Citation: Chelsea N. Widener, Alexandria N. Bone, Mykhaylo Ozerov, Rachael Richardson, LU Zheng-Guang, Komalavalli Thirunavukkuarasu, Dmitry Smirnov, CHEN Xue-Tai, XUE Zi-Ling. Direct Observation of Magnetic Transitions in a Nickel(Ⅱ) Complex with Large Anisotropy[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(6): 1149-1156. doi: 10.11862/CJIC.2020.126 shu

Direct Observation of Magnetic Transitions in a Nickel(Ⅱ) Complex with Large Anisotropy

1.
Department of Chemistry, University of Tennessee, Knoxville, Tennessee 37996, United States
2.
National High Magnetic Field Laboratory, Florida State University, Tallahassee, Florida 32310, United States
3.
Department of Physics, Florida A&M University, Tallahassee, Florida 32307, United States
4.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Corresponding author: XUE Zi-Ling, xue@utk.edu
Received Date: 2 March 2020
Revised Date: 5 April 2020

Fund Project: U.S. National Science Foundation CHE-1900296Supported by U.S. National Science Foundation (No.CHE-1633870, CHE-1900296)U.S. National Science Foundation CHE-1633870

Figures(5)

Trigonal bipyramidal Ni(Ⅱ) complex [Ni(Me₆tren)Cl](ClO₄) (1, Me₆tren=tris(2-(dimethylamino)ethyl)amine) has recently been shown by Ruamps and coworkers to possess large, uniaxial magnetic anisotropy (J. Am. Chem. Soc., 2013, 135:3017-3026). Their HF-EPR studies gave rhombic zero-field-splitting (ZFS) parameter E=1.56(5) cm^-1 for 1. However, the axial ZFS parameter D has not been determined. We have used far-IR magnetic spectroscopy (FIRMS) at 0~17.5 T and 5 K to probe the magnetic transitions between the M_S=±1 and M_S=0 states of the ground spin state S=1 in 1. Direct observation of the transitions between Zeeman-split states in FIRMS gives axial ZFS parameter D=-110.7(3) cm^-1. Hirshfeld surface analysis of the crystal structure of 1 has been performed, revealing the interactions between the cation and anion in a molecule of 1 as well as among the molecules of 1 in crystals.
- nickel complex,
- zero-field splitting transition,
- uniaxial magnetic anisotropy,
- far-IR magnetospectroscopy (FIRMS)
1. [1]
  Benelli C, Gatteschi D. Introduction to Molecular Magnetism. Weinheim:Wiley-VCH, 2015:217-237
2. [2]
  Frost J M, Harriman K L M, Murugesu M. Chem. Sci., 2016, 7:2470-2491 doi: 10.1039/C5SC03224E
3. [3]
  Layfield R A. Organometallics, 2014, 33:1084-1099 doi: 10.1021/om401107f
4. [4]
  Krzystek J, Telser J. Dalton Trans., 2016, 45:16751-16763 doi: 10.1039/C6DT01754A
5. [5]
  McInnes E J L, Winpenny R E P. Comprehensive Inorganic Chemistry: Vol.2. Amsterdam: Elsevier, 2013: 371-395
6. [6]
  Neese F, Pantazis D A. Faraday Discuss., 2011, 148:229-238 doi: 10.1039/C005256F
7. [7]
  Gao S. Molecular Nanomagnets and Related Phenomena. Heidelberg: Springer, 2015: 1-460
8. [8]
  Zhang P, Zhang L, Tang J K. Dalton Trans., 2015, 44:3923-3929 doi: 10.1039/C4DT03329A
9. [9]
  Liu J L, Chen Y C, Tong M L. Chem. Soc. Rev., 2018, 47:2431-2453 doi: 10.1039/C7CS00266A
10. [10]
  Craig G A, Murrie M. Chem. Soc. Rev., 2015, 44:2135-2147 doi: 10.1039/C4CS00439F
11. [11]
  Rinehart J D, Long J R. Chem. Sci., 2011, 2:2078-2085 doi: 10.1039/c1sc00513h
12. [12]
  Gatteschi D, Sessoli R. Angew. Chem. Int. Ed., 2003, 42:268-297 doi: 10.1002/anie.200390099
13. [13]
  Demir S, Jeon I-R, Long J R, et al. Coord. Chem. Rev., 2015, 289:149-176
14. [14]
  Dey M, Gogoi N. Angew. Chem. Int. Ed., 2013, 52:12780-12782 doi: 10.1002/anie.201304982
15. [15]
  Boča R. Coord. Chem. Rev., 2004, 248:757-815 doi: 10.1016/j.ccr.2004.03.001
16. [16]
  Shatruk M, Gómez-Coca S, Dunbar K R. Molecular Magnetic Materials:Concepts and Applications. Weinheim:Wiley-VCH, 2017:29-77
17. [17]
  Yamashita M, Katoh K. Molecular Magnetic Materials:Concepts and Applications. Weinheim:Wiley-VCH, 2017:79-101
18. [18]
  Gatteschi D, Sessoli R, Villain J. Molecular Nanomagnets. Oxford:Oxford University Press, 2006:1-317
