Citation: TIAN Qian, ZHANG Jian-Guo, NI Chun-Yan, YANG Zhan-Yong, YAO Zhi-Gang, ZHANG Min-Jie, LANG Jian-Ping. Synthesis, Structures and Properties of Six Coordination Polymers of 1, 3, 5-Tri-4-pyridyl-1, 2-ethenylbenzene[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(6): 1063-1071. doi: 10.11862/CJIC.2020.110 shu

Synthesis, Structures and Properties of Six Coordination Polymers of 1, 3, 5-Tri-4-pyridyl-1, 2-ethenylbenzene

1.
Suzhou Key Laboratory of Precision Transformation of Resource Molecules, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China
2.
Analysis and Testing Center, Soochow University, Suzhou, Jiangsu 215123, China

Corresponding author: NI Chun-Yan, chunyan89.ok@163.com YAO Zhi-Gang, zhgyao@suda.edu.cn LANG Jian-Ping, jplang@suda.edu.cn
Received Date: 3 February 2020
Revised Date: 14 March 2020

Figures(7)

Reactions of the tri-olefinic tri-pyridyl ligand 1, 3, 5-tri-4-pyridyl-1, 2-ethenylbenzene (tpeb) with four metal nitrates M(NO₃)₂ (M=Co, Ni, Zn, Cd) and various carboxylic acids including 3, 5-dibromobenzoic acid (3, 5-HDBB), 2, 5-thiophenedicarboxylic acid (2, 5-H₂TDC), 2, 5-furandicarboxylic acid (2, 5-H₂FDC) and 2, 5-dibromoterephthalic acid (2, 5-H₂DBTP) gave rise to six coordination polymers, namely [Zn(tpeb)(3, 5-DBB)₂]_n (1), [Co₂(tpeb)₂(2, 5-TDC)₂]_n (2), [Co₂(tpeb)₂(2, 5-FDC)₂]_n (3), [Co(tpeb)(2, 5-DBTP)]_n (4), [Ni(tpeb)(2, 5-DBTP)]_n (5) and [Cd(tpeb)_0.5(2, 5-DBTP)]_n (6). Complexes 1~6 were characterized by elemental analysis, infrared spectrum (IR), thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD) and single crystal X-ray diffraction. Complexes 1~6 show rich structure varieties from one-dimensional (1D) to three-dimensional (3D). Compound 1 has a 1D zigzag chain structure in which the [Zn(3, 5-DBB)₂] units are interconnected by tpeb ligands. Complexes 2 and 3 contain a similar two-dimensional (2D) double-layer network assembled from 1D ladder chains of [Co(tpeb)]_n bridged by 2, 5-TDC or 2, 5-FDC. Complexes 4 and 5 hold a 3D framework constructed by bridging 1D chains of [M(2, 5-DBTP)]_n (M=Co, Ni) with tpeb ligands. Compound 6 contains 2D [Cd(2, 5-DBTP)]_n networks, which are interlinked by tpeb bridges, forming a unique 3D framework. Complexes 1~6 have good thermal stability, and exhibit various fluorescence emissions in the solid state.
- coordination polymers,
- crystal structures,
- tri-olefinic tri-pyridyl ligand,
- fluorescence properties
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