Citation: WANG Zhuang-Zhuang, LIU Sang-Xin, HOU Qi-Rui, ZHANG Li-Cui, ZHANG An-Ping, WU Ping, ZHU Xiao-Shu, WEI Shao-Hua, ZHOU Yi-Ming. Facile Synthesis and Sodium Storage Performance of N, Se-Co-doped Carbon Restricted NiSe Nanocrystalline Through a Two Step Direct Solid State Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(8): 1524-1534. doi: 10.11862/CJIC.2020.167 shu

Facile Synthesis and Sodium Storage Performance of N, Se-Co-doped Carbon Restricted NiSe Nanocrystalline Through a Two Step Direct Solid State Reaction

1.
Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, China
2.
Centre for Analysis and Testing, Nanjing Normal University, Nanjing 210023, China
3.
School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China

Corresponding author: ZHOU Yi-Ming, zhouyiming@njnu.edu.cn
Received Date: 10 March 2020
Revised Date: 17 May 2020

Figures(8)

In this work, a very simple and cost-effective two-step solid state reaction method for the preparation of NiSe nanocrystalline restricted within N, Se-codoped carbon scaffold was presented. By directly grinding nickel acetate tetrahydrate, o-vanillin and o-phenylenediamine together with a molar ratio of 1:2:1 at room temperature, a self -assembly solid state reaction took place to give rise to a bis-Schiff base complex with Ni(Ⅱ). After subsequent annealing at 700℃ in the presence of selenium powder, simultaneous carbonization and selenization occurred, resulting in the in -situ formation of NiSe nanocrystalline (~100 nm) confined within an irregular N, Se-codoped carbon scaffold (denoted as NiSe⊂NSeC). By means of X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS) and thermogravimetric analysis (TGA), the phase, morphology, composition and mass content for the NiSe ⊂ NSeC composite were identified. Its electrochemical sodium storage performance was tested by cyclic voltammetry, constant current charge and discharge cycling process, and electrochemical impedance spectrum. When tested as an anode material for sodium-ion batteries (SIBs), the NiSe⊂NSeC composite exhibited an impressive electrochemical sodium storage performance in terms of long-term cycling stability (291 mAh·g^-1 of charging capacity after 100 cycles at 0.1 A·g^-1, with a 88% of charging capacity retention compared with the first cycle) and excellent rate capability (197 mAh·g^-1 of charging capacity at 5 A·g^-1).
- NiSe nanocrystalline,
- carbon,
- N, Se-codoping,
- composite,
- two step solid-state reaction,
- anode material,
- sodium-ion batteries
1. [1]
  Chu S, Cui Y, Liu N. Nat. Mater., 2017, 16(1):16-22
2. [2]
  Dunn B, Kamath H, Tarascon J M. Science, 2011, 334(6058):928-935 doi: 10.1126/science.1212741
3. [3]
  Choi N S, Chen Z H, Freunberger S A, et al. Angew. Chem. Int. Ed., 2012, 51(40):9994-10024 doi: 10.1002/anie.201201429
4. [4]
  Simon P, Gogotsi Y, Dunn B. Science, 2014, 343(6176):1210-1211 doi: 10.1126/science.1249625
5. [5]
  Bruce P G, Freunberger S A, Hardwick L J, et al. Nat. Mater., 2012, 11(1):19-29
6. [6]
  Armand M, Tarascon J M. Nature, 2008, 451(7179):652-657 doi: 10.1038/451652a
