Citation: HUANG Ling, WANG Ying, TANG Ren-Heng, XIAO Fang-Ming, LI Wen-Chao. Effect of Surfactant on Structure and Properties of LiNi_0.80Co_0.15Al_0.05O₂[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(8): 1465-1474. doi: 10.11862/CJIC.2020.111 shu

Effect of Surfactant on Structure and Properties of LiNi_0.80Co_0.15Al_0.05O₂

Guangdong Research Institute of Rare Metals and Guangdong Provincial Key Laboratory of Rare Earth Development and Application, Guangdong 510650, China

Corresponding author: HUANG Ling, hlsxg@163.com
Received Date: 16 January 2020
Revised Date: 18 March 2020

Figures(11)

A uniform LiNi_0.80Co_0.15Al_0.05O₂ microsphere materials (NCA) with tap density of 1.86~2.07 g·cm^-3 were successfully prepared using co-precipitation method assisted by surfactants polyethylene glycol (PEG) or polyvinylpyrrolidone (PVP). Crystal structure, particles morphology and electrochemical features were evaluated through X-ray diffraction (XRD), transmission electron microscope (TEM), scanning electron microscope (SEM), cyclic voltammogram (CV), electrochemical impedance spectra (EIS) and charge/discharge studies. The results showed that the atomic ratio of Ni, Co and Al could not be affected in the materials which were synthesized with PEG or PVP and the materials had high tap density. The result of XRD showed that all the diffraction peaks of NCA materials were indexed to the pure α-NaFeO₂ layered structure which belonged to R3m space group. SEM images of precursors and NCA materials were obvious that the growth of primary grains was improved with the addition of PVP and PEG. The NCA obtained with the addition of PEG and PVP displayed a high discharge capacity of 210.8 and 188.9 mAh·g^-1 at 0.2C, and showed good capacity retention of 78.8% and 93.2% after 100 cycles respectively, which were better than that of NCA obtained without surfactant (173.0 mAh·g^-1 and 82.7%). EIS curves showed that electrochemical impedance of NCA-2 electrode least than NCA-1 and NCA-3 after 100 cycles. SEM images of positive plates after 200 cycles were obvious that positive plates synthesized by using PVP had least cracks and particle fragmentation. NCA-2 showed better capacity retention than NCA obtained with the addition of PEG and NCA obtained without surfactant.
- battery,
- cathode materials,
- co-precipitation,
- lithium nickel cobalt aluminum oxide (NCA),
- surfactant,
- polyethylene glycol (PEG),
- polyvinylpyrrolidone (PVP)
1. [1]
  ZHANG Ying-Ying, YANG Xu-Zhao, HUI Meng-Meng, et al. Detergent & Cosmetics, 2018, 41(2):52-56
2. [2]
3. [3]
  ZHANG Zheng-Guo, LUO Chun-Hui, ZHU Liang, et al. China Powder Science And Technology, 2015, 21(2):32-34
4. [4]
  ZHANG Zheng-Guo. Inorganic Chemicals Industry, 2015, 47(2):67-70
5. [5]
  WU Zhao-Cong, DAI Yong-Nian, HUANG Rui-An, et al. Materials Reports B, 2012, 26(6):22-24, 35
6. [6]
  ZHANG Jin-Li, YANG Sai, LIU Yuan-Yuan, et al. New Chemical Materials, 2013, 41(6):140-142 doi: 10.3969/j.issn.1006-3536.2013.06.050
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
  WU Tian-Ya, ZHANG Zheng-Fu, WANG Zi, et al. Chinese Journal of Rare Matals, 2017, 41(10):1105-1111
13. [13]
14. [14]
15. [15]
  WANG Wei-Dong, QIU Wei-Hua, DING Qian-Qian, et al. Nickel Cobalt Manganese Based Cathode Materials for Li-Ion Batteries Technology Production and Application. Beijing:Chemical Industry Press, 2015.
16. [16]
  LONG Yu-Sheng, KANG Zheng, LIAO Lie-Wen, et al. Guangzhou Chemical Industry, 1999, 27(2):33-35
1. [1]
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2. [2]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
3. [3]
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4. [4]
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5. [5]
  Pengyang FAN , Shan FAN , Qinjin DAI , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Xiaoxiao HUANG , Yong ZHANG . Preparation and performance of rich 1T-MoS₂ nanosheets for high-performance aqueous zinc ion battery cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 675-682. doi: 10.11862/CJIC.20240339
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7. [7]
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14. [14]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
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  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
16. [16]
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17. [17]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
18. [18]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
19. [19]
  Tingting Yu , Si Chen , Lianglong Sun , Tongtong Shi , Kai Sun , Xin Wang . Comprehensive Experimental Design for the Photochemical Synthesis, Analysis, and Characterization of Difluoropyrroles. University Chemistry, 2024, 39(11): 196-203. doi: 10.3866/PKU.DXHX202401022
20. [20]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022

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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Surfactant on Structure and Properties of LiNi0.80Co0.15Al0.05O2

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通讯作者: 陈斌, bchen63@163.com

Effect of Surfactant on Structure and Properties of LiNi_0.80Co_0.15Al_0.05O₂