Citation: ZHANG Lin, WANG Jing, TANG Yan-Ping, GUO Yu-Zhong, HUANG Rui-An. Preparation and Li⁺-Storage Behaviour of Ordered Mesoporous Si/C Composite Structure[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(5): 893-900. doi: 10.11862/CJIC.2020.092 shu

Preparation and Li⁺-Storage Behaviour of Ordered Mesoporous Si/C Composite Structure

1.
College of Material Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China
2.
Guizhou University of Commerce, Guiyang 550000, China
3.
National Engineering Laboratory for Vacuum Metallurgy, Kunming 650093, China

Corresponding author: GUO Yu-Zhong, yzguocn62@sina.com; HUANG Rui-An,
Received Date: 16 December 2019
Revised Date: 28 February 2020

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In this paper, an ordered mesoporous Si/C composite structure was prepared successfully for the anode materials of Li-ion batteries through the synthesis of SiO₂-ordered mesoporous precursor (SiO₂-OMPs) by a P123-copolymer templet route and then a magnesiothermic reduction reaction (MRR) for the SiO₂-OMPs precursor and ensuing a phenolic-resin based carbon-capsuling treatment. From the observations of SEM/TEM, it is found that the morphology of SiO₂-OMPs can be got well-controlled by HCl concentration and obtained a short rod with densified geometrical stacking under high acid concentration, and the ordered mesoporous symmetry kept unchanged perfectly through later MRR and C-capsuling routes. In addition, the detailed and reasonable analyses based on XRD data reveal that MRR process consists of two-step serial reactions:the Mg₂Si intermediate formation from Mg and SiO₂ reactants and its transition to final Si products by re-reducing SiO₂. The slow feature of the solid/solid diffusive reaction in the second step restrains the completion of whole reduction process, resulting in a low yield of silicon and the existence of some impurity phases. Electrochemical measurements show that the ordered mesoporous Si/C composite exhibited excellent cyclic stability and rate performance, which can be attributed to the robust architect and unblocked mesopore system within such composite structure.
- Si/C composite structure,
- mesoporous materials,
- lithium ion battery,
- anode material,
- electrochemistry
1. [1]
  Davis M E. Nature, 2002, 417(20):813-821
2. [2]
  Cristina M, Avelino C.. Coord. Chem. Rev., 2011, 255(13):1558-1580
3. [3]
  Dorin R M, Sai H, Wiesner U.. Chem. Mater., 2014, 26:339-347
4. [4]
  Chen Y P, Chen C T, Hung Y, et al.. J. Am. Chem. Soc., 2013, 135:1516-1523
5. [5]
  Lin C, Mao C, Zhang J J, et al.. Biomed. Mater., 2014, 45:435-451
6. [6]
  Karimi S, Amini R.. ChemCatChem, 2015, 7(11):827-829 doi: 10.1002/cctc.201500126
7. [7]
  Kresge C T, Leonowicz M E, Roth W J, et al.. Nature, 1992, 359(6397):710-712 doi: 10.1038/359710a0
8. [8]
  Zhao D Y, Feng J L, Huo Q S, et al.. Science, 1998, 279:548-552
9. [9]
  Jia H P, Gao P F, Yang J, et al.. Adv. Energy Mater., 2011, 1(6):1036-1039
10. [10]
  Chan C K, Peng H L, Liu G, et al.. Nat. Nanotechnol., 2008, 3(1):491-495 doi: 10.1038/nnano.2007.411
11. [11]
  Tarascon J M, Armand M.. Nature, 2001, 414(6861):359-367 doi: 10.1038/35104644
12. [12]
  Szczech J R, Song J.. Energy Environ. Sci., 2010, 4:56-72 doi: 10.1039/C0EE00281J
