Citation: YI Wen-Hai, HU Jun-Jie, ZHANG Jia-Li, WEN He-Rui, LIU Sui-Jun, LI Yun-Wu. Dy(Ⅲ) and Zn/Ni-Dy(Ⅲ) Complexes Derived from Polyamine Phenol Ligand with Slow Magnetic Relaxation and Luminescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(4): 607-619. doi: 10.11862/CJIC.2020.085 shu

Dy(Ⅲ) and Zn/Ni-Dy(Ⅲ) Complexes Derived from Polyamine Phenol Ligand with Slow Magnetic Relaxation and Luminescent Properties

YI Wen-Hai ¹ ,
HU Jun-Jie ¹ ,
ZHANG Jia-Li ¹ ,
WEN He-Rui ^1,2,, ,
LIU Sui-Jun ^1,, ,
LI Yun-Wu ^3,,

1.
School of Chemistry and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China
2.
School of Chemistry and Chemical Engineering, Jinggangshan University, Ji'an, Jiangxi 343009, China
3.
School of Chemistry and Chemical Engineering, Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng, Shandong 252000, China

Corresponding author: WEN He-Rui, wenherui63@163.com LIU Sui-Jun, sjliu@jxust.edu.cn LI Yun-Wu, lyw5251851@163.com
Received Date: 25 August 2019
Revised Date: 13 January 2020

Figures(10)

