Citation: ZHOU Qi, LI Xin-Bao, LI Zhi-Yang. Composite Electrodes of Nano-Porous Ni-Mo Modified by RuO₂ and Electrocatalytic Property for Hydrogen Evolution[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(9): 1649-1658. doi: 10.11862/CJIC.2020.186 shu

Composite Electrodes of Nano-Porous Ni-Mo Modified by RuO₂ and Electrocatalytic Property for Hydrogen Evolution

ZHOU Qi ^1,2,, ,
LI Xin-Bao ² ,
LI Zhi-Yang ²

1.
State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China
2.
College of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China

Corresponding author: ZHOU Qi, zhouxq301@sina.com
Received Date: 4 February 2020
Revised Date: 12 June 2020

Figures(12)

The nano-porous Ni/RuO₂ and Ni-Mo/RuO₂ composite electrode material were prepared by de-alloying combined with deposition precipitation. The phase, element, morphology and structure, pore size and crystallinity of the electrode material were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), transmission electron microscope (TEM). The electrocatalytic hydrogen evolution of porous electrode was tested by linear sweep voltammetry, AC impedance and cyclic voltammetry. The analysis results showed that RuO₂ was cladded on the surface of the Ni-based alloy skeleton due to polycondensation. The addition of Mo enhanced the amorphization of the Ni-Mo alloy and promoted the refinement of the pore size of the porous skeleton to form a bicontinuous and porous nanostructure. The addition of Mo and RuO₂ and the increase of Mo content all improved the electrocatalytic hydrogen evolution performance. The nanoporous Ni_2.5Mo_2.5/RuO₂ composite electrode had a better electrocatalytic hydrogen evolution activity:at a current density of 50 mA·cm^-2, its hydrogen overpotential was 182 mV.
- nanostructures,
- dealloying,
- RuO₂,
- electrochemistry,
- water splitting
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沈阳化工大学材料科学与工程学院沈阳 110142

Composite Electrodes of Nano-Porous Ni-Mo Modified by RuO2 and Electrocatalytic Property for Hydrogen Evolution

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通讯作者: 陈斌, bchen63@163.com

Composite Electrodes of Nano-Porous Ni-Mo Modified by RuO₂ and Electrocatalytic Property for Hydrogen Evolution