7. [7]
  Yuan D D, He W, Pei F, et al. J. Mater. Chem. A, 2013, 1(12):3895-3899 doi: 10.1039/c3ta01430d
8. [8]
  Liu Y, He D D, Han R M, et al. Chem. Commun., 2017, 53(40):5569-5572 doi: 10.1039/C7CC02303K
9. [9]
  Li Y M, Lu Y X, Zhao C L, et al. Energy Storage Mater., 2017, 7:130-151 doi: 10.1016/j.ensm.2017.01.002
10. [10]
  Liu Y, Qiao Y, Lou X D, et al. ACS Appl. Mater. Interfaces, 2016, 8(23):14564-14571 doi: 10.1021/acsami.6b03089
11. [11]
  Xiong W, Wang Z Y, Zhang J Q, et al. Energy Storage Mater., 2017, 7:229-235 doi: 10.1016/j.ensm.2017.03.006
12. [12]
  Ortiz-Vitoriano N, Drewett N E, Gonzalo E, et al. Energy En-viron. Sci., 2017, 10(5):1051-1074
13. [13]
  Cui J, Yao S S, Kim J K. Energy Storage Mater., 2017, 7:64-114 doi: 10.1016/j.ensm.2016.12.005
14. [14]
  Ge P, Fouletier M. Solid State Ionics, 1988, 28-30:1172-1175 doi: 10.1016/0167-2738(88)90351-7
15. [15]
  Doeff M M, Ma Y P, Visco S J, et al. J. Electrochem. Soc., 1993, 140(12):L169-L170
16. [16]
  Stevens D A, Dahn J R. J. Electrochem. Soc., 2001, 148(8):A803-A811 doi: 10.1149/1.1379565
17. [17]
  Luo M H, Yu H X, Hu F Y, et al. Chem. Eng. J., 2020, 380:122557 doi: 10.1016/j.cej.2019.122557
18. [18]
  Ali Z, Zhang T, Asif M, et al. Mater. Today, 2020, DOI: 10.1016/j.mattod.2019.11.008
19. [19]
  Zhang Z, Shi X D, Yang X. Electrochim. Acta, 2016, 208:238-243 doi: 10.1016/j.electacta.2016.04.183
20. [20]
  Yang X M, Zhang J L, Wang Z G, et al. Small, 2018, 14(7):1702669 doi: 10.1002/smll.201702669
21. [21]
  Bai J, Xi B J, Mao H Z, et al. Adv. Mater., 2018, 30(35):1802310 doi: 10.1002/adma.201802310
22. [22]
  Ma Y F, Guo Q B, Yang M, et al. Energy Storage Mater., 2018, 13:134-141 doi: 10.1016/j.ensm.2018.01.005
23. [23]
  Yin B, Cao X X, Pan A Q, et al. Adv. Sci., 2018, 5(9):1800829 doi: 10.1002/advs.201800829
24. [24]
  Ye J C, Zang J, Tian Z W, et al. J. Mater. Chem. A, 2016, 4(34):13223-13227 doi: 10.1039/C6TA04592H
25. [25]
  Jin Z P, Nie H G, Yang Z, et al. Nanoscale, 2012, 4(20):6455-6460 doi: 10.1039/c2nr31858j
26. [26]
  Dong Y J, Wang W, Wang Y H, et al. J. Taiwan Inst. Chem. Eng., 2018, 93:500-508 doi: 10.1016/j.jtice.2018.08.028
27. [27]
  Zhu S H, Li Q D, Wei Q L, et al. ACS Appl. Mater. Interfaces, 2017, 9(1):311-316 doi: 10.1021/acsami.6b10143
28. [28]
  Park J S, Kang Y C. J. Mater. Chem. A, 2017, 5(18):8616-8623 doi: 10.1039/C7TA01088E
29. [29]
  Lu T, Dong S M, Zhang C J, et al. Coord. Chem. Rev., 2017, 332:75-99 doi: 10.1016/j.ccr.2016.11.005
30. [30]
  ZHOU Yi-Ming, XIN Xin-Quan. Chinese J. Inorg. Chem., 1999, 15(3):273-292 doi: 10.3321/j.issn:1001-4861.1999.03.001
31. [31]
  YANG Yu, JIA Dian-Zeng, GE Wei-Wei, et al. Chinese J. Inorg. Chem., 2004, 20(8):881-888 doi: 10.3321/j.issn:1001-4861.2004.08.001
32. [32]
  Li Y Z, Cao Y L, Jia D Z. J. Mater. Chem. A, 2014, 2(11):3761-3765 doi: 10.1039/c3ta14427e
33. [33]
  Wang Q, Ming M, Niu S, et al. Adv. Energy Mater., 2018, 8(31):1801698 doi: 10.1002/aenm.201801698
34. [34]
  Li F, Han G F, Noh H J, et al. Adv. Mater., 2018, 30(44):1803676 doi: 10.1002/adma.201803676
35. [35]
