Citation: XU Tian-Yang, ZHAO Ya-Li, LI Jia-Ming, SHI Zhong-Feng. Co(Ⅱ) Coordination Polymer Based on Bis(carboxyl) Dibenzylamine and Bis(imidazole) Biphenyl Ligands: Synthesis, Crystal Structure and Detection for Fe³⁺ Ions in Water[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(9): 1735-1743. doi: 10.11862/CJIC.2020.183 shu

Co(Ⅱ) Coordination Polymer Based on Bis(carboxyl) Dibenzylamine and Bis(imidazole) Biphenyl Ligands: Synthesis, Crystal Structure and Detection for Fe³⁺ Ions in Water

XU Tian-Yang ^1,2 ,
ZHAO Ya-Li ³ ,
LI Jia-Ming ^1,, ,
SHI Zhong-Feng ^1,2,,

1.
College of Petroleum and Chemical Engineering, Beibu Gulf University, Qinzhou, Guangxi 535011, China
2.
School of Chemistry and Pharmacy, Guangxi Normal University, Guilin, Guangxi 541004, China
3.
College of International Studies, Beibu Gulf University, Qinzhou, Guangxi 535011, China

Corresponding author: LI Jia-Ming, jmli@bbgu.edu.cn SHI Zhong-Feng, shizhongfeng01@163.com
Received Date: 20 December 2019
Revised Date: 5 April 2020

Figures(6)

A new Co(Ⅱ)-based coordination polymer (CP), namely {[Co(H₃bcba)(bdmi)]·H₂O}_n (1), where H₃bcba is 4, 4'-biscarboxyl-N, N-dibenzylamine and bdmi is 4, 4'-bis(2-methyl-1H-imidazol-1-yl)-1, 1'-biphenyl, has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, IR spectroscopy, elemental analysis, thermogravimetric and Hirshfeld surface analyses. X-ray diffraction crystallographic analyses show that the partly deprotonated H₃bcba ligand coordinates two Co (Ⅱ) ions with two carboxylate groups bending bidentate chelate modes, while bdmi serves as a μ₂-bridging ligand in 1, result in a 2D polymeric grid frameworks with a 4-connected (4, 4) topology. In the crystal, a 3D supramolecular architecture is further formed by O-H…O and N-H…O hydrogen bonds, C-H…O and C-H…N interactions, as well as C-H…π stacking in 1. Complex 1 showed intense luminescence in the solid state, and exhibited a high selectivity and sensitivity for Fe³⁺ ions through the fluorescence quenching effect in aqueous solution at room temperature.
- coordination polymer,
- luminescence property,
- fluorescence quenching effect,
- crystal structure,
- synthesis
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Co(Ⅱ) Coordination Polymer Based on Bis(carboxyl) Dibenzylamine and Bis(imidazole) Biphenyl Ligands: Synthesis, Crystal Structure and Detection for Fe3+ Ions in Water

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通讯作者: 陈斌, bchen63@163.com

Co(Ⅱ) Coordination Polymer Based on Bis(carboxyl) Dibenzylamine and Bis(imidazole) Biphenyl Ligands: Synthesis, Crystal Structure and Detection for Fe³⁺ Ions in Water