Citation: LI Si-Jia, ZHU Jie, ZHENG Ji-Ming, GENG Ji-Ye, LI Yi-Bing. Preparation and Oxygen Reduction Properties of Cu-N Co-doped Carbon-Based Catalysts[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(4): 627-635. doi: 10.11862/CJIC.2020.079 shu

Preparation and Oxygen Reduction Properties of Cu-N Co-doped Carbon-Based Catalysts

College Material Science and Engineering, Guilin University of Technology, Guilin, Guangxi 541000, China

Corresponding author: LI Yi-Bing, lybgems@glut.edu.cn
Received Date: 26 June 2019
Revised Date: 5 November 2019

Figures(8)

In order to solve the problems of high cost and poor stability of fuel cell cathode catalysts, Cu, N co-doped carbon based catalyst (Cu-N-KB) was prepared by simple heat treatment using α-nitroso-β-naphthol copper, melamine and conductive carbon black. The characterization results show that Cu and N are uniformly distributed in the carbon support and the copper exists in the form of crystalline copper particles and amorphous Cu-N_x. The high specific surface area and mesoporous structure of the catalyst ensure a large number of active sites and fast mass transfer efficiency. The catalyst exhibits excellent oxygen reduction catalysis, methanol resistance and stability in an alkaline medium compared to commercial Pt/C catalysts.
- oxygen reduction recation,
- transition metal-nitrogen co-doped,
- copper particles
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