Citation: XU Zhong-Xuan, LI Li-Feng, BAI Xu-Ling. Helical Coordination Polymers Based on Tetra-coordinated Co(Ⅱ): Syntheses, Structures and Photocatalytic CO₂ Reduction Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(8): 1430-1436. doi: 10.11862/CJIC.2020.154 shu

Helical Coordination Polymers Based on Tetra-coordinated Co(Ⅱ): Syntheses, Structures and Photocatalytic CO₂ Reduction Reaction

School of Chemistry and Chemical Engineering, Zunyi Normal College, Zunyi, Guizhou 563002, China

Corresponding author: XU Zhong-Xuan, xuzhongxuan4201@163.com
Received Date: 20 November 2019
Revised Date: 27 March 2020

Figures(5)

A pair of homochiral coordination polymers, {[Co((R)-CBA)(1, 3-BMIB)₂]·H₂O}_n (1-D, (R)-H₂CBA=(R)-4-(1-carboxyethoxy)benzoic acid, 1, 3-BMIB=1, 3-bis(2-methyl-1H-imidazol-1-yl)benzene) and {[Co((S)-CBA)(1, 3-BMIB)₂]·H₂O}_n (1-L), were prepared by mixing Co²⁺, 1, 3-BMIB and lactic acid derivates (R)-H₂CBA/(S)-H₂CBA under hydrothermal condition, respectively. X-ray crystallography reveals there are three types of helical chains constructed by tetra-coordinated Co(Ⅱ) centers, 1, 3-BMIB and/or CBA^2- ligands in complexes 1-D and 1-L. For unsaturated Co(Ⅱ) centers can act as catalytic active site, complex 1-D with high yield was further used for photo-catalytic research. Mott-Schottky measurements indicate that complex 1-D is a typical n-type semiconductor, while the UV-Vis spectrum confirmed that complex 1-D showed strong absorption in a range of 420~650 nm. Further more, complex 1-D has the small radius and the lowest resistance in charge transportation. Finally, complex 1-D realized photocatalytic reduction of CO₂ to CO with an evolution rate of 577.8 μmol·g^-1·h^-1 in the course of the experiment.
- coordination polymer,
- helical chain,
- tetra-coordinated Co(Ⅱ) center,
- photo-catalytic CO₂ reduction
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通讯作者: 陈斌, bchen63@163.com

Helical Coordination Polymers Based on Tetra-coordinated Co(Ⅱ): Syntheses, Structures and Photocatalytic CO₂ Reduction Reaction