrogen adsorption-desorption, scanning electron microscopy (SEM) and high power transmission electron microscopy (HRTEM). The results show that hexagonal columnar structure of ZnO₄₅₀, which was obtained from calcination of Zn-MOF-74 at 450℃, was stacked by nanosheets composed of nanoparticles with average size of 20 nm, and some organic functional groups remaining on the surface as well as the absorbed oxygen content was obviously higher than that of samples calcinated at 350 and 550℃. The response of the sensor based on ZnO 450 to 100 mL·m^-3 NO₂ reached 77.40 which was 6~105 times higher than that of the selective gases. In addition, the low detection limit was 0.1 mL·m^-3. Moreover, the response to NO₂ was remain unchanged in the coexistence of the gases such as SO₂, et al, indicating strong anti-interference ability. The sensor's excellent response to NO 2 is due to the high adsorbed oxygen content on the surface, and the large specific surface area and pore diameter, which are conducive to NO₂ adsorption, surface reaction and diffusion.
- metal-organic frameworks,
- self-sacrifice template method,
- ZnO,
- sensors,
- gas sensing,
- NO₂
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

MOFs Self-Sacrifice Template Preparation and NO2 Gas Sensing Performance of ZnO

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通讯作者: 陈斌, bchen63@163.com

MOFs Self-Sacrifice Template Preparation and NO₂ Gas Sensing Performance of ZnO