Citation: QI Xiao-Wei, LIU Jian, YANG Qian-Ying, ZHANG Hua-Hong, HAN Li-Zhi, ZHANG Xiao-Peng, SHI Zai-Feng. Stretch-Induced Luminescent Changes of a Self-Healing Elastic Polymer Functionalized with Platinum Complex[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(5): 933-940. doi: 10.11862/CJIC.2020.107 shu

Stretch-Induced Luminescent Changes of a Self-Healing Elastic Polymer Functionalized with Platinum Complex

1.
College of Chemistry and Chemical Engineering, Key Laboratory of Water Pollution Treatment & Resource Reuse of Hainan Province, Hainan Normal University, Haikou 571158, China
2.
College of Chemical Engineering, Jiangsu Key Lab of Biomass-Based Green Fuels and Chemicals, Nanjing Forestry University, Nanjing 210037, China

Corresponding author: ZHANG Xiao-Peng, xpzhang@hainnu.edu.cn SHI Zai-Feng, zaifengshi@163.com
Received Date: 19 November 2019
Revised Date: 12 March 2020

Figures(10)

An elastic orange-red film (PDMS-PtL1) has been prepared by grafting formyl-containing Pt(Ⅱ) complex Pt(N^C^N)Cl (N^C^N=1, 3-dipyridyl benzene) onto polydimethylsiloxane (PDMS) backbone. The film was highly stretchable (up to 1500% strain) and shows room-temperature self-healing property. Interestingly, stretch-induced luminescent change of the film was observed, where an emission tentatively originating from ³π-π^* of separated platinum moieties was detected after stretching. Luminescence quenching is avoided in this elastic film, and the switch of emission state can be realized by changing external forces.
- platinum complex,
- functional film,
- stretch,
- self-healing,
- luminescent change
1. [1]
  Aliprandi A, Mauro M, De Cola L. Nat. Chem., 2016, 8:10-15 doi: 10.1038/nchem.2383
2. [2]
  Ravotto L, Ceroni P. Coord. Chem. Rev., 2017, 346:62-76 doi: 10.1016/j.ccr.2017.01.006
3. [3]
  Wong V C H, Po C, Leung S Y L, et al. J. Am. Chem. Soc., 2018, 140:657-666 doi: 10.1021/jacs.7b09770
4. [4]
  Lu W, Chen Y, Roy V A L, et al. Angew. Chem. Int. Ed., 2009, 48:7621-7625 doi: 10.1002/anie.200903109
5. [5]
  Ganesan P, Hung W Y, Tso J Y, et al. Adv. Funct. Mater., 2019, 29:1900923 doi: 10.1002/adfm.201900923
6. [6]
  ZHANG Si-Qi, GAO Li-Hua, ZHAO Hua, et al. Chinese J. Inorg. Chem., 2019, 35(11):1974-1986 doi: 10.11862/CJIC.2019.231
7. [7]
  Bryant M J, Skelton J M, Hatcher L E, et al. Nat. Commun., 2017, 8:1800 doi: 10.1038/s41467-017-01941-2
8. [8]
  Lin C J, Liu Y H, Peng S M, et al. Inorg. Chem., 2017, 56:4978-4989 doi: 10.1021/acs.inorgchem.7b00009
9. [9]
  Chen J, Ao L, Wei C, et al. Chem. Commun., 2019, 55:229-232 doi: 10.1039/C8CC06770H
10. [10]
  Zhang X P, Zhu L H, Wang X H, et al. Inorg. Chim. Acta, 2016, 442:56-63 doi: 10.1016/j.ica.2015.11.028
11. [11]
  Zhang X P, Zhang D S, Qi X W, et al. Inorg. Chim. Acta, 2017, 467:99-105 doi: 10.1016/j.ica.2017.07.054
12. [12]
  Zhang X P, Wang L L, Qi X W, et al. Dalton Trans., 2018, 47:10179-10186 doi: 10.1039/C8DT02277A
13. [13]
  Zhang X P, Mei J F, Lai J C, et al. J. Mater. Chem. C, 2015, 3:2350-2357 doi: 10.1039/C4TC02800G
14. [14]
  Cuerva C, Campo J A, Cano M, et al. Chem. Eur. J., 2016, 22:10168-10178 doi: 10.1002/chem.201601115
15. [15]
  Zhang X, Wang J Y, Ni J, et al. Inorg. Chem., 2012, 51:5569-5579 doi: 10.1021/ic202421d
16. [16]
  Cuerva C, Campo J A, Ovejero P, et al. J. Mater. Chem. C, 2014, 2:9167-9181 doi: 10.1039/C4TC01666A
17. [17]
  Kumpfer J R, Taylor S D, Connick W B, et al. J. Mater. Chem., 2012, 22:14196-14204 doi: 10.1039/c2jm32160b
18. [18]
  Che C M, Fu W F, Lai S W, et al. Chem. Commun., 2003:118-119
19. [19]
  Rivera E J, Barbosa C, Torres R, et al. J. Mater. Chem., 2011, 21:15899-15902 doi: 10.1039/c1jm12053k
20. [20]
  Krikorian M, Liu S, Swager T M. J. Am. Chem. Soc., 2014, 136:2952-2955 doi: 10.1021/ja4114352
21. [21]
  Lai J C, Jia X Y, Wang D P, et al. Nat. Commun., 2019, 10:1164 doi: 10.1038/s41467-019-09130-z
22. [22]
  Lai J C, Li L, Wang D P, et al. Nat. Commun., 2018, 9:2725 doi: 10.1038/s41467-018-05285-3
23. [23]
  Li C H, Zuo J L. Adv. Mater., 2019:e1903762 doi: 10.1002/adma.201903762
24. [24]
  ZHANG Ting, BAI Yuanyuan, SUN Fuqin. Sci. Sin. Inform., 2018, 48(6):650-669
25. [25]
  Mei J F, Jia X Y, Lai J C, et al. Macromol. Rapid Commun., 2016, 37:1667-1675 doi: 10.1002/marc.201600428
26. [26]
  SAINT-Plus, Ver. 6.02, Bruker Analytical X-ray System, Madison, WI, 1999.
27. [27]
  Sheldrick G M. SADABS, an Empirical Absorption Correction Program, Bruker Analytical X-ray Systems, Madison, WI, 1996.
28. [28]
  Sheldrick G M. Acta Crystallogr. Sect. A, 2008, A64:112-122
29. [29]
  Wang D P, Lai J C, Lai H Y, et al. Inorg. Chem., 2018, 57:3232-3242 doi: 10.1021/acs.inorgchem.7b03260
30. [30]
  Wang D P, Zhao Z H, Li C H, et al. Mater. Chem. Front., 2019, 3:1411-1421 doi: 10.1039/C9QM00115H
31. [31]
  Cárdenas D J, Echavarren A M, de Arellano M C R. Organometallics, 1999, 18:3337-3341 doi: 10.1021/om990125g
32. [32]
  Burnworth M, Tang L, Kumpfer J R, et al. Nature, 2011, 472:334-337 doi: 10.1038/nature09963
33. [33]
  Williams J A G, Beeby A, Davies E S, et al. Inorg. Chem., 2003, 42:8609-8611 doi: 10.1021/ic035083+
34. [34]
  Farley S J, Rochester D L, Thompson A L, et al. Inorg. Chem., 2005, 44:9690-9703 doi: 10.1021/ic051049e
35. [35]
  Wang Z, Turner E, Mahoney V, et al. Inorg. Chem., 2010, 49:11276-11286 doi: 10.1021/ic100740e
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沈阳化工大学材料科学与工程学院沈阳 110142