Citation: MEI Jian, ZENG Ting-Jian, QIU Lü-Chao, ZHANG Jie, LIU Chun-Li, XIE Jian, ZHAO Xin-Bing. Preparation and Electrochemical Na-Storage Properties of Fe-Based Prussian Blue Cathode[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(5): 795-801. doi: 10.11862/CJIC.2020.113 shu

Preparation and Electrochemical Na-Storage Properties of Fe-Based Prussian Blue Cathode

1.
State Grid Zhejiang Electric Power Research Institute, Hangzhou 310014, China
2.
Zhejiang Huayun Electric Power Industrial Group Co. Ltd., Hangzhou 310000, China
3.
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: XIE Jian, xiejian1977@zju.edu.cn
Received Date: 2 January 2020
Revised Date: 13 March 2020

Figures(7)

In this work, Na-rich, low-defect Fe-based Prussian blue material has been synthesized by coprecipitation method at room temperature using antioxidant (ascorbic acid) and chelating agent (sodium citrate). At 0.1C, the material exhibited a high capacity of 110.0 mAh·g^-1 due to high Na content and low crystal defect. The material also showed excellent rate capability and cycling stability due to the border-rich structure and low defect, besides unique open framework structure of the Prussian blue material. At a current rate up to 10C, the material can still yield a capacity of 86.6 mAh·g^-1. After 1 300 cycles at current density of 1C, the material could keep a capacity of 90.1 mAh·g^-1, corresponding to the capacity retention of 86.9%.
- electrochemistry,
- energy conversion,
- sodium ion battery,
- cathode material,
- Prussian blue material,
- electrochemical performance
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1.
沈阳化工大学材料科学与工程学院沈阳 110142