Four Dy(Ⅲ) and Zn/Ni-Dy(Ⅲ) complexes with polyamine phenol ligand were synthesized and structurally characterized, namely[Dy(CH₃OCH₃)L] (1), [Dy₂(μ-H₂O)L₂] (2), [Zn₂DyL₂]ClO₄·H₂O (3) and[Ni₂DyL₂]ClO₄·H₂O (4) (H₃L=N, N', N″-tris(3, 5-dimethyl-2-hydroxybenzyl)-1, 4, 7-triazacyclononane). X-ray crystallographic analysis reveals that 1 and 2 take mononuclear and binuclear structures, respectively, and both 3 and 4 take trinuclear M-Dy(Ⅲ)-M structures (M=Zn (3), Ni (4)). Magnetic measurements showed that complexes 1 and 2 exhibited field-induced slow magnetic relaxation behaviours, while 2 had multiple magnetic relaxation processes. However, no obvious slow magnetic relaxation behaviors were observed in 3 and 4. Fluorescence analyses reveal that complexes 1~3 have narrow-band characteristic emissions of Dy(Ⅲ) ions, but no significant emission was observed in 4 because of the fluorescence quenching effect of Ni(Ⅱ) ions.
- lanthanide complex,
- slow magnetic relaxation,
- luminescence,
- magnetic-luminescent material
1. [1]
  (a) Cui Y J, Yue Y F, Qian G D, et al.. Chem. Rev., 2012, 112(2): 1126-1162 (b)Allendorf M D, Bauer C A, Bhakta R K, et al.. Chem. Soc. Rev., 2009, 38(5): 1330-1352 (c)Hazra A, Kanoo A, Maji T K.. Chem. Commun., 2011, 47(1): 538-540
2. [2]
3. [3]
  (a) Lee J E, Lee N, Kim N, et al.. J. Am. Chem. Soc., 2009, 132(2): 552-557 (b)Jia J H, Li Q W, Chen Y C, et al.. Coor. Chem. Rev., 2019, 378: 365-381 (c)Shrivastava N, Khan L U, Khan Z U, et al.. J. Mater. Chem. C, 2017, 5(9): 2282-2290
4. [4]
  Kas R, Sevinc E, Topal U, et al.. J. Phys. Chem. C, 2010, 114(17):7758-7766 doi: 10.1021/jp100312e
5. [5]
  Prasad A I, Parchur A K, Juluri R R, et al.. Dalton Trans., 2013, 42(14):4885-4896 doi: 10.1039/c2dt32508j
6. [6]
  Chorazy S, Rams M, Nakabayashi K, et al.. Chem. Eur. J., 2016, 22(22):7371-7375 doi: 10.1002/chem.201601244
7. [7]
  Sanchez C, Belleville P, Popall M, et al.. Chem. Soc. Rev., 2011, 40(2):696-753 doi: 10.1039/c0cs00136h
8. [8]
  Feng S S, Xie L, Lu L P, et al.. J. Solid. State. Chem., 2018, 258:335-345 doi: 10.1016/j.jssc.2017.10.035
9. [9]
  Wang J W, Niu Y J, Zhang M, et al.. Inorg. Chem., 2018, 57(4):1796-1805 doi: 10.1021/acs.inorgchem.7b02672
10. [10]
  Ruiz J, Lorusso G, Evangelisti M, et al.. Inorg. Chem., 2014, 53(7):3586-3594 doi: 10.1021/ic403097s
11. [11]
  Tanaka D, Inose T, Tanaka H, et al.. Chem Commun., 2012, 48(63):7796-7798 doi: 10.1039/c2cc00086e
12. [12]
  Vallezo J, Cano J, Castro I, et al.. Chem Commun., 2012, 48(62):7726-7728 doi: 10.1039/c2cc33674j
13. [13]
14. [14]
  (a) Ren M, Brites C D, Bao S S, et al.. J. Mater. Chem. C, 2015, 3(33): 8480-8484 (b)Katayama Y, Kayumi T, Viana B, et al.. J. Mater. Chem. C, 2017, 5(34): 8893-8900
15. [15]
16. [16]
  Ferbinteanu M, Kajiwara T, Choi K Y, et al.. J. Am. Chem. Soc., 2006, 128(28):9008-9009 doi: 10.1021/ja062399i
17. [17]
  Liu J L, Chen Y C, Zheng Y Z, et al.. Chem. Sci., 2013, 4(8):3310-3316 doi: 10.1039/c3sc50843a
18. [18]
  Titos-Padilla S, Ruiz J, Herrera J M, et al.. Inorg. Chem., 2013, 52(16):9620-9626 doi: 10.1021/ic401378k
19. [19]
  Chandrasekhar V, Dey A, Mota A J, et al.. Inorg. Chem., 2013, 52(8):4554-4561 doi: 10.1021/ic400073y
20. [20]
  Palacios M A, Titos-Padilla S, Ruiz J, et al.. Inorg. Chem., 2014, 53(3):1465-1474
21. [21]
  Upadhyay A, Singh S K, Das C, et al.. Chem. Commun., 2014, 50(64):8838-8841 doi: 10.1039/C4CC02094D
22. [22]
  Das S, Bejoymohandas K S, Dey A, et al.. Chem. Eur. J., 2015, 21(17):6449-6464 doi: 10.1002/chem.201406666
23. [23]
  Oyarzabal I, Ruiz J, Ruiz E, et al.. Chem. Commun., 2015, 51(62):12353-12356 doi: 10.1039/C5CC04495B
24. [24]
  Wang S Q, Yang X P, Zhu T, et al.. Dalton Trans., 2018, 47(1):53-57 doi: 10.1039/C7DT02576A
25. [25]
