Citation: LI Jing, YANG Li, YIN Lei, JIANG Shang-Da, OUYANG Zhong-Wen, ZHANG Yi-Quan, WANG Zhen-Xing, SONG You. Dielectric and Magnetic Exchange Natures of a Dinuclear Double-Stranded Hydrogen Bonds Helicates[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(6): 1123-1130. doi: 10.11862/CJIC.2020.117 shu

Dielectric and Magnetic Exchange Natures of a Dinuclear Double-Stranded Hydrogen Bonds Helicates

LI Jing ¹ ,
YANG Li ¹ ,
YIN Lei ² ,
JIANG Shang-Da ³ ,
OUYANG Zhong-Wen ² ,
ZHANG Yi-Quan ^4,, ,
WANG Zhen-Xing ^2,, ,
SONG You ^1,,

1.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
2.
Wuhan National High Magnetic Field Center, Huazhong University of Science and Technology, Wuhan 430074, China
3.
National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
4.
Jiangsu Key Laboratory for NSLSCS, School of Physical Science and Technology, Nanjing Normal University, Nanjing 210023, China

Corresponding author: ZHANG Yi-Quan, zhangyiquan@njnu.edu.cn WANG Zhen-Xing, zxwang@hust.edu.cn SONG You, yousong@nju.edu.cn
Received Date: 8 February 2020
Revised Date: 18 March 2020

Figures(4)

The dielectric and magnetic properties of a dinuclear Co(Ⅱ) double-stranded helicate containing hydrogen bridging bond have been investigated. Magnetic properties, HF-EPR spectra and dielectric properties all indicate that this intramolecular hydrogen bond plays an important role in the magnetic exchange interactions and dielectric properties. Ab initio calculations provide further support for above conclusions.
- dinuclear Co(Ⅱ) double-stranded helicate,
- hydrogen bridging bond,
- dielectric properties,
- magnetic exchange interaction
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