Citation: HU Qing-Tao, ZHANG Wen-Da, LI Tao, YAN Xiao-Dong, GU Zhi-Guo. Preparation and Application in Supercapacitors of Shiitake Biomass-Based Nitrogen-Doped Microporous Carbon[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(8): 1573-1581. doi: 10.11862/CJIC.2020.114 shu

Preparation and Application in Supercapacitors of Shiitake Biomass-Based Nitrogen-Doped Microporous Carbon

HU Qing-Tao ¹ ,
ZHANG Wen-Da ¹ ,
LI Tao ¹ ,
YAN Xiao-Dong ^1,, ,
GU Zhi-Guo ^1,2,,

1.
School of Chemistry and Material Engineering, Jiangnan University, Wuxi, Jiangsu 214122, China
2.
Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, Wuxi, Jiangsu 214122, China

Corresponding author: YAN Xiao-Dong, xiaodong.yan@jiangnan.edu.cn GU Zhi-Guo, zhiguogu@jiangnan.edu.cn
Received Date: 13 January 2020
Revised Date: 13 March 2020

Figures(7)

Shiitake-derived nitrogen-doped microporous carbon materials were prepared by a simple activation/carbonization process. It was found that the nitrogen content was enhanced owing to the consumption of carbon in the activation process, and that the pyridinic nitrogen groups were promoted after activation. The microporous carbons offered a high specific surface area of 1 930 m²·g^-1 with a high micropore surface area of 1 594 m²·g^-1. The high micropore surface area accompanied with rich nitrogen and oxygen groups contributed to a remarkable specific capacitance of 325 F·g^-1 at 0.5 A·g^-1 and high rate capability. In addition, shiitake-derived microporous carbons presented robust cycling stability with 2.3% capacitance loss during 5 000 cycles, and a high specific capacitance of 203 F·g^-1 at 0.5 A·g^-1 in symmetric supercapacitors. The high performance could be attributed to the high surface area, enhancing electric double layer capacitance, and numerous nitrogen groups.
- supercapacitors,
- carbon,
- microporous materials,
- carbonization,
- nitrogen doping
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