Citation: LI Chun, TIAN Peng, PANG Hong-Chang, YE Jun-Wei, NING Gui-Ling. Tungsten Doped Iron-Nickel Layered Hydroxide for Oxygen Evolution and Hydrogen Evolution Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(8): 1492-1498. doi: 10.11862/CJIC.2020.163 shu

Tungsten Doped Iron-Nickel Layered Hydroxide for Oxygen Evolution and Hydrogen Evolution Reaction

School of Chemical Engineering, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: TIAN Peng, tianpeng@dlut.edu.cn NING Gui-Ling, ninggl@dlut.edu.cn
Received Date: 20 February 2020
Revised Date: 1 May 2020

Figures(7)

We utilize a simple one-step hydrothermal synthesis method to introduce trace amount of W⁶⁺ into Fe_0.02Ni(OH)₂ LDH, which grow on nickel foam in situ. The morphology, composition and structure of W_0.03Fe_0.2Ni(OH)₂ LDH were characterized by means of field emission scanning electron microscope (FESEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Raman spectra, and so on. W_0.03Fe_0.2Ni(OH)₂ LDH exhibited better electrochemical performance than others due to W⁶⁺ introduction. Electrochemical tests show that the lowest overpotentials for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) at the 25 mA·cm^-2 were only 271 and 208 mV, respectively. The corresponding Tafel slopes were 61 and 181 mV·dec^-1. In addition, there were no obvious decrease of electrocatalytic activity after more than 20-hours of chronopotentiometric test.
- tungsten doping,
- layered double hydroxide,
- electrocatalysis,
- oxygen evolution reaction (OER),
- hydrogen evolution reaction (HER)
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