  Ye X R, Jia D Z, Yu J Q, et al. Adv. Mater., 1999, 11(11):941-942 doi: 10.1002/(SICI)1521-4095(199908)11:11<941::AID-ADMA941>3.0.CO;2-T
36. [36]
  Service R F. Science, 2008, 320(5883):1584-1585
37. [37]
  Patil S A, Shinde D V, Ahn D Y, et al. J. Mater. Chem. A, 2014, 2(33):13519-13526 doi: 10.1039/C4TA02267J
38. [38]
  Ou G, Xu Y S, Wen B, et al. Nat. Commun., 2018, 9(1):1302 doi: 10.1038/s41467-018-03765-0
39. [39]
  Tajik S, Dubal D P, Gomez-Romero P, et al. Int. J. Hydrogen Energy, 2017, 42(17):12384-12395 doi: 10.1016/j.ijhydene.2017.03.117
40. [40]
  Zhou Y M, Ye X R, Xin F B, et al. Transition Met. Chem., 1999, 24(1):118-120 doi: 10.1023/A:1006989707001
41. [41]
  Tian Y F, Ruan Y J, Zhang J Y, et al. Electrochim. Acta, 2017, 250:327-334 doi: 10.1016/j.electacta.2017.08.084
42. [42]
  Tuinstra F, Koenig J L. J. Chem. Phys., 1970, 53(3):1126-1130 doi: 10.1063/1.1674108
43. [43]
  Ferrari A C, Robertson J. Phys. Rev. B, 2000, 61(20):14095-14107 doi: 10.1103/PhysRevB.61.14095
44. [44]
  Stankovich S, Dikin D A, Piner R D, et al. Carbon, 2007, 45(7):1558-1565 doi: 10.1016/j.carbon.2007.02.034
45. [45]
  Shi W D, Zhang X, Che G B. Int. J. Hydrogen Energy, 2013, 38(17):7037-7045 doi: 10.1016/j.ijhydene.2013.03.145
46. [46]
  Murugadoss V, Lin J, Liu H, et al. Nanoscale, 2019, 11(38):17579-17589 doi: 10.1039/C9NR07060E
47. [47]
  Ruan Y J, Jiang J J, Wan H Z, et al. J. Power Sources, 2016, 301:122-130 doi: 10.1016/j.jpowsour.2015.09.116
48. [48]
  Luo C, Wang J J, Suo L M, et al. J. Mater. Chem. A, 2015, 3(2):555-561 doi: 10.1039/C4TA04611K
49. [49]
  Yun Y S, Yoon G, Park M, et al. NPG Asia Mater., 2016, 8(12):e338-e338 doi: 10.1038/am.2016.191
50. [50]
  Li H M, Qian X, Zhu C L, et al. J. Mater. Chem. A, 2017, 5(9):4513-4526 doi: 10.1039/C6TA10718D
51. [51]
  Wei X J, Tang C J, An Q Y, et al. Nano Res., 2017, 10(9):3202-3211 doi: 10.1007/s12274-017-1537-z
52. [52]
  Sheng Z H, Shao L, Chen J J, et al. ACS Nano, 2011, 5(6):4350-4358 doi: 10.1021/nn103584t
53. [53]
  Kang W W, Lin B P, Huang G X, et al. J. Mater. Sci.-Mater. Electron., 2018, 29(4):3340-3347 doi: 10.1007/s10854-017-8269-4
54. [54]
  Mi L W, Ding Q, Sun H, et al. CrystEngComm, 2013, 15(14):2624-2630 doi: 10.1039/c3ce26754g
55. [55]
  Zhang Y F, Pan A Q, Ding L, et al. ACS Appl. Mater. Inter-faces, 2017, 9(4):3624-3633 doi: 10.1021/acsami.6b13153
56. [56]
  Zhang K, Park M H, Zhou L M, et al. Adv. Funct. Mater., 2016, 26(37):6728-6735 doi: 10.1002/adfm.201602608
57. [57]
  Zhang Z A, Shi X D, Yang X. Electrochim. Acta, 2016, 208:238-243 doi: 10.1016/j.electacta.2016.04.183
58. [58]
  Cao X, Li A J, Yang Y, et al. RSC Adv., 2018, 8(45):25734-25744 doi: 10.1039/C8RA03479F
59. [59]
  Liu X B, Liu Y C, Feng M, et al. J. Mater. Chem. A, 2018, 6(46):23621-23627 doi: 10.1039/C8TA09247H
60. [60]
  Zhang G J, Liu K H, Liu S T, et al. J. Alloys Compd., 2018, 731:714-722 doi: 10.1016/j.jallcom.2017.10.094
61. [61]
  Jin J, Huang S Z, Liu J, et al. J. Mater. Chem. A, 2014, 2(25):9699-9708 doi: 10.1039/c4ta01775g
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