13. [13]
  Tang Y P, Yuan S, Guo Y Z, et al.. Electrochim. Acta, 2016, 200:182-188 doi: 10.1016/j.electacta.2009.12.074
14. [14]
  Zhao D Y, Yang P D, Chmelka B F, et al.. Chem. Mater., 1999, 11(5):1174-1178 doi: 10.1002/chin.199929264
15. [15]
  Evers S, Nazar L F.. Acc. Chem. Res., 2013, 46(5):1135-1143 doi: 10.1021/ar3001348
16. [16]
  Bao X Y, Zhao X J.. J. Phys. Chem. B, 2005, 109(21):10727-10736 doi: 10.1021/jp050449k
17. [17]
  Bao Z H, Weatherspoon M R, Shian S, et al.. Nature, 2007, 38:172-175 doi: 10.1002/chin.200723210
18. [18]
  Fan H Y, Lu Y F, Stump A, et al.. Nature, 2000, 405:56-60 doi: 10.1038/35011026
19. [19]
  Baratto C, Faglia G, Sberveglieri G, et al.. Thin Solid Films, 2001, 391(2):261-264 doi: 10.1016/s0040-6090(01)00992-0
20. [20]
  Cha J N, Stucky G D, Morse D E, et al.. Nature, 2000, 403:289-292 doi: 10.1038/35002038
21. [21]
  Wang Y G, Zhang F Y, Wang Y Q, et al.. Mater. Chem. Phys., 2009, 115(2):649-655 doi: 10.1021/cm000094b
22. [22]
  Jung D S, Ryou M H, Sung Y J, et al.. Proc. Natl. Acad. Sci. U.S.A., 2013, 110:12229-12234 doi: 10.1016/j.matchemphys.2009.01.027
23. [23]
  Liu N, Huo K, Mcdowell M T, et al.. Sci. Rep., 2013, 3:1919 doi: 10.1038/srep01919
24. [24]
  Yoo J, Kim J, Choi M, Park Y, et al.. Adv. Energy Mater., 2014, 4(16):1400622 doi: 10.1038/srep01919
25. [25]
  Favors Z, Wang W, Bay H H, et al.. Sci. Rep., 2014, 4:5623 doi: 10.1038/srep05623
26. [26]
  Zhong Y, Shaw L L, Manjarres M, et al.. J. Am. Ceram. Soc., 2010, 93(10):3159-3167 doi: 10.1111/j.1551-2916.2010.03867.x
27. [27]
  Barati M, Sarder S, Mclean A, et al.. J. Non-Cryst. Solids, 2011, 357:18-23 doi: 10.1016/j.jnoncrysol.2010.09.079
28. [28]
  Zhang T, Hu L, Liang J, et al.. RSC Adv., 2016, 6(36):30577-30581 doi: 10.1039/C6RA00182C
29. [29]
  Choi S, Bok T, Ryu J, et al.. Nano Energy, 2015, 12:161-168 doi: 10.1016/j.nanoen.2014.12.010
30. [30]
  Yin Y X, Wan L J, Guo Y G.. Sci. Bull., 2012, 57(32):4104-4110
31. [31]
  Su X, Wu Q, Li J, et al.. Adv. Energy Mater., 2014, 4(1):1300882 doi: 10.1002/aenm.201300882
32. [32]
  Kasavajjula U, Wang C, Appleby A J.. J. Power Sources, 2007, 163(2):1003-1039 doi: 10.1016/j.jpowsour.2006.09.084
33. [33]
  Song T, Xia J, Lee J H, et al.. Nano Lett., 2010, 10(5):1710-1716 doi: 10.1021/acs.nanolett.7b01154
34. [34]
  Bang B M, Lee J, Kim H, et al.. Adv. Energy Mater., 2012, 2:878-883 doi: 10.1002/aenm.201100765
35. [35]
  Wada T, Ichitsubo T, Yubuta K, et al.. Nano Lett., 2014, 14(8):4505-4510 doi: 10.1021/nl501500g
36. [36]
  Liang J W, Li X N, Hou Z G, et al.. ACS Nano, 2016, 10(2):2295-2304 doi: 10.1021/acsnano.5b06995
37. [37]
  Sayari A, Han A B, Yang Y, et al.. J. Am. Chem. Soc., 2004, 126(44):14348-14349 doi: 10.1021/ja0478734
38. [38]
  Zhang R Y, Du Y J, Li D, et al.. Adv. Mater., 2014, 26(39):6749-6755 doi: 10.1002/adom.201300489
39. [39]
  Huo Q, Margolese D I, Ciesla U, et al.. Chem. Mater., 1994, 6(8):1176-1191 doi: 10.1021/cm00044a016
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Li+-Storage Behaviour of Ordered Mesoporous Si/C Composite Structure

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通讯作者: 陈斌, bchen63@163.com

Preparation and Li⁺-Storage Behaviour of Ordered Mesoporous Si/C Composite Structure