Citation: MENG Liu-Li, CHENG Hong-Tao, XUE Dong-Xu, WANG Qian, BAI Jun-Feng. Synthesis and Selective CO₂ Adsorption of a rtl-MOF Based upon 5-(3-Amino-pyridin-4-yl)-isophthalic Acid and [Cu₂(COO)₄]-Paddlewheel Unit[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(6): 1098-1104. doi: 10.11862/CJIC.2020.120 shu

Synthesis and Selective CO₂ Adsorption of a rtl-MOF Based upon 5-(3-Amino-pyridin-4-yl)-isophthalic Acid and [Cu₂(COO)₄]-Paddlewheel Unit

1.
Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an 710062, China
2.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Corresponding author: WANG Qian, wangq@snnu.edu.cn BAI Jun-Feng, bjunfeng@snnu.edu.cn; bjunfeng@nju.edu.cn
Received Date: 10 January 2020
Revised Date: 26 March 2020

Figures(5)

Based upon a new ligand of 5-(3-amino-pyridin-4-yl)-isophthalic acid (NH₂-H₂L₁), the NH₂-functionalized pillar-layer rtl-MOF, SNNU-Bai65, has been successfully designed and synthesized. With the polar amino group decorating the pore surface and partitioning the pore channel, activated SNNU-Bai65 exhibits more highly selective CO₂ adsorption over N₂ and CH₄ than the parent MOF, SYSU.
- amino-functionalization,
- rtl-MOF,
- selective CO₂ adsorption
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Synthesis and Selective CO2 Adsorption of a rtl-MOF Based upon 5-(3-Amino-pyridin-4-yl)-isophthalic Acid and [Cu2(COO)4]-Paddlewheel Unit

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Selective CO₂ Adsorption of a rtl-MOF Based upon 5-(3-Amino-pyridin-4-yl)-isophthalic Acid and [Cu₂(COO)₄]-Paddlewheel Unit