19. [19]
  Stavretis S E, Mamontov E, Moseley D H, et al. Phys. Chem. Chem. Phys., 2018, 20:21119-21126 doi: 10.1039/C8CP01660G
20. [20]
  Marriott K E R, Bhaskaran L, Wilson C, et al. Chem. Sci., 2015, 6:6823-6828 doi: 10.1039/C5SC02854J
21. [21]
  Miklovič J, Valigura D, Boča R, et al. Dalton Trans., 2015, 44:12484-12487 doi: 10.1039/C5DT01213A
22. [22]
  Lomjanský D, Moncol' J, Rajnak C, et al. Chem. Commun., 2017, 53:6930-6932 doi: 10.1039/C7CC03275G
23. [23]
  Craig G A, Sarkar A, Woodall C H, et al. Chem. Sci., 2018, 9:1551-1559 doi: 10.1039/C7SC04460G
24. [24]
  Titiš J, Rajnák C, Valigura D, et al. Dalton Trans., 2018, 47:7879-7882 doi: 10.1039/C8DT01445K
25. [25]
  Titiš J, Chrenková V, Rajnák C, et al. Dalton Trans., 2019, 48:11647-11650 doi: 10.1039/C9DT02159K
26. [26]
  Chen L, Wang J, Wei J M, et al. J. Am. Chem. Soc., 2014, 136:12213-12216 doi: 10.1021/ja5051605
27. [27]
  Ruamps R, Maurice R, Batchelor L, et al. J. Am. Chem. Soc., 2013, 135:3017-3026 doi: 10.1021/ja308146e
28. [28]
  Rudowicz C, Açıkgöz M, Gnutek P. J. Magn. Magn. Mater., 2017, 434:56-61 doi: 10.1016/j.jmmm.2017.03.035
29. [29]
  Ray K, Begum A, Weyhermuller T, et al. J. Am. Chem. Soc., 2005, 127:4403-4415 doi: 10.1021/ja042803i
30. [30]
  Rechkemmer Y, Fischer J E, Marx R, et al. J. Am. Chem. Soc., 2015, 137:13114-13120 doi: 10.1021/jacs.5b08344
31. [31]
  Rechkemmer Y, Breitgoff F D, van der Meer M, et al. Nat. Commun., 2016, 7:10467 doi: 10.1038/ncomms10467
32. [32]
  Bunting P C, Atanasov M, Damgaard-Moller E, et al. Science, 2018, 362:eaat7319 doi: 10.1126/science.aat7319
33. [33]
  Jiang S D, Maganas D, Levesanos N, et al. J. Am. Chem. Soc., 2015, 137:12923-12928 doi: 10.1021/jacs.5b06716
34. [34]
  Switlicka A, Machura B, Penkala M, et al. Inorg. Chem., 2018, 57:12740-12755 doi: 10.1021/acs.inorgchem.8b01906
35. [35]
  Hay M A, Sarkar A, Craig G. Chem. Sci., 2019, 10:6354-6361 doi: 10.1039/C9SC00987F
36. [36]
  Haas S. Thesis for the Doctorate of University of Stuttgart. 2015.
37. [37]
  Moseley D H, Stavretis S E, Thirunavukkuarasu K, et al. Nat. Commun., 2018, 9:2572 doi: 10.1038/s41467-018-04896-0
38. [38]
  Stavretis S E, Moseley D H, Fei F, et al. Chem. Eur. J., 2019, 25:15846-15857 doi: 10.1002/chem.201903635
39. [39]
  Brackett G C. Thesis for the Doctorate of University of California Berkeley. 1970.
40. [40]
  Brackett G C, Richards P L, Caughey W S. J. Chem. Phys., 1971, 54:4383-4401 doi: 10.1063/1.1674688
41. [41]
  McKinnon J J, Jayatilaka D, Spackman M A. Chem. Commun., 2007, 37:3814-3816
42. [42]
  Spackman M A, Jayatilaka D. CrystEngComm, 2009, 11:19-32 doi: 10.1039/B818330A
43. [43]
  Spackman M A, McKinnon J J. CrystEngComm, 2002, 4:378-392 doi: 10.1039/B203191B
44. [44]
  McKinnon J J, Spackman M A, Mitchell A S. Acta Crystallogr. Sect. B, 2004, B60:627-668
45. [45]
  Turner M J, McKinnon J J, Jayatilaka D, et al. CrystEngComm, 2011, 13:1804-1813 doi: 10.1039/C0CE00683A
46. [46]
  Hunter S C, Smith B A, Hoffmann C M, et al. Inorg. Chem., 2014, 53:11552-11562 doi: 10.1021/ic5015835
47. [47]
  Bone A N, Stavretis S E, Krzystek J, et al. Polyhedron, 2020, doi: https://doi.org/10.1016/j.poly.2020.114488
48. [48]
  Turner M J, McKinnon J J, Wolff S K, et al. CrystalExplorer17. https://crystalexplorer.scb.uwa.edu.au/downloads.html
49. [49]
  Stoll S, Schweiger A. J. Magn. Reson., 2006, 178:42-55 doi: 10.1016/j.jmr.2005.08.013
50. [50]
  Fingerprint plots; Website: http://crystalexplorer.scb.uwa.edu.au/wiki/index.php/Fingerprint_Plots
51. [51]
  Hirshfeld surface properties; Website: http://crystalexplorer.scb.uwa.edu.au/wiki/index.php/Surface_Properties
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2. [2]
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3. [3]
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4. [4]
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沈阳化工大学材料科学与工程学院沈阳 110142