Citation: XI Jing, MA Xiu-Fang, XU Yan-Hong, ZHOU Hui-Liang, ZHOU Yu-Ting, LIU Xiang-Yu. Solvent-Induced Syntheses, Crystal Structures and Magnetic Properties of Two Mononuclear Er(Ⅲ) Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(5): 927-932. doi: 10.11862/CJIC.2020.103 shu

Solvent-Induced Syntheses, Crystal Structures and Magnetic Properties of Two Mononuclear Er(Ⅲ) Complexes

State Key Laboratory of High-Efficiency Coal Utilization and Green Chemical Engineering, National Demonstration Center for Experimental Chemistry Education, College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, China

Corresponding author: ZHOU Hui-Liang, 13995209835@163.com LIU Xiang-Yu, xiangyuliu432@126.com
Received Date: 15 November 2019
Revised Date: 13 March 2020

Figures(2)

By adjusting the ratio of the solvent components, two mononuclear erbium complexes, [Er(bpad)₃]·CH₃OH·H₂O (1) and[Er(bpad)₂(H₂O)₂]NO₃·3H₂O (2) (Hbpad=N₃-benzoylpyridine-2-carboxamidrazone), have been successfully synthesized. In the mixure of methanol and water solvent (2:1, V/V), yellow crystals of 1 were prepared by solution reaction of Er(NO₃)₃·6H₂O, Hbpad and triethylamine. Interestingly, complex 2 was obtained by the similar way of 1, while the volume ratio of CH₃OH to H₂O is altered to be 1:2. The resulting complexes were characterized by IR spectrum, elemental analysis. Two complexes are air stable, and can maintain the crystalline integrities at ambient conditions. Crystal structure analysis indicates that the Er(Ⅲ) ions in 1 and 2 present nona-coordinated and octa-coordinated environments in different coordination geometries, respectively. Monocapped square antiprism (C_4v) is formed in 1, while biaugmented trigonal prism (C_2v) is observed in 2. The direct-current (dc) and alternating-current (ac) magnetic susceptibilities of 1 and 2 have been analyzed as well.
- erbium (Ⅲ) complex,
- solvent effect,
- crystal structure,
- magnetic property
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