  Fondo M, Corredoira-Vazquez J, García-Deibe A M, et al.. Inorg. Chem., 2017, 56(10):5646-5656 doi: 10.1021/acs.inorgchem.7b00165
26. [26]
  Wen H R, Dong P P, Liu S J, et al.. Dalton Trans., 2017, 46(4):1153-1162 doi: 10.1039/C6DT04027F
27. [27]
  (a) Nakai H, Kuyama M, Seo Y, et al.. Dalton Trans., 2018, 46: 9126-9130 (b)Nakai H, Seo J, Kitagawa K, et al.. Inorg. Chem., 2016, 55(13): 6609-6615
28. [28]
  Wen H R.. Zhang J L, Liang F Y, et al. New J. Chem., 2019, 43(10):4067-4074
29. [29]
  Moore D A, Fanwick P E, Welch M J.. Inorg. Chem., 1989, 28(8):1504-1506 doi: 10.1021/ic00307a016
30. [30]
  Sheldrick G M.. SHELXS-97, Program for the Solution of Crystal Structures, University of Göttingen, Göttingen, 1997.
31. [31]
  Process-Auto, Rigaku America Corporation, Texas: The Woodlands, 1998..
32. [32]
  Sheldrick G M.. SADABS, University of Göttingen, Germany, 2008.
33. [33]
  Sheldrick G M.. Acta Crystallogr. Sect. A, 2015, A71:3-8
34. [34]
  Llunell M, Casanova D, Cirera J, et al.. SHAPE, Ver. 2.1, Barcelona, Spain, University of Barcelona, 2013.
35. [35]
  Dreiser J, Pedersen K S, Piamonteze C, et al.. Chem. Sci., 2012, 3:1024-1032 doi: 10.1039/C2SC00794K
36. [36]
  Ungur L, Chibotaru L F.. Phys. Chem. Chem. Phys., 2011, 13(45):20086-20090 doi: 10.1039/c1cp22689d
37. [37]
  Lin P H, Burchell T J, Ungur L, et al.. Angew. Chem., 2009, 48(50):9489-9492 doi: 10.1002/anie.200903199
38. [38]
  Abragan A, Bleaney B.. Electron Paramagnetic Resonance of Transition Ions. Clarendon:Oxford University Press, 1970.
39. [39]
  Hewitt I J, Lan Y, Anson C E, et al.. Chem. Commun., 2009(44):6765-6767 doi: 10.1039/b908194a
40. [40]
  (a) Ogiego J M, Zych A, Ivanovskikh K V, et al.. J. Phys. Chem. A, 2012, 116(33): 8464-8474 (b)Lewis D J, Deshmukh P, Tedstone A A, et al.. Chem. Commun., 2014, 50(87): 13334-13337
41. [41]
  Maity M, Majee M C, Kundu S, et al.. Inorg. Chem., 2015, 54(20):9715-9726 doi: 10.1021/acs.inorgchem.5b01142
42. [42]
  Parker D.. Chem. Soc. Rev., 2004, 33(3):156-165 doi: 10.1039/b311001j
43. [43]
  Zhan C, Ou S, Zou C, et al.. Anal. Chem., 2014, 86(13):6648-6653 doi: 10.1021/ac5013442
44. [44]
  Blagg R J, Eric C A, Mcinnes E J L, et al.. Angew. Chem., 2011, 50:6530-6533 doi: 10.1002/anie.201101932
1. [1]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
2. [2]
  Yan Cheng , Hua-Peng Ruan , Yan Peng , Longhe Li , Zhenqiang Xie , Lang Liu , Shiyong Zhang , Hengyun Ye , Zhao-Bo Hu . Magnetic, dielectric and luminescence synergetic switchable effects in molecular material [Et₃NCH₂Cl]₂[MnBr₄]. Chinese Chemical Letters, 2024, 35(4): 108554-. doi: 10.1016/j.cclet.2023.108554
3. [3]
  Hongdao LI , Shengjian ZHANG , Hongmei DONG . Magnetic relaxation and luminescent behavior in nitronyl nitroxide-based annuluses of rare-earth ions. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 972-978. doi: 10.11862/CJIC.20230411
4. [4]
  Zhao-Bo Hu , Ling-Ao Gui , Long-He Li , Tong-Tong Xiao , Adam T. Hand , Pagnareach Tin , Mykhaylo Ozerov , Yan Peng , Zhongwen Ouyang , Zhenxing Wang , Zi-Ling Xue , You Song . Co^Ⅱ single-ion magnet and its multi-dimensional aggregations: Influence of the structural rigidity on magnetic relaxation process. Chinese Chemical Letters, 2025, 36(2): 109600-. doi: 10.1016/j.cclet.2024.109600
5. [5]
  Hao Jiang , Yuan-Yuan He , Hai-Chao Liang , Meng-Jia Shang , Han-Han Lu , Chun-Hua Liu , Yin-Shan Meng , Tao Liu , Yuan-Yuan Zhu . Tuning lanthanide luminescence from bipyridine-bis(oxazoline/thiazoline) tetradentate ligands. Chinese Journal of Structural Chemistry, 2024, 43(9): 100354-100354. doi: 10.1016/j.cjsc.2024.100354
6. [6]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
7. [7]
  Zhaodong WANG . In situ synthesis, crystal structure, and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 597-604. doi: 10.11862/CJIC.20240268
8. [8]
  Di ZHANG , Tianxiang XIE , Xu HE , Wanyu WEI , Qi FAN , Jie QIAO , Gang JIN , Ningbo LI . Construction and antitumor activity of pH/GSH dual-responsive magnetic nanodrug. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 786-796. doi: 10.11862/CJIC.20240329
9. [9]
  Shihong Wu , Ronghui Zhou , Hang Zhao , Peng Wu . Sonoafterglow luminescence for in vivo deep-tissue imaging. Chinese Chemical Letters, 2024, 35(10): 110026-. doi: 10.1016/j.cclet.2024.110026
10. [10]
  Rui Wang , He Qi , Haijiao Zheng , Qiong Jia . Light/pH dual-responsive magnetic metal-organic frameworks composites for phosphorylated peptide enrichment. Chinese Chemical Letters, 2024, 35(7): 109215-. doi: 10.1016/j.cclet.2023.109215
11. [11]
  Mengyuan Li , Xitong Ren , Yanmei Gao , Mengyao Mu , Shiping Zhu , Shufang Tian , Minghua Lu . Constructing bifunctional magnetic porous poly(divinylbenzene) polymer for high-efficient removal and sensitive detection of bisphenols. Chinese Chemical Letters, 2024, 35(12): 109699-. doi: 10.1016/j.cclet.2024.109699
12. [12]
  Yanjie Li , Chaoqun Qu , Siqi Meng , Jiaqi Hu , Ze Gao , Hongji Xu , Rui Gao , Ming Feng . Revealing electronic state evolution of Co(Ⅱ)/Co(Ⅲ) in CoO (111) plane during OER process through magnetic measurement. Chinese Chemical Letters, 2025, 36(3): 109872-. doi: 10.1016/j.cclet.2024.109872
13. [13]
  Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269
14. [14]
  Xiao-Fang Lv , Xiao-Yun Ran , Yu Zhao , Rui-Rui Zhang , Li-Na Zhang , Jing Shi , Ji-Xuan Xu , Qing-Quan Kong , Xiao-Qi Yu , Kun Li . Combing NIR-Ⅱ molecular dye with magnetic nanoparticles for enhanced photothermal theranostics with a 95.6% photothermal conversion efficiency. Chinese Chemical Letters, 2025, 36(4): 110027-. doi: 10.1016/j.cclet.2024.110027
15. [15]
  Huijie An , Chen Yang , Zhihui Jiang , Junjie Yuan , Zhongming Qiu , Longhao Chen , Xin Chen , Mutu Huang , Linlang Huang , Hongju Lin , Biao Cheng , Hongjiang Liu , Zhiqiang Yu . Luminescence-activated Pt(Ⅳ) prodrug for in situ triggerable cancer therapy. Chinese Chemical Letters, 2024, 35(7): 109134-. doi: 10.1016/j.cclet.2023.109134
16. [16]
  Chaohui Zheng , Jing Xi , Shiyi Long , Tianpei He , Rui Zhao , Xinyuan Luo , Na Chen , Quan Yuan . Persistent luminescence encoding for rapid and accurate oral-derived bacteria identification. Chinese Chemical Letters, 2025, 36(1): 110223-. doi: 10.1016/j.cclet.2024.110223
17. [17]
  Yuanpeng Ye , Longfei Yao , Guofeng Liu . Engineering circularly polarized luminescence through symmetry manipulation in achiral tetraphenylpyrazine structures. Chinese Journal of Structural Chemistry, 2025, 44(2): 100460-100460. doi: 10.1016/j.cjsc.2024.100460
18. [18]
  Shuangying Li , Qingxiang Zhou , Zhi Li , Menghua Liu , Yanhui Li . Sensitive measurement of silver ions in environmental water samples integrating magnetic ion-imprinted solid phase extraction and carbon dot fluorescent sensor. Chinese Chemical Letters, 2024, 35(5): 108693-. doi: 10.1016/j.cclet.2023.108693
19. [19]
  Guang-Xu Duan , Queting Chen , Rui-Rui Shao , Hui-Huang Sun , Tong Yuan , Dong-Hao Zhang . Encapsulating lipase on the surface of magnetic ZIF-8 nanosphers with mesoporous SiO₂ nano-membrane for enhancing catalytic performance. Chinese Chemical Letters, 2025, 36(2): 109751-. doi: 10.1016/j.cclet.2024.109751
20. [20]
  Xianzheng Zhang , Yana Chen , Zhiyong Ye , Huilin Hu , Ling Lei , Feng You , Junlong Yao , Huan Yang , Xueliang Jiang . Magnetic field-assisted microbial corrosion construction iron sulfides incorporated nickel-iron hydroxide towards efficient oxygen evolution. Chinese Journal of Structural Chemistry, 2024, 43(1): 100200-100200. doi: 10.1016/j.cjsc.2023.100200

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(567)
HTML